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Research Article

Flat Zn deposition at battery anode via an ultrathin robust interlayer

Yizhou Wang1,§, Jianyu Chen2,§, Zibo Chen2, Qian He2, Zhengnan Tian1, Jin Zhao2( ), Yanwen Ma2,3, Husam N. Alshareef1( )
Materials Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
State Key Laboratory of Organic Electronics and Information Displays (KLOEID) and Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing 210023, China
Suzhou Vocational Institute of Industrial Technology, Suzhou 215104, China

§ Yizhou Wang and Jianyu Chen contributed equally to this work.

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Graphical Abstract

Kevlar membrane is employed as an interlayer to render flat Zn deposition on Zn metal anodes. The flat morphology of different deposition capacities and the significantly enhanced (002)-plane peak in X-ray diffraction demonstrate the dendrite-suppression effect of such Kevlar interlayer. This work provides a new solution for stabilizing Zn anodes with the crystal plane regulation strategy.

Abstract

Rechargeable aqueous zinc (Zn) ion batteries (AZIBs) using low-cost and safe Zn metal anodes are considered promising candidates for future grid-scale energy storage systems, but the Zn dendrite problem severely hinders the further prospects of AZIBs. Regulating Zn depositing behaviors toward horizontal alignment is highly effective and thus has received huge attention. However, such a strategy is usually based on previous substrate engineering, which requires complex preparation or expensive equipment. Therefore, it is essential to develop a novel solution that can realize horizontally aligned Zn flake deposition via easy operation and low cost. Herein, we report an ultrathin and robust Kevlar membrane as the interlayer to mechanically suppress Zn dendrite growth. Compared to the randomly distributed flaky dendrites in the control group, the deposited Zn sheets would grow into parallel alignment with the existence of such interlayer. As the dendrites are effectively suppressed, Zn||Cu asymmetric, Zn||Zn symmetric, and Zn||MnO2 full batteries using Kevlar interlayer deliver significantly improved cycling stabilities. Furthermore, the Zn||MnO2 pouch cell using a Kevlar interlayer delivers stable cycling performance and shows stable operation during multi-angle folding. We believe this work provides a new possibility for regulating Zn deposition from a crystallographic perspective.

Keywords

Zn dendritesdendrite suppressionZn metal anodesaqueous Zn ion batteries(002) crystal plane

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Nano Research
Volume 17 Issue 9,
September 2024
Pages 8104-8111
DOI: 10.1007/s12274-024-6783-2
Cite this article:
Wang Y, Chen J, Chen Z, et al. Flat Zn deposition at battery anode via an ultrathin robust interlayer. Nano Research, 2024, 17(9): 8104-8111. https://doi.org/10.1007/s12274-024-6783-2
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Secondary batteries

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Received: 20 March 2024
Revised: 06 May 2024
Accepted: 26 May 2024
Published: 24 June 2024
© Tsinghua University Press 2024
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