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Communication

Cauliflower-like Ni3S2 foam for ultrastable oxygen evolution electrocatalysis in alkaline seawater

Qiuying Dai1Xun He1Yongchao Yao1Kai Dong1Xuwei Liu1Xiankun Guo1Jie Chen1Xiaoya Fan1Dongdong Zheng2Yongsong Luo2Shengjun Sun2Luming Li3Wei Chu3Asmaa Farouk4Mohamed S. Hamdy4Xuping Sun1,2,5( )Bo Tang2,6( )
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, 61413 Abha, Saudi Arabia
Center for High Altitude Medicine, West China Hospital, Sichuan University, Chengdu 610041, China
Laoshan Laboratory, Qingdao 266237, China
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Graphical Abstract

A three-dimensional (3D) porous cauliflower-like Ni3S2 foam on Ni foam acts as an effective electrocatalyst for alkaline seawater oxidation, achieving a current density of 100 mA·cm−2 at just 369 mV overpotential, and demonstrates a robust 1000-h endurance in alkaline seawater oxidation.

Abstract

It is of great importance to design and develop electrocatalysts that are both long-lasting and efficient for seawater oxidation. Herein, a three-dimensional porous cauliflower-like Ni3S2 foam on Ni foam (Ni3S2 foam/NF) is proposed as a high-performance electrocatalyst for the oxygen evolution reaction in alkaline seawater. The as-synthesis Ni3S2 foam/NF achieves exceptional efficacy, achieving a current density of 100 mA·cm−2 at mere overpotential of 369 mV. Notably, its electrocatalytic stability extends up to 1000 h at 500 mA·cm−2.

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Nano Research
Pages 6820-6825
Cite this article:
Dai Q, He X, Yao Y, et al. Cauliflower-like Ni3S2 foam for ultrastable oxygen evolution electrocatalysis in alkaline seawater. Nano Research, 2024, 17(8): 6820-6825. https://doi.org/10.1007/s12274-024-6744-9
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Received: 21 February 2024
Revised: 29 April 2024
Accepted: 07 May 2024
Published: 31 May 2024
© Tsinghua University Press 2024
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