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Traditional iridium (Ir) oxide catalysts have faced significant limitations in water electrolysis, particularly under acidic conditions where instability and degradation severely restrict the efficiency of the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). To overcome these challenges, this study successfully synthesized highly dispersed IrPtPdNi alloy nanoparticles on a graphene oxide support using a vertically moving reactor, demonstrating exceptional performance in water electrolysis. These nanoparticles, synthesized via a fast-moving bed pyrolysis method, combine iridium, platinum, palladium, and nickel. They exhibit lower overpotentials in OER and comparable performance in HER to commercial catalysts, while also offering enhanced stability. These results surpass the limitations of traditional catalysts, marking significant progress toward more efficient and sustainable hydrogen production technologies. This advancement is expected to contribute significantly to the development of sustainable energy systems by innovatively enhancing the performance of catalysts in the electrochemical water-splitting process.
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Zhang, Y. Q.; Wang, D. D.; Wang, S. Y. High-entropy alloys for electrocatalysis: Design, characterization, and applications. Small 2022, 18, 2104339.
Tajuddin, A. A. H.; Wakisaka, M.; Ohto, T.; Yu, Y.; Fukushima, H.; Tanimoto, H.; Li, X. G.; Misu, Y.; Jeong, S.; Fujita, J. I. et al. Corrosion-resistant and high-entropic non-noble-metal electrodes for oxygen evolution in acidic media. Adv. Mater. 2023, 35, 2207466.
Feng, G.; Ning, F. H.; Song, J.; Shang, H. F.; Zhang, K.; Ding, Z. P.; Gao, P.; Chu, W. S.; Xia, D. G. Sub-2 nm ultrasmall high-entropy alloy nanoparticles for extremely superior electrocatalytic hydrogen evolution. J. Am. Chem. Soc. 2021, 143, 17117–17127.
Esquius, J. R.; Liu, L. F. High entropy materials as emerging electrocatalysts for hydrogen production through low-temperature water electrolysis. Mater. Futures 2023, 2, 022102.
Zhang, L. L.; Lei, Y. T.; Xu, W. J.; Wang, D.; Zhao, Y. F.; Chen, W. X.; Xiang, X.; Pang, X. C.; Zhang, B.; Shang, H. S. Highly active and durable nitrogen-doped CoP/CeO2 nanowire heterostructures for overall water splitting. Chem. Eng. J. 2023, 460, 141119.
Lei, Y. T.; Zhang, L. L.; Xu, W. J.; Xiong, C. L.; Chen, W. X.; Xiang, X.; Zhang, B.; Shang, H. S. Carbon-supported high-entropy Co-Zn-Cd-Cu-Mn sulfide nanoarrays promise high-performance overall water splitting. Nano Res. 2022, 15, 6054–6061.
Cai, Z. X.; Goou, H.; Ito, Y.; Tokunaga, T.; Miyauchi, M.; Abe, H.; Fujita, T. Nanoporous ultra-high-entropy alloys containing fourteen elements for water splitting electrocatalysis. Chem. Sci. 2021, 12, 11306–11315.
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Jahan, M.; Liu, Z. L.; Loh, K. P. A graphene oxide and copper-centered metal organic framework composite as a tri-functional catalyst for HER, OER, and ORR. Adv. Funct. Mater. 2013, 23, 5363–5372.
Zhang, S.; Rui, Y.; Zhang, X.; Sa, R. J.; Zhou, F.; Wang, R. H.; Li, X. J. Ultrafine cobalt-ruthenium alloy nanoparticles induced by confinement effect for upgrading hydrogen evolution reaction in all-pH range. Chem. Eng. J. 2021, 417, 128047.
Park, J. C.; Kim, A.; Jang, S.; Yang, J. I.; Kang, S. W.; Lee, C. W.; Kim, B. H.; Park, K. H. Facile synthesis of a high performance NiPd@CMK-3 nanocatalyst for mild Suzuki–Miyaura coupling reactions. ChemCatChem 2019, 11, 991–996.
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Yao, Y. G.; Huang, Z. N.; Xie, P. F.; Lacey, S. D.; Jacob, R. J.; Xie, H.; Chen, F. J.; Nie, A. M.; Pu, T. C.; Rehwoldt, M. et al. Carbothermal shock synthesis of high-entropy-alloy nanoparticles. Science 2018, 359, 1489–1494.
Waag, F.; Li, Y.; Ziefuß, A. R.; Bertin, E.; Kamp, M.; Duppel, V.; Marzun, G.; Kienle, L.; Barcikowski, S.; Gökce, B. Kinetically-controlled laser-synthesis of colloidal high-entropy alloy nanoparticles. RSC Adv. 2019, 9, 18547–18558.
Kim, K. S.; Couillard, M.; Tang, Z. Q.; Shin, H.; Poitras, D.; Cheng, C. J.; Naboka, O.; Ruth, D.; Plunkett, M.; Chen, L. X. et al. Continuous synthesis of high-entropy alloy nanoparticles by in-flight alloying of elemental metals. Nat. Commun. 2024, 15, 1450.
Lee, H. K.; Kang, S. W.; Yang, J. I.; Chun, D. H.; Lee, J. H.; Oh, D.; Ban, J.; Jung, T.; Jung, H.; Park, J. C. A new systematic synthesis of ultimate nickel nanocatalysts for compact hydrogen generation. React. Chem. Eng. 2020, 5, 1218–1223.
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Wang, Z. F.; Wang, J. Q.; Li, Z. P.; Gong, P. W.; Ren, J. F.; Wang, H. G.; Han, X. X.; Yang, S. R. Cooperatively exfoliated fluorinated graphene with full-color emission. RSC Adv. 2012, 2, 11681–11686.