AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (388.1 KB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Transport and physical properties of V2O5–P2O5–B2O3 glasses doped with Dy2O3

R. V. BARDEa, S. A. WAGHULEYb,*( )
Department of Engineering Physics, Shri Hanuman Vyayam Prasarak Mandal’s College of Engineering and Technology, Amravati 444 605, India
Department of Physics, Sant Gadge Baba Amravati University, Amravati 444 602, India
Show Author Information

Abstract

We investigate the DC transport properties of 60V2O5–5P2O5–(35-x)B2O3–xDy2O3 (x = 0.4, 0.6, 0.8, 1.0 and 1.2 mol%) glasses as function of temperature which were prepared using the conventional melt-quenching method. These glasses are characterised by thermo gravimetric-differential thermal analysis (TG-DTA). Activation energy (EDC) is obtained from Arrhenius plots of temperature-dependent DC conductivity, and it is found to be 0.30 eV for high conducting glass. In order to understand the role of Dy2O3 in these glasses, the density and molar volume are investigated. The results show that molar volume of the glass increases with the increasing of Dy2O3 concentration. The ionic conductivity is found to be dominant over the electronic conductivity and varies between 82% and 96%.

Keywords

transport propertiesmelt quenchingArrhenius plotglasses

References

[1]
Al-Hajry A, Soliman AA, El-Desoky MM. Electrical and thermal properties of semiconducting Fe2O3–Bi2O3–Na2B4O7 glasses. Thermochim Acta 2005, 427: 181-186.
Crossref Google Scholar
[2]
El-Desoky MM, Al-Shahrani A. Variable—Range hopping in Fe2O3–Bi2O3–K2B4O7 glasses. J Mater Sci: Mater El 2005, 16: 221-224.
Crossref Google Scholar
[3]
Al-Hajry A, Tashtoush N, El-Desoky MM. Characterization and transport properties of semiconducting Fe2O3–Bi2O3–Na2B4O7 glasses. Physica B 2005, 368: 51-57.
Crossref Google Scholar
[4]
Saddeek YB, Shaaban ER, Aly KA, et al. Characterization of some lead vanadate glasses. J Alloys Compd 2009, 478: 447-452.
Crossref Google Scholar
[5]
El-Desoky MM. Small polaron transport in V2O5–NiO–TeO2 glasses. J Mater Sci: Mater El 2003, 14: 215-221.
Crossref Google Scholar
[6]
Al-Shahrani A, Al-Hajry A, El-Desoky MM. Non-adiabatic small polaron hopping conduction in sodium borate tungstate glasses. Phys Status Solidi a 2003, 200: 378-387.
Crossref Google Scholar
[7]
El-Desoky MM, Tashtoush NM, Habib MH. Characterization and electrical properties of semiconducting Fe2O3–Bi2O3–K2B4O7 glasses. J Mater Sci: Mater El 2005, 16: 533-539.
Crossref Google Scholar
[8]
El-Desoky MM, Al-Hajry A, Tokunaga M, et al. Effect of sulfur addition on the redox state of iron in iron phosphate glasses. Hyperfine Interact 2004, 156–157: 547-553.
Crossref Google Scholar
[9]
Mahmoud KH, Abdel-Rahim FM, Atef K, et al. Dielectric dispersion in lithim–bismuth–borate glasses. Curr Appl Phys 2011, 11: 55-60.
Crossref Google Scholar
[10]
Terczynska-Madej A, Cholewa-Kowalska K, Laczka M. The effect of silicate network modifiers on colour and electron spectra of transition metal ions. Opt Mater 2010, 32: 1456-1462.
Crossref Google Scholar
[11]
Venkat Reddy P, Laxmi Kanth C, Prasanth Kumar V, et al. Optical and thermoluminescence properties of R2O–RF–B2O3 glass systems doped with MnO. J Non-Cryst Solids 2005, 351: 3752-3759.
Crossref Google Scholar
[12]
Ramesh Babu A, RajyaSree C, Srinivasa Rao P, et al. Vanadyl ions influence on spectroscopic and dielectric properties of glass network. J Mol Struct 2011, 1005: 83-90.
Crossref Google Scholar
[13]
Ramesh Babu A, RajyaSree C, Vinaya Teja PM, et al. Influence of manganese ions on spectroscopic and dielectric properties of LiF–SrO–B2O3 glasses. J Non-Cryst Solids 2012, 358: 1391-1398.
Crossref Google Scholar
[14]
Srinivasa Rao P, Bala Murali Krishna S, Yusub S, et al. Spectroscopic and dielectric investigations of tungsten ions doped zinc bismuth phosphate glass-ceramics. J Mol Struct 2013, 1036: 452-463.
Crossref Google Scholar
[15]
Takahashi H, Karasawa T, Sakuma T, et al. Electrical conduction in the vitreous and crystallized Li2O–V2O5–P2O5 system. Solid State Ionics 2010, 181: 27-32.
Crossref Google Scholar
[16]
Kiran N, Kesavulu CR, Suresh Kumar A, et al. Spectral studies on Cr3+ ions doped in sodium–lead borophosphate glasses. Physica B 2011, 406: 1897-1901.
Crossref Google Scholar
[17]
Kim CE, Hwang HC, Yoon MY, et al. Fabrication of a high lithium ion conducting lithium borosilicate glass. J Non-Cryst Solids 2011, 357: 2863-2867.
Crossref Google Scholar
[18]
Pisarski WA, Goryczka T, Wodecka-Dus B, et al. Structure and properties of rare earth-doped lead borate glasses. Mat Sci Eng B 2005, 122: 94-99.
Crossref Google Scholar
[19]
Qiu J, Igarashi H, Makishima A. Long-lasting phosphorescence in Mn2+:Zn2GeO4 crystallites containing transparent GeO2–B2O3–ZnO glass-ceramics. Sci Technol Adv Mater 2005, 6: 431-434.
Crossref Google Scholar
[20]
Barde RV, Waghuley SA. Study of AC electrical properties of V2O5–P2O5–B2O3–Dy2O3 glasses. Ceram Int 2013, 39: 6303-6311.
Crossref Google Scholar
[21]
Yoon HJ, Jun DH, Yang JH, et al. Carbon dioxide gas sensor using a graphene sheet. Sensor Actuat B: Chem 2011, 157: 310-313.
Crossref Google Scholar
[22]
Sekhon SS, Chandra S. Mixed cation effect in silver borate ion conducting glass. J Mater Sci 1999, 34: 2899-2902.
Crossref Google Scholar
[23]
Das SS, Srivastava V, Singh P. Ionic transport sodium phosphate glasses doped with chloride of Co, Cd and Ag. Indian J Eng Mater Sci 2006, 13: 455-461.
Google Scholar
[24]
Sheha E. Ionic conductivity and dielectric properties of plasticized PVA0.7(LiBr)0.3(H2SO4)2.7M solid acid membrane and its performance in a magnesium battery. Solid State Ionics 2009, 180: 1575-1579.
Crossref Google Scholar
[25]
Reddy J, Ramesh Ch, Kumar S, et al. Conductivity study of PEO complex with Mg2+ borate glass polymer electrolyte—Its application as electrochemical cell. Int J Appl Engng Res Dindigul 2011, 2: 147-156.
Google Scholar
[26]
Govindaraj G, Mariappan CR. Synthesis, characterization and ion dynamic studies of NASICON type glasses. Solid State Ionics 2002, 147: 49-59.
Crossref Google Scholar
[27]
Abid M, Et-tabirou M, Taibi M. Structure and DC conductivity of lead sodium ultraphosphate glasses. Mat Sci Eng B 2003, 97: 20-24.
Crossref Google Scholar
[28]
Mansour E, El-Damrawi GM, Moustafa YM, et al. Polaronic conduction in barium borate glasses containing iron oxide. Physica B 2001, 293: 268-275.
Crossref Google Scholar
[29]
Ramadevudu G, Laxmi Srinivasa Rao S, Hameed A, et al. FTIR and some physical properties of alkaline earth borate glasses containing heavy metal oxides. Int J Eng Sci Tech 2011, 3: 6998-7005.
Google Scholar
[30]
Insiripong S, Chimalawong P, Kaewkhao J, et al. Optical and physical properties of bismuth borate glasses doped with Dy3+. Am J Applied Sci 2011, 8: 574-578.
Crossref Google Scholar
[31]
Bale S, Rahman S. Spectroscopic and physical properties of Bi2O3–B2O3–ZnO–Li2O glasses. Int Sch Res Netw Spectrosc 2012, .
Crossref Google Scholar
[32]
Gedam RS, Deshpande VK. An anomalous enhancement in the electrical conductivity of Li2O: B2O3:Al2O3 glasses. Solid State Ionics 2006, 177: 2589-2592.
Crossref Google Scholar
[33]
Alexander MN, Onorato PIK, Struck CW, et al. Structure of alkali (alumino) silicate glasses: I. Tl+ luminescence and the nonbridging oxygen issue. J Non-Cryst Solids 1986, 79: 137-154.
Crossref Google Scholar
[34]
El-Desoky MM, Ibrahim FA, Mostafa AG, et al. Effect of nanocrystallization on the electrical conductivity enhancement and Mössbauer hyperfine parameters of iron based glasses. Mater Res Bull 2010, 45: 1122-1126.
Crossref Google Scholar
[35]
Abid M, Et-tabirou M, Taibi M. Structure and DC conductivity of lead sodium ultraphosphate glasses. Mat Sci Eng B 2003, 97: 20-24.
Crossref Google Scholar
[36]
Abdel-Baki M, El-Diasty F. Role of oxygen on the optical properties of borate glass doped with ZnO. J Solid State Chem 2011, 184: 2762-2769.
Crossref Google Scholar
[37]
Veeranna Gowda VC, Anavekar RV. Elastic properties and spectroscopic studies of lithium lead borate glasses. Ionics 2004, 10: 103-108.
Crossref Google Scholar
[38]
Silim HA. Composition effect on some physical properties and FTIR spectra of alumino–borate glasses containing lithium, sodium, potassium and barium oxides. Egypt J Solids 2006, 29: 293-301.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 2 Issue 3,
September 2013
Pages 246-251
DOI: 10.1007/s40145-013-0067-8
Cite this article:
BARDE RV, WAGHULEY SA. Transport and physical properties of V2O5–P2O5–B2O3 glasses doped with Dy2O3. Journal of Advanced Ceramics, 2013, 2(3): 246-251. https://doi.org/10.1007/s40145-013-0067-8

958

Views

25

Downloads

17

Crossref

N/A

Web of Science

19

Scopus

0

CSCD

Altmetrics
Received: 26 February 2013
Revised: 02 April 2013
Accepted: 26 April 2013
Published: 07 September 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
Return