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CsPbCl3 perovskite is considered a highly promising material for ultraviolet (UV) photodetectors due to its exceptional thermal stability and excellent short-wavelength light response. However, its high lattice energy and low polarizability result in extremely low solubility in conventional solvents, making the synthesis of CsPbCl3 single crystals a significant challenge. In this study, we propose a novel thermodynamically induced crystal restructuring (TICR) process that can transform microcrystalline films (MCFs) into single crystal films (SCFs) within a short period. This method, for the first time, has successfully achieved the synthesis of centimeter-sized CsPbCl3 SCFs and the mechanism has been explored in depth using in-situ techniques. Furthermore, we report the first instance of a CsPbCl3 SCF UV photodiode, which exhibits a record-breaking on/off ratio of 3.32 × 107 and a detectivity of up to 1.15 × 1014 Jones under 0 V bias. It demonstrates excellent response even under weak light conditions of 10 nW·cm−² and maintains outstanding stability with almost no performance degradation after 15 months. This study provides a novel approach for the synthesis of perovskite single crystals and holds significant potential for advancing the development of high-performance optoelectronic devices.
Li, G. R.; Wong, T. W.; Shih, B.; Guo, C. Y.; Wang, L. W.; Liu, J. Q.; Wang, T.; Liu, X. B.; Yan, J. Y.; Wu, B. S. et al. Bioinspired soft robots for deep-sea exploration. Nat. Commun. 2023, 14, 7097.
Romano, V.; Agresti, A.; Verduci, R.; D’Angelo, G. Advances in perovskites for photovoltaic applications in space. ACS Energy Lett. 2022, 7, 2490–2514.
Zhang, X. J.; Chu, D. P.; Jia, B. X.; Zhao, Z. Q.; Pi, J. C.; Yang, Z.; Li, Y. H.; Hao, J. L.; Shi, R. X.; Dong, X. F. et al. Heterointerface design of perovskite single crystals for high-performance X-ray imaging. Adv. Mater. 2024, 36, 2305513.
Li, L. Y.; Yu, Y. T.; Li, P.; Liu, J. X.; Liang, L. H.; Wang, L. Y.; Ding, Y.; Han, X. C.; Ji, J. M.; Chen, S. L. et al. The universal growth of ultrathin perovskite single crystals. Adv. Mater. 2022, 34, 2108396.
Tang, X. B.; Wang, Z. J.; Wu, D.; Wu, Z. H.; Ren, Z. W.; Li, R. X.; Liu, P.; Mei, G. D.; Sun, J. Y.; Yu, J. H. et al. In situ growth mechanism for high-quality hybrid perovskite single-crystal thin films with high area to thickness ratio: Looking for the sweet spot. Adv. Sci. 2022, 9, 2104788.
Yang, Z.; Xu, Q.; Wang, X. D.; Lu, J. F.; Wang, H.; Li, F. T.; Zhang, L.; Hu, G. F.; Pan, C. F. Large and ultrastable all-inorganic CsPbBr3 monocrystalline films: Low-temperature growth and application for high-performance photodetectors. Adv. Mater. 2018, 30, 1802110.
Nie, J. H.; Zhang, Y. M.; Li, L. J.; Zhang, Y. High-performance piezophototronic solar cells based on polarization modulation perovskite. Adv. Devices Instrum. 2023, 4, 0025.
Tian, W. J.; Song, P. Q.; Zhao, Y. P.; Shen, L. N.; Liu, K. K.; Zheng, L. F.; Luo, Y. J.; Tian, C. B.; Xie, L. Q.; Wei, Z. H. Monolithic bilayered In2O3 as an efficient interfacial material for high-performance perovskite solar cells. Interdiscip. Mater. 2022, 1, 526–536.
Xie, Y. M.; Yao, Q.; Xue, Q. F.; Zeng, Z. X.; Niu, T. Q.; Zhou, Y. Z.; Zhuo, M. P.; Tsang, S. W.; Yip, H. L.; Cao, Y. Subtle side chain modification of triphenylamine-based polymer hole-transport layer materials produces efficient and stable inverted perovskite solar cells. Interdiscip. Mater. 2022, 1, 281–293.
Pan, X. Y.; Zhang, J. Q.; Zhou, H.; Liu, R. H.; Wu, D. J.; Wang, R.; Shen, L. P.; Tao, L.; Zhang, J.; Wang, H. Single-layer ZnO hollow hemispheres enable high-performance self-powered perovskite photodetector for optical communication. Nano-Micro Lett. 2021, 13, 70.
Liu, Y. C.; Zhang, Y. X.; Zhao, K.; Yang, Z.; Feng, J. S.; Zhang, X.; Wang, K.; Meng, L. N.; Ye, H. C.; Liu, M. et al. A 1300 mm2 ultrahigh-performance digital imaging assembly using high-quality perovskite single crystals. Adv. Mater. 2018, 30, 1707314.
Huang, J. S.; Yuan, Y. B.; Shao, Y. C.; Yan, Y. F. Understanding the physical properties of hybrid perovskites for photovoltaic applications. Nat. Rev. Mater. 2017, 2, 17042.
Chen, Z. L.; Dong, Q. F.; Liu, Y.; Bao, C. X.; Fang, Y. J.; Lin, Y.; Tang, S.; Wang, Q.; Xiao, X.; Bai, Y. et al. Thin single crystal perovskite solar cells to harvest below-bandgap light absorption. Nat. Commun. 2017, 8, 1890.
Feng, J. G.; Gong, C.; Gao, H. F.; Wen, W.; Gong, Y. J.; Jiang, X. Y.; Zhang, B.; Wu, Y. C.; Wu, Y. S.; Fu, H. B. et al. Single-crystalline layered metal-halide perovskite nanowires for ultrasensitive photodetectors. Nat. Electron. 2018, 1, 404–410.
Li, Z. Q.; Liu, X. Y.; Zuo, C. L.; Yang, W.; Fang, X. S. Supersaturation-controlled growth of monolithically integrated lead-free halide perovskite single-crystalline thin film for high-sensitivity photodetectors. Adv. Mater. 2021, 33, 2103010.
Chen, Y. X.; Ge, Q. Q.; Shi, Y.; Liu, J.; Xue, D. J.; Ma, J. Y.; Ding, J.; Yan, H. J.; Hu, J. S.; Wan, L. J. General space-confined on-substrate fabrication of thickness-adjustable hybrid perovskite single-crystalline thin films. J. Am. Chem. Soc. 2016, 138, 16196–16199.
Yao, F.; Peng, J. L.; Li, R. M.; Li, W. J.; Gui, P. B.; Li, B. R.; Liu, C.; Tao, C.; Lin, Q. Q.; Fang, G. J. Room-temperature liquid diffused separation induced crystallization for high-quality perovskite single crystals. Nat. Commun. 2020, 11, 1194.
Gui, P. B.; Zhou, H.; Yao, F.; Song, Z. H.; Li, B. R.; Fang, G. J. Space-confined growth of individual wide bandgap single crystal CsPbCl3 microplatelet for near-ultraviolet photodetection. Small 2019, 15, 1902618.
He, Y. H.; Stoumpos, C. C.; Hadar, I.; Luo, Z. Z.; McCall, K. M.; Liu, Z. F.; Chung, D. Y.; Wessels, B. W.; Kanatzidis, M. G. Demonstration of energy-resolved γ-ray detection at room temperature by the CsPbCl3 perovskite semiconductor. J. Am. Chem. Soc. 2021, 143, 2068–2077.
Li, X.; Liu, C.; Ding, F.; Lu, Z. Y.; Gao, P.; Huang, Z. W.; Dang, W. Q.; Zhang, L. Q.; Lin, X. H.; Ding, S. M. et al. Ultra-stable and sensitive ultraviolet photodetectors based on monocrystalline perovskite thin films. Adv. Funct. Mater. 2023, 33, 2213360.
Gu, Z. K.; Huang, Z. D.; Li, C.; Li, M. Z.; Song, Y. L. A general printing approach for scalable growth of perovskite single-crystal films. Sci. Adv. 2018, 4, 2390.
Chen, Y.; Zeng, H. B.; Ma, P. P.; Chen, G. Y.; Jian, J.; Sun, X.; Li, X. M.; Wang, H. Y.; Yin, W. J.; Jia, Q. X. et al. Overcoming the anisotropic growth limitations of free-standing single-crystal halide perovskite films. Angew. Chem., Int. Ed. 2021, 60, 2629–2636.
Bao, C. X.; Chen, Z. L.; Fang, Y. J.; Wei, H. T.; Deng, Y. H.; Xiao, X.; Li, L. L.; Huang, J. S. Low-noise and large-linear-dynamic-range photodetectors based on hybrid-perovskite thin-single-crystals. Adv. Mater. 2017, 29, 03209.
Lei, Y. S.; Chen, Y. M.; Zhang, R. Q.; Li, Y. H.; Yan, Q. Z.; Lee, S.; Yu, Y. G.; Tsai, H.; Choi, W.; Wang, K. P. et al. A fabrication process for flexible single-crystal perovskite devices. Nature 2020, 583, 790–795.
He, Y. H.; Matei, L.; Jung, H. J.; McCall, K. M.; Chen, M.; Stoumpos, C. C.; Liu, Z. F.; Peters, J. A.; Chung, D. Y.; Wessels, B. W. et al. High spectral resolution of gamma-rays at room temperature by perovskite CsPbBr3 single crystals. Nat. Commun. 2018, 9, 1609.
Pan, W. C.; Yang, B.; Niu, G. D.; Xue, K. H.; Du, X. Y.; Yin, L. X.; Zhang, M. Y.; Wu, H. D.; Miao, X. S.; Tang, J. Hot-pressed CsPbBr3 quasi-monocrystalline film for sensitive direct X-ray detection. Adv. Mater. 2019, 31, 1904405.
Yan, J.; Zheng, Q.; Wang, S. P.; Tian, Y. Z.; Gong, W. Q.; Gao, F.; Qiu, J. J.; Li, L.; Yang, S. H.; Cao, M. S. Multifunctional organic–inorganic hybrid perovskite microcrystalline engineering and electromagnetic response switching multi-band devices. Adv. Mater. 2023, 35, 2300015.
Li, X. C.; Meng, Y.; Li, W. P.; Zhang, J.; Dang, C. Q.; Wang, H. Y.; Hung, S. W.; Fan, R.; Chen, F. R.; Zhao, S. et al. Multislip-enabled morphing of all-inorganic perovskites. Nat. Mater. 2023, 22, 1175–1181.
Schweizer, P.; Sharma, A.; Pethö, L.; Huszar, E.; Vogl, L. M.; Michler, J.; Maeder, X. Atomic scale volume and grain boundary diffusion elucidated by in situ STEM. Nat. Commun. 2023, 14, 7601.
Yu, X. P.; Liu, Z. Z.; Yang, X. Y.; Wang, Y. D.; Zhang, J. H.; Duan, J. L.; Liu, L. M.; Tang, Q. W. Crystal-plane controlled spontaneous polarization of inorganic perovskite toward boosting triboelectric surface charge density. ACS Appl. Mater. Interfaces 2021, 13, 26196–26203.
Roknuzzaman, M.; Ostrikov, K.; Wang, H. X.; Du, A. J.; Tesfamichael, T. Towards lead-free perovskite photovoltaics and optoelectronics by ab- initio simulations. Sci. Rep. 2017, 7, 14025.
Jin, S.; Huang, M.; Kwon, Y.; Zhang, L. N.; Li, B. W.; Oh, S.; Dong, J. C.; Luo, D.; Biswal, M.; Cunning, B. V. et al. Colossal grain growth yields single-crystal metal foils by contact-free annealing. Science 2018, 362, 1021–1025.
Al-Handawi, M. B.; Dushaq, G.; Commins, P.; Karothu, D. P.; Rasras, M.; Catalano, L.; Naumov, P. Autonomous reconstitution of fractured hybrid perovskite single crystals. Adv. Mater. 2022, 34, 2109374.
Xue, J.; Zhu, Z. F.; Xu, X. B.; Gu, Y.; Wang, S. L.; Xu, L. M.; Zou, Y. S.; Song, J. Z.; Zeng, H. B.; Chen, Q. Narrowband perovskite photodetector-based image array for potential application in artificial vision. Nano Lett. 2018, 18, 7628–7634.
Li, Z. Q.; Yan, T. T.; Fang, X. S. Low-dimensional wide-bandgap semiconductors for UV photodetectors. Nat. Rev. Mater. 2023, 8, 587–603.
Fang, Y. J.; Armin, A.; Meredith, P.; Huang, J. S. Accurate characterization of next-generation thin-film photodetectors. Nat. Photonics 2018, 13, 1–4.
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