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Research Article

Simultaneous improving luminescence intensity and stability of CsPbBr3:SCN−@Eu/Zr-Uio-66-NH2 with tunable emissions from blue to green and applications in indoor photovoltaics

Minze Li1,§, Yao Sun1,§, Honglai Lu1,§, Peifen Zhu2, Ruihong Wang1,2, Guofeng Wang1 ( )
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
Department of Electrical Engineering and Computer Science, University of Missouri, Columbia, MO 65211, USA

§ Minze Li, Yao Sun, and Honglai Lu contributed equally to this work.

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Graphical Abstract

Based on the construction of CPB:SCN−@MOF:Eu (CPB = CsPbBr3 and MOF = metal-organic framework), the interaction between CPB:SCN− and MOFs:Eu enhances the luminescence efficiency of each other, both of which were sufficient to construct high-performance light-emitting diode (LED) devices and further excite solar cells to generate stable photoelectric signals. The optical properties, band structures, and charge density differences were calculated using the density functional theory (DFT) method.

Abstract

The construction of stable and efficient materials that emit blue and green light remains a challenge. Among the blue light materials reported, metal-organic framework (MOF) materials are rarely reported as blue phosphors due to their weak luminescence intensity. Based on the construction of CsPbBr3@MOF (CPB@MOF), an innovative idea was proposed to simultaneously enhance the green luminescence of CPB and the blue luminescence of MOF through the interaction between CPB and MOF for the first time. As expected, the blue luminescence from CPB:7%SCN−@0.5%MOF:Eu as well as the green luminescence from 5%CPB:7%SCN−@MOF:Eu was sufficient to construct high-performance light-emitting diode (LED) devices and further excite solar cells to generate stable photoelectric signals. The white LED (WLED) device with excellent color quality (color rendering index (CRI) = 96.2) and correlated color temperature (CCT = 9688 K) can be constructed by using the obtained blue-emitting CPB:7%SCN-@0.5%MOF:Eu, green-emitting 5%CPB:7%SCN−@MOF:Eu, and red-emitting PPB:30%Mn2+. The density functional theory (DFT) theoretical calculation results indicate that the p orbital of Pb plays the major role in the conduction band, and the p orbital of Br plays the major role in the valance band of CPB and CPB:SCN−. While the p orbital of O plays the major role in both the conduction band and valance band of MOF. The heat capacity of CPB and CPB:SCN− separately reaches the Dulong–Petit limit at 200 and 400 K, indicating that the thermal stability of CsPbBr3 increases after SCN− doping.

Keywords

CsPbBr3:SCN−@Uio-66-NH2 compositesluminescence stabilitywhite light-emitting diodes (WLEDs)indoor photovoltaicsdensity functional theory (DFT) calculation

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Nano Research
Volume 17 Issue 8,
August 2024
Pages 6879-6887
DOI: 10.1007/s12274-024-6663-9
Cite this article:
Li M, Sun Y, Lu H, et al. Simultaneous improving luminescence intensity and stability of CsPbBr3:SCN−@Eu/Zr-Uio-66-NH2 with tunable emissions from blue to green and applications in indoor photovoltaics. Nano Research, 2024, 17(8): 6879-6887. https://doi.org/10.1007/s12274-024-6663-9
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Received: 17 February 2024
Revised: 15 March 2024
Accepted: 26 March 2024
Published: 27 April 2024
© Tsinghua University Press 2024
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