AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (2.4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Substitution of a fraction of zircon by cristobalite in nano hematite encapsulated pigment and examination of glaze application

Department of Inorganic Pigments and Glazes, Institute for Color Science and Technology (ICST), P.O. Box 1668814811, Tehran, Iran
Show Author Information

Abstract

Hematite pigment has a long history, but it cannot be used for ceramic application, because it must be thermally and chemically stable at high firing temperature when using a pigment in a glaze or ceramic body. Recently, through encapsulated systems, a new pigment with suitable thermal and chemical stability can be obtained by encapsulating hematite crystals into selected silica or zircon matrices. It means that nano-sized red hematite has been encapsulated into the protected phases. Transmission electron micrographs of hematite encapsulated into silica and zircon matrices by sol–gel method show spherical single crystals with diameter of about 5–10 nm. In order to optimize ceramic glaze formulations for application of the synthesized red inorganic nanocomposite inclusion pigment by sol–gel method, four different types of glazes (i.e., alkalis, borate, earth alkalis, and leaded glazes) have been tested. The results show that the substitution of a fraction of zircon by cristobalite in hematite-zircon pigment produces acceptable stability with red hue.

Keywords

nano hematiteinclusion pigmentzirconsilicaceramic glaze

References

[1]
Bondioli F, Ferrari AM, Leonelli C, et al. Synthesis of Fe2O3/silica red inorganic inclusion pigments for ceramic application. Mater Res Bull 1998, 33: 723–729.
Crossref Google Scholar
[2]
Candeia RA, Bernardi MIB, Longo E, et al. Synthesis and characterization of spinel pigment CaFe2O4 obtained by the polymeric precursor method. Mater Lett 2004, 58: 569–572.
Crossref Google Scholar
[3]
Sorlı́ S, Tena MA, Badenes JA, et al. Structure and color of NixA1-3xB2xO2 (A=Ti, Sn; B=Sb, Nb) solid solutions. J Eur Ceram Soc 2004, 24: 2425–2432.
Crossref Google Scholar
[4]
Harisanov V, Pavlov RS, Marinova IT, et al. Influence of crystallinity on chromatic parameters of enamels coloured with malayaite pink pigments. J Eur Ceram Soc 2003, 23: 429–435.
Crossref Google Scholar
[5]
Hosseini-Zori M, Taheri-Nassaj E, Mirhabibi AR. Effective factors on synthesis of the hematite–silica red inclusion pigment. Ceram Int 2008, 34: 491–496.
Crossref Google Scholar
[6]
Bondioli F, Manfredini T, Siligardi C, et al. A new glass–ceramic red pigment. J Eur Ceram Soc 2004, 24: 3593–3601.
Crossref Google Scholar
[7]
Hosseini-Zori M. Synthesis of inclusion nano composite as a non toxic red ceramic pigment by sol–gel method. In Ceramic Transactions Volume 210: Ceramic Materials Components for Energy and Environmental Applications. Jiang DL, Zeng YP, Singh M, et al. Eds. Hoboken: John Wiley & Sons, 2010: 60–65.
Crossref
[8]
Hosseini-Zori M, Bondioli F, Manfredini T, et al. Effect of synthesis parameters on hematite–silica red pigment obtained using a coprecipitation route. Dyes Pigments 2008, 77: 53–58.
Crossref Google Scholar
[9]
Bondioli F, Manfredini T. The search for new red pigments. Am Ceram Soc Bull 2000, 79: 68–70.
Google Scholar
[10]
Vicent JB, Llusar M, Badenes J, et al. Occlusion of chromophore oxides by sol–gel methods: Application to the synthesis of hematite–silica red pigments. Bol Soc Esp Cerám Vidrio 2000, 39: 83–93.
Crossref Google Scholar
[11]
Hosseini-Zori M, Taheri-Nassaj E. Nano encapsulation of hematite into silica matrix as a red inclusion ceramic pigment. J Alloys Compd 2012, 510: 83–86.
Crossref Google Scholar
[12]
Hradil D, Grygar T, Hradilová J, et al. Clay and iron oxide pigments in the history of painting. Appl Clay Sci 2003, 22: 223–236.
Crossref Google Scholar
[13]
Dondi M, Matteucci F, Cruciani G. Zirconium titanate ceramic pigments: Crystal structure, optical spectroscopy and technological properties. J Solid State Chem 2006, 179: 233–246.
Crossref Google Scholar
[14]
Llusar M, Badenes JA, Calbo J, et al. Environmental and colour optimisation of mineraliser addition in synthesis of iron zircon ceramic pigment. Br Ceram Trans 2000, 99: 14–22.
Crossref Google Scholar
[15]
Bondioli F, Manfredini T, Siligardi C, et al. New glass–ceramic inclusion pigment. J Am Ceram Soc 2005, 88: 1070–1071.
Crossref Google Scholar
[16]
Ricceri R, Ardizzone S, Baldi G, et al. Ceramic pigments obtained by sol–gel techniques and by mechanochemical insertion of color centers in Al2O3 host matrix. J Eur Ceram Soc 2002, 22: 629–637.
Crossref Google Scholar
[17]
Garcia A, Llusar M, Badenes J, et al. Encapsulation of hematite in zircon by microemulsion and sol–gel methods. J Sol–Gel Sci Technol 2003, 27: 267–275.
Crossref Google Scholar
[18]
Nero GD, Cappelletti G, Ardizzone S, et al. Yellow Pr–zircon pigments the role of praseodymium and of the mineralizer. J Eur Ceram Soc 2004, 24: 3603–3611.
Crossref Google Scholar
[19]
Garcı́a A, Llusar M, Sorlı́ S, et al. Effect of the surfactant and precipitant on the synthesis of pink coral by a microemulsion method. J Eur Ceram Soc 2003, 23: 1829–1838.
Crossref Google Scholar
[20]
Hosseini-Zori M. Synthesis of the new ternary nano composite pigment of hematite–zircon–silica by sol–gel method. Iran Patent PV 49877, 2008.
[21]
Katsuki H, Komarneni S. Role of α-Fe2O3 morphology on the color of red pigment for porcelain. J Am Ceram Soc 2003, 86: 183–185.
Crossref Google Scholar
[22]
Gualtieri AF. Natural red pigment for single-fired ceramic glaze. Ceram Bull 2002, 81: 48–52.
Google Scholar
Journal of Advanced Ceramics
Volume 2 Issue 2,
June 2013
Pages 149-156
DOI: 10.1007/s40145-013-0054-0
Cite this article:
HOSSEINI-ZORI M. Substitution of a fraction of zircon by cristobalite in nano hematite encapsulated pigment and examination of glaze application. Journal of Advanced Ceramics, 2013, 2(2): 149-156. https://doi.org/10.1007/s40145-013-0054-0

911

Views

29

Downloads

5

Crossref

N/A

Web of Science

8

Scopus

0

CSCD

Altmetrics
Received: 14 January 2013
Revised: 24 February 2013
Accepted: 14 March 2013
Published: 04 June 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
Return