Home Journal of Advanced Ceramics Article
PDF (851.9 KB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Research Article | Open Access

Preparation of titanium phosphate white pigments with titanium sulfate and their powder properties

Hiroaki ONODAa(), Syohei FUJIKADOa, Takeshi TOYAMAb
Department of Informatics and Environmental Sciences, Kyoto Prefectural University, 1-5, Shimogamo Nakaragi-cyo, Sakyo-ku, Kyoto 606-8522, Japan
Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, 1-8-14 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan
Show Author Information

Abstract

Titanium oxide that has photocatalytic activity is used as white pigment for cosmetics. A certain degree of sebum on the skin is decomposed by the ultraviolet radiation in sunlight. In this work, as novel white pigment, titanium phosphates were synthesized with titanium sulfate and phosphoric acid for cosmetics. Their chemical composition, powder properties, photocatalytic activity, color phase, moisture retention, and smoothness were studied. These titanium phosphates had less photocatalytic activity to protect the sebum on the skin. Samples without heating and those heated at 100 ℃ showed high reflectance in the range of visible light. Sample prepared in Ti/P = 3/2 had higher moisture retention than samples prepared in other Ti/P ratios.

Keywords

white pigmenttitanium phosphatesphotocatalytic activitysmoothness

References

[1]
Diebold U. The surface science of titanium dioxide. Surf Sci Rep 2003, 48: 53–229.
Crossref Google Scholar
[2]
Senzui M, Tamura T, Miura K, et al. Study on penetration of titanium dioxide (TiO2) nanoparticles into intact and damaged skin in vitro. J Toxicol Sci 2010, 35: 107–113.
Crossref Google Scholar
[3]
Sarkar K, Nandi M, Bhaumik A. Enhancement in microporosity and catalytic activity on grafting silica and organosilica moieties in lamellar titanium phosphate framework. Appl Catal A: Gen 2008, 343: 55–61.
Crossref Google Scholar
[4]
Gamer AO, Leibold E, van Ravenzwaay B. The in vitro absorption of microfine zinc oxide and titanium dioxide through porcine skin. Toxicol in Vitro 2006, 20: 301–307.
Crossref Google Scholar
[5]
Jones DJ, Aptel G, Brandhorst M, et al. High surface area mesoporous titanium phosphate: Synthesis and surface acidity determination. J Mater Chem 2000, 10: 1957–1963.
Crossref Google Scholar
[6]
Bhaumik A, Inagaki S. Mesoporous titanium phosphate molecular sieves with ion-exchange capacity. J Am Chem Soc 2001, 123: 691–696.
Crossref Google Scholar
[7]
Dutta A, Patra AK, Dutta S, et al. Hierarchically porous titanium phosphate nanoparticles: An efficient solid acid catalyst for microwave assisted conversion of biomass and carbohydrates into 5-hydroxymethylfurfural. J Mater Chem 2012, 22: 14094–14100.
Crossref Google Scholar
[8]
Onoda H, Yamaguchi T. Influence of ultrasonic treatment on preparation and powder properties of titanium phosphates. J Mater Chem 2012, 22: 19826–19830.
Crossref Google Scholar
[9]
Onoda H, Yamaguchi T, Takenaka A. Synthesis and pigmental properties of titanium phosphates with the addition of urea. Int J Cosmetic Sci 2012, 34: 86–90.
Crossref Google Scholar
[10]
Ramaswamy V, Jagtap NB, Vijayanand S, et al. Photocatalytic decomposition of methylene blue on nanocrystalline titania prepared by different methods. Mater Res Bull 2008, 43: 1145–1152.
Crossref Google Scholar
[11]
Du P, Bueno-López A, Verbaas M, et al. The effect of surface OH-population on the photocatalytic activity of rare earth-doped P25-TiO2 in methylene blue degradation. J Catal 2008, 260: 75–80.
Crossref Google Scholar
[12]
Cheng SY, Yuen CWM, Kan CW, et al. A comprehensive study of silicone-based cosmetic textile agent. Fiber Polym 2009, 10: 132–140.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 3 Issue 2,
June 2014
Pages 132-136
DOI: 10.1007/s40145-014-0103-3
Cite this article:
ONODA H, FUJIKADO S, TOYAMA T. Preparation of titanium phosphate white pigments with titanium sulfate and their powder properties. Journal of Advanced Ceramics, 2014, 3(2): 132-136. https://doi.org/10.1007/s40145-014-0103-3
Metrics & Citations  
Article History
Copyright
Rights and Permissions
Return