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Research Article | Open Access

Preparation, crystallization, microstructure and dielectric properties of lead bismuth titanate borosilicate glass ceramics

Chandkiram R. GAUTAMa( ), Abhishek MADHESHIYAa, Ranabrata MAZUMDERb
Advanced Glass and Glass Ceramic Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, India
Department of Ceramic Engineering, National Institute of Technology, Rouerkela 769008, India
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Abstract

Various bulk and transparent glasses were prepared by rapid melt quenching technique in the glass system 55[(PbxBi1-x)TiO3]–44[2SiO2B2O3]–La2O3 (x = 0–0.7). The X-ray diffraction (XRD) studies of the glass samples confirmed the amorphous nature. The differential thermal analyses (DTA) were carried out from room temperature to 900 ℃ with a heating rate of 10 ℃/min. The DTA patterns of the samples showed one or more exothermic sharp peaks shifting towards lower temperature side with increasing concentration of bismuth oxide (BiO). On the basis of DTA results, the solid solution of bismuth titanum oxide (Bi2Ti2O7)/lead bismuth titanium oxide (Pb3Bi4Ti6O21) was precipitated in borosilicate glassy matrix as a major phase. The glasses were subjected to 4 h and 8 h heat treatment schedules to convert into glass ceramics. XRD analysis of these glass ceramic samples showed that the major crystalline phase of the entire glass ceramic samples with 0 ≤ x ≤ 0.5 is found to have cubic crystal structure, while it is tetragonal for glass ceramic sample with x = 0.7. The scanning electron microscopy (SEM) micrographs indicated the uniform distribution of Bi2Ti2O7 and Pb3Bi4Ti6O21 crystallites in the glassy matrix.

Keywords

lead bismuth titanatedifferential thermal analysis (DTA)crystallizationscanning electron microscopy (SEM)dielectric behavior

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Journal of Advanced Ceramics
Volume 3 Issue 3,
September 2014
Pages 194-206
DOI: 10.1007/s40145-014-0110-4
Cite this article:
GAUTAM CR, MADHESHIYA A, MAZUMDER R. Preparation, crystallization, microstructure and dielectric properties of lead bismuth titanate borosilicate glass ceramics. Journal of Advanced Ceramics, 2014, 3(3): 194-206. https://doi.org/10.1007/s40145-014-0110-4

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Received: 10 April 2014
Revised: 15 May 2014
Accepted: 28 May 2014
Published: 02 September 2014
© The author(s) 2014

Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
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