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Research Article | Open Access

Dielectric and electrical properties of Na2Pb2La2W2Ti4Ta4O30 electroceramics

P. R. DASa,*( ), S. BEHERAb, R. PADHEEa, P. NAYAKc, R.N.P. CHOUDHARYa
Department of Physics, Institute of Technical Education & Research,Siksha 'O' Anusandhan University, Bhubaneswar-751030, Odisha, India
Department of Physics, Hi-tech College Engineering, Bhubaneswar- 75102, Odisha, India
School of Physics, Sambalpur University, Jyoti Vihar, Burla -768019, Odisha, India
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Abstract

The polycrystalline sample of complex tungsten-bronze type compound (Na2Pb2La2W2Ti4Ta4O30 ) was prepared by a high-temperature solid-state reaction technique. Room temperature preliminary structural study using X-ray diffraction (XRD) data exhibits the formation of a single-phase new compound. The SEM micrograph of the compound exhibits non uniform rectangular grains distributed throughout the sample surface. Detailed studies of dielectric parameters (εr, tan δ) as a function of temperature and frequency, and P-E hysteresis (spontaneous polarization) confirmed the existence of ferroelectricity in the material. Complex impedance spectroscopy analysis, carried out as a function of frequency at different temperatures, established a correlation between the microstructure and electrical properties of the material. The electrical relaxation process occurring in the material is temperature dependent. The activation energy found from the Arrhenius plot that the conduction process in the material is of mixed type. The nature of frequency dependence of ac conductivity suggests that the material obeys Jonscher's universal power law.

Keywords

Key words: electronic materialferroelectricityXRDelectrical conductivity

References

[1]
Neurgaonkar RR, Nelson JG, Oliver JR, et al. Ferroelectric and structural properties of the tungsten bronze system K2Ln3+Nb5O15, Ln = La to Lu. Ma Res Bull 1990, 25: 959-970.
Crossref Google Scholar
[2]
Neurgaonkar RR, Cory WK, Ratnakar R. Progress in photorefractive tungstenbronze crystals. J Opt Soc Am B 1986, 3: 274-282.
Crossref Google Scholar
[3]
Wakiya N, Wang JK, Saiki A, et al. Synthesis and dielectric properties of Ba1−xR2x/3Nb2O6 (R: rare earth) with tetragonal tungsten bronze structure. J Eur Ceram Soc 1999, 19: 1071-1075.
Crossref Google Scholar
[4]
Goodman G. Ferroelectric properties of lead metaniobate. J Am Ceram Soc 1953, 36: 368-372.
Crossref Google Scholar
[5]
Francombe MH, Lewis B. Structural, dielectric and optical properties of ferroelectric lead metaniobate. Acta Crystallogr 1958, 11: 696-703.
Crossref Google Scholar
[6]
Smolenskii GA, Agranovskaya AI. Doklady Akademii Nauk SSSR 1954, 97: 237.
[7]
Glass AM. Ferroelectric Sr1-x BaxNb2O6 As a fast and sensitive detector of infrared radiation. Appl Phys Lett 1968, 13: 147-149.
Crossref Google Scholar
[8]
Sakamoto S, Yazaki T. Anomalous electro-optic properties of ferroelectric strontium barium niobate and device applications. Appl Phys Lett 1973, 22: 429-431.
Crossref Google Scholar
[9]
Haussonne JM, Desgardin G, Herve A, et al. Dielectric ceramics with relaxors and a tetragonal tungsten bronze. J Eur Ceram Soc 1992, 10: 437-452.
Crossref Google Scholar
[10]
Alaoui-Belghiti H El, Von der Miihll R, Simon A, et al. Relaxor or classical ferroelectric behavior in ceramics with composition Sr2−xA1+xNb5O15−xFx (A = Na, K). Mater Lett 2002, 55: 138-144.
Crossref Google Scholar
[11]
Chen XM, Xu ZY, Li J. Dielectric ceramics in BaO-Sm2O3-TiO2-Ta2O5 quaternary system. J Mater Res 2000, 15: 125-129.
Crossref Google Scholar
[12]
Das PR, Biswal L, Parida BN, et al. Diffuse ferroelectric phase transition in Na2Pb2Pr2W2Ti4Nb4O30 ceramic. Int J Mat Sc 2010, 5: 759-767.
Google Scholar
[13]
Das PR, Behera S, Nayak P. Structural and ferroelectric properties of
[14]
Na2Pb2Nd2W2Ti4Ta4O30 ceramic. AIP Conf Proc 2011, 1372: 33-40.
Google Scholar
[15]
Das PR, Behera S, Nayak P. Structural and dielectric properties of Na2Pb2Sm2W2Ti4Ta4O30 ferroelectric ceramics. Int J Mat Sc 2010, 5: 739-746.
Google Scholar
[16]
Pradhan DK, Behera B, Das PR. Studies of dielectric and electrical properties of a new type of complex tungsten bronze electro ceramics. J Mater Sci: Mater Electron 2012, 23: 779-785.
Crossref Google Scholar
[17]
Parida BN, Das PR, Padhee R, et al. A new ferroelectric oxide Li2Pb2Pr2W2Ti4Nb4O30: Synthesis and characterization, J Phys Chem Solids 2012, 73: 713-719.
Crossref Google Scholar
[18]
Das Piyush R, Pati B, Sutar BC, et al. Electrical properties of complex tungsten bronze ferroelectrics: Na2Pb2R2W2Ti4V4O30 (R = Gd, Eu). Adv Mat Lett 2012, 3: 8-14.
Crossref Google Scholar
[19]
Parida BN, Das Piyush R, Padhee R, et al. Synthesis and chracterization of a tungsten bronze ferroelectric oxide. Adv Mat Lett 2012, 3: 231-238.
Crossref Google Scholar
[20]
Lines ME, Glass AM. Principle and Applications of Ferroelectrics and Related Materials. Oxford: Clarndon Press, 1977.
[21]
Das PR, Biswal L, Behera B, et al. Structural and electrical properties of Na2Pb2Eu2W2Ti4X4O30 (X = Nb, Ta) ferroelectric ceramics. Mater Res Bull 2009, 44: 1214-1218.
Crossref Google Scholar
[22]
Massarotti V, Capsoni D, Bini M, et al. Structural and spectroscopic properties of pure and doped Ba6Ti2Nb8O30 tungsten bronze. J Phys Chem B 2006, 110: 17798-17805.
Crossref Google Scholar
[23]
Ganguly P, Jha AK, Deori KL. Complex impedance studies of tungsten-bronze structured Ba5SmTi3Nb7O30ferroelectric ceramics. Solid State Comm 2008,146: 472-477.
Crossref Google Scholar
[24]
Das Piyush R, Choudhary RNP, Samantray BK. Diffuse ferroelectric phase transition in Na2Pb2Sm2W2Ti4 Nb4O30 ceramics. Mat Chem Phy 2007, 101: 228-233.
Crossref Google Scholar
[25]
Das Piyush R, Behera B, Choudhary RNP, et al. Ferroelectric properties of Na2Pb2R2W2Ti4V4O30 (R= Dy, Pr) ceramics. Res Lett Mat Sci 2007, ID: 91796.
Google Scholar
[26]
Behera B, Nayak P, Choudhary RNP. Structural, dielectric and electrical properties of LiBa2X5O15 (X= Nb and Ta) ceramics. Mat Chem Phys 2006, 100: 138-141.
Crossref Google Scholar
[27]
Das Piyush R, Choudhary RNP, Samantray BK. Diffuse phase transition in Na2Pb2R2W2Ti4V4O30 (R=Gd, Eu) ferroelectric ceramics. J Phys Chem Solids 2007, 68: 516-522.
Crossref Google Scholar
[28]
Behera B, Nayak P, Choudhary RNP. Studies of dielectric and impedance properties of KCa2V5O15 ceramics. J Phys Chem Solids 2008, 69: 1990-1995.
Crossref Google Scholar
[29]
Wu PE. An interactive powder diffraction data interpretation and indexing Program, Ver. 2.5, School of Physical Sciences, Finders University of South Australia Bedford Park, S.A. 5042, Australia.
[30]
Anderson JC. Dielectrics. London: Chapman and Hall, 1964.
[31]
Padhee R, Das PR, Parida BN, et al. Structural, dielectric and electrical properties of dysprosium based new complex electro ceramics. J Mat Sci: Mater Electron 2012, 23: 1688-1697.
Crossref Google Scholar
[32]
Pilgrim SM, Sutherland AE, Winzer SR. Diffuseness as a useful parameter for relaxor ceramics. J Amer Ceram Soc 1990, 73: 3122-3125.
Crossref Google Scholar
[33]
Clarke R, Burfoot JC. The diffuse phase transition in potassium strontium niobate. Ferroelectrics 1974, 8: 505-506.
Crossref Google Scholar
[34]
Suman CK, Prasad K, Choudhary RNP. Complex impedance studies on tungsten-bronze electro ceramic: Pb2Bi3LaTi5O18. J Mater Sci 2006, 41: 369-375.
Crossref Google Scholar
[35]
Suman CK, Prasad K, Choudhary RNP. Electrical properties of Pb2Bi3NdTi5O18 ceramic. Mat Chem Phys 2003, 82: 140-144.
Crossref Google Scholar
[36]
Kroger FA, Vink HJ. Relations between the concentrations of imperfections in crystalline. Solids Solid State Phys 1956, 3: 307-435.
Crossref Google Scholar
[37]
Raghavan V. Materials Science and Engineering. New Delhi: Prentice-Hall of India, 2004.
[38]
Macdonald JR. Impedance Spectroscopy. New York: Wiley, 1987.
Crossref
[39]
Jonscher AK. The 'universal' dielectric response. Nature 1977, 267: 673-679.
Crossref Google Scholar
[40]
Sen S, Choudhary RNP. Impedance studies of Sr modified BaZr0.05 Ti0.95O3 ceramics. Mater Chem Phys 2004, 87: 256-263.
Crossref Google Scholar
[41]
Kim JS, Kim JN. Impedance spectra near the phase transition temperature of potassium lithium niobate crystals. Jpn J Appl Phys 2000, 39: 3502-3505.
Crossref Google Scholar
[42]
Lu Z, Bonnet JP, Ravez J, et al. An impedance study of Pb2KNb5O15 ferroelectric ceramics. Phys Chem Solids 1992, 53: 1-9.
Crossref Google Scholar
[43]
Jonscher AK. Dielectric Relaxation in Solids. London: Chelesa Dielectric Press, 1983.
[44]
Dissado LA, Hill RH. Non-exponential decay in dielectrics and dynamics of correlated systems. Nature 1979, 279: 685-689.
Crossref Google Scholar
[45]
Dissado LA, Hill RM. Dielectric behaviour of materials undergoing dipole alignment transitions. Phill Mag B 1980, 41: 625-642.
Crossref Google Scholar
[46]
Yeum B. Z SimpWin Version 2.00, Echem Software Ann Arbor, MI, USA.
[47]
Irvine TS, Sinclair DC, West AR. Electroceramics: Characterization by impedance spectroscopy. Adv Mater 1990, 2: 132-138.
Crossref Google Scholar
[48]
Nobre MAL, Lanfredi S. Ferroelectric state analysis in grain boundary of Na0.85Li0.15NbO3 ceramic. J Appl Phy 2003, 93: 5557-5562.
Crossref Google Scholar
[49]
Macdonald JR. Note on the parameterization of the constant-phase admittance element. Solid state Ionics 1984, 13: 47-149.
Crossref Google Scholar
[50]
West AR, Sinclair DC, Hirose N. Characterization of electrical materials, especially ferroelectrics, by impedance spectroscopy. J Electro Ceram 1997, 1: 65-71.
Crossref Google Scholar
[51]
Choudhary RNP, Pradhan DK, Tirado CM, et al. Effect of La-substitution on structural and electrical properties of Ba(Fe2/3W1/3)O3 nanoceramics. J Mater Sci 2007, 42: 7423-7432.
Crossref Google Scholar
[52]
Deng G, Li G, Ding A, et al. Evidence for oxygen vacancy inducing spontaneous normal-relaxor transition in complex perovskite ferroelectrics. Appl Phys Lett 2005, 87: 192905-192908.
Crossref Google Scholar
[53]
Molak A, Talik E, Kruczek M, et al. Characterisation of Pb(Mn1/3Nb2/3)O3 ceramics by SEM, XRD, XPS and dielectric permittivity tests. Mater Sci Eng B 2006, 128: 16-24.
Crossref Google Scholar
[54]
Jonscher AK. Dielectric Relaxation in Solids. London: Chelsea Dielectric Press, 1983.
Journal of Advanced Ceramics
Volume 1 Issue 3,
September 2012
Pages 232-240
DOI: 10.1007/s40145-012-0024-y
Cite this article:
DAS PR, BEHERA S, PADHEE R, et al. Dielectric and electrical properties of Na2Pb2La2W2Ti4Ta4O30 electroceramics. Journal of Advanced Ceramics, 2012, 1(3): 232-240. https://doi.org/10.1007/s40145-012-0024-y

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Received: 23 August 2012
Accepted: 06 October 2012
Published: 11 December 2012
© The author(s) 2012
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