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Research Article | Online First

Five-level anti-counterfeiting based on versatile luminescence of tri-doped double perovskites

Xingru Yang1, Yuhang Sheng1, Linglong Zhang2, Lun Yang3, Fangjian Xing1, Yunsong Di1, Cihui Liu1, Fengrui Hu4, Xifeng Yang5, Guofeng Yang6, Yushen Liu7, Zhixing Gan1( )
Center for Future Optoelectronic Functional Materials, School of Computer and Electronic Information/School of Artificial Intelligence, Nanjing Normal University, Nanjing 210023, China
College of Physics, Nanjing University of Aeronautics and Astronautics, Key Laboratory of Aerospace Information Materials and Physics (NUAA), MIIT, Nanjing 211106, China
Hubei Key Laboratory of Photoelectric Materials and Devices, School of Materials Science and Engineering, Hubei Normal University, Huangshi 435002, China
College of Engineering and Applied Sciences and MOE Key Laboratory of Intelligent Optical Sensing and Manipulation, Nanjing University, Nanjing 210093, China
College of Electronic and Information Engineering, Changshu Institute of Technology, Suzhou 215500, China
School of Science, Jiangsu Provincial Research Center of Light Industrial Optoelectronic Engineering and Technology, Jiangnan University, Wuxi 214122, China
Yancheng Polytechnic College, Yancheng 224005, China
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Graphical Abstract

Abstract

Luminescent materials with multi-emission features are difficult to be replicated, which are highly desirable for advanced anti-counterfeiting. Here, we report the pioneering synthesis of Mn2+/Yb3+/Er3+ tri-doped Cs2Ag0.8Na0.2InCl6 double perovskites (MYE-DP), which exhibit photoluminescence (PL) covering from visible to near-infrared (NIR). The PL colors under excitations of 254 and 365 nm are notably different due to the changed relative emission intensities of self-trapped excitons (STEs) and Mn2+ d–d transition. Moreover, under the excitation of a NIR laser, the MYE-DP exhibits upconversion (UC) emissions of Mn2+ and Er3+. After ceasing the excitation, the long-lived trapped electrons can be thermally released to Mn2+ and Er3+ ions, resulting in both visible and NIR afterglow. Based on multi-modal emissions of the MYE-DP, we demonstrate a five-level anti-counterfeiting strategy, which significantly increases the anti-counterfeiting security. In addition, this work provides valuable insights into the energy transfer between STEs, Mn2+, Ln3+, and traps, laying a solid foundation for future development of new lead-free perovskites.

Keywords

photoluminescenceupconversionanti-counterfeitingself-trapped excitons

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Nano Research
DOI: 10.1007/s12274-024-6918-5
Cite this article:
Yang X, Sheng Y, Zhang L, et al. Five-level anti-counterfeiting based on versatile luminescence of tri-doped double perovskites. Nano Research, 2024, https://doi.org/10.1007/s12274-024-6918-5
Topics:
Photoluminescence

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Received: 15 June 2024
Revised: 18 July 2024
Accepted: 26 July 2024
Published: 22 August 2024
© Tsinghua University Press 2024
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