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Research Article | Open Access

Phase evolution, microstructure, electric properties of (Ba1-xBi0.67xNa0.33x)(Ti1-xBi0.33xSn0.67x)O3 ceramics

Xiuli CHEN( ), Xu LI, Huanfu ZHOU, Jie SUN, Xiaoxia LI, Xiao YAN, Congcong SUN, Junpeng SHI
Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi, Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, School of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
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Abstract

(Ba1-xBi0.67xNa0.33x)(Ti1-xBi0.33xSn0.67x)O3 (abbreviated as BBNTBS, 0.02 ≤ x ≤ 0.12) ceramics were fabricated via a traditional solid state reaction method. The phase transition of BBNTBS from tetragonal to pseudo cubic is demonstrated by XRD and Raman spectra. The BBNTBS (x = 0.1) ceramics have decent properties with a high εr (~2250), small Δε/ε25°C values of ±15% over a wide temperature range from -58 to 171 ℃, and low tanδ ≤ 0.02 from 10 to 200 ℃. The basic mechanisms of conduction and relaxation processes in the high temperature region were thermal activation, and oxygen vacancies might be the ionic charge transport carriers. Meanwhile, BBNTBS (x = 0.1) exhibited decent energy storage density (Jd = 0.58 J/cm3) and excellent thermal stability (the variation of Jd is less than 3% in the temperature range of 25-120 ℃), which could be a potential candidate for high energy density capacitors.

Keywords

structurethermal stabilityenergy storage

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References

[1]
A Zeb, SJ Milne. High temperature dielectric ceramics: A review of temperature-stable high-permittivity perovskites. J Mater Sci: Mater Electron 2015, 26: 9243-9255.
Crossref Google Scholar
[2]
G Singh, VS Tiwari. Electro-caloric effect in relaxor and ferroelectric compositions of Pb(Mg(1-x)/3Nb2(1-x)/3Zrx)O3 ceramics. J Alloys Compd 2012, 523: 30-35.
Crossref Google Scholar
[3]
RE Eitel, CA Randall, TR Shrout, et al. New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics. Jpn J Appl Phys 2001, 40: 5999-6002.
Crossref Google Scholar
[4]
X Li, XL Chen, HF Zhou, et al. Phase evolution, microstructure, thermal stability and conductivity behavior of (Ba1-xBi0.67xK0.33x)(Ti1-xBi0.33xSn0.67x)O3 solid solutions ceramics. J Alloys Compd 2019, 777: 1066-1073.
Crossref Google Scholar
[5]
XL Chen, J Chen, DD Ma, et al. High relative permittivity, low dielectric loss and good thermal stability of BaTiO3-Bi(Mg0.5Zr0.5)O3 solid solution. Ceram Int 2015, 41: 2081-2088.
Crossref Google Scholar
[6]
H Ogihara, CA Randall, S Trolier-Mckinstry. High-energy density capacitors utilizing 0.7BaTiO3-0.3BiScO3 ceramics. J Am Ceram Soc 2009, 92: 1719-1724.
Crossref Google Scholar
[7]
QB Yuan, FZ Yao, YF Wang, et al. Relaxor ferroelectric 0.9BaTiO3-0.1Bi(Zn0.5Zr0.5)O3 ceramic capacitors with high energy density and temperature stable energy storage properties. J Mater Chem C 2017, 5: 9552-9558.
Crossref Google Scholar
[8]
J Wang, SL Jiang, D Jiang, et al. Microstructural design of BaTiO3-based ceramics for temperature-stable multilayer ceramic capacitors. Ceram Int 2012, 38: 5853-5857.
Crossref Google Scholar
[9]
QB Yuan, G Li, FZ Yao, et al. Simultaneously achieved temperature-insensitive high energy density and efficiency in domain engineered BaTiO3-Bi(Mg0.5Zr0.5)O3 lead-free relaxor ferroelectrics. Nano Energy 2018, 52: 203-210.
Crossref Google Scholar
[10]
LW Wu, XH Wang, ZB Shen, et al. Ferroelectric to relaxor transition in BaTiO3-Bi(Zn2/3Nb1/3)O3 ceramics. J Am Ceram Soc 2017, 100: 265-275.
Crossref Google Scholar
[11]
K Wang, JF Li. Low-temperature sintering of Li-modified (K,Na)NbO3 lead-free ceramics: Sintering behavior, microstructure, and electrical properties. J Am Ceram Soc 2010, 93: 1101-1107.
Crossref Google Scholar
[12]
HB Zhang, SL Jiang, JZ Xiao, et al. Low temperature preparation and electrical properties of sodium-potassium bismuth titanate lead-free piezoelectric thick films by screen printing. J Eur Ceram Soc 2010, 30: 3157-3165.
Crossref Google Scholar
[13]
XL Chen, J Chen, DD Ma, et al. Thermally stable BaTiO3-Bi(Mg2/3Nb1/3)O3 solid solution with high relative permittivity in a broad temperature usage range. J Am Ceram Soc 2015, 98: 804-810.
Crossref Google Scholar
[14]
Q Xu, HX Liu, L Zhang, et al. Structure and electrical properties of lead-free Bi0.5Na0.5TiO3-based ceramics for energy-storage applications. RSC Adv 2016, 6: 59280-59291.
Crossref Google Scholar
[15]
J Shi, X Liu, WC Tian. High energy-storage properties of Bi0.5Na0.5TiO3-BaTiO3-SrTi0.875Nb0.1O3 lead-free relaxor ferroelectrics. J Mater Sci Technol 2018, 34: 2371-2374.
Google Scholar
[16]
QN Li, CR Zhou, JW Xu, et al. Tailoring antiferroelectricity with high energy-storage properties in Bi0.5Na0.5TiO3-BaTiO3 ceramics by modulating Bi/Na ratio. J Mater Sci: Mater Electron 2016, 27: 10810-10815.
Crossref Google Scholar
[17]
F Li, JW Zhai, B Shen, et al. Simultaneously high-energy storage density and responsivity in quasi-hysteresis-free Mn-doped Bi0.5Na0.5TiO3-BaTiO3-(Sr0.7Bi0.2□0.1)TiO3 ergodic relaxor ceramics. Mater Res Lett 2018, 6: 345-352.
Google Scholar
[18]
YR Wang, YP Pu, HY Zheng, et al. Enhanced dielectric relaxation in (1-x)BaTiO3-xBiYO3 ceramics. Mater Lett 2016, 181: 358-361.
Crossref Google Scholar
[19]
XL Chen, XX Li, X Yan, et al. (Ba1-xBi0.33xSr0.67x) (Ti1-xBi0.67xV0.33x)O3 and (Ba1-xBi0.5xSr0.5x)(Ti1-xBi0.5xTi0.5x)O3 solid solutions: Phase evolution, microstructure, dielectric properties and impedance analysis. Appl Phys A 2018, 124: 423.
Google Scholar
[20]
Y Yang, H Hao, L Zhang, et al. Structure, electrical and dielectric properties of Ca substituted BaTiO3 ceramics. Ceram Int 2018, 44: 11109-11115.
Crossref Google Scholar
[21]
T Kako, A Nakajima, H Irie, et al. Adhesion and sliding of wet snow on a super-hydrophobic surface with hydrophilic channels. J Mater Sci 2004, 39: 547-555.
Crossref Google Scholar
[22]
S Behara, L Ghatti, S Kanthamani, et al. Structural, optical, and Raman studies of Gd doped sodium bismuth titanate. Ceram Int 2018, 44: 12118-12124.
Crossref Google Scholar
[23]
YP Pu, WH Yang, ST Chen. Influence of rare earths on electric properties and microstructure of barium titanate ceramics. J Rare Earth 2007, 25: 154-157.
Crossref Google Scholar
[24]
N Baskaran, H Chang. Effect of Sn doping on the phase transformation properties of ferroelectric BaTiO3. J Mater Sci: Mater Electron 2001, 12: 527-531.
Crossref Google Scholar
[25]
YH Xie, S Yin, T Hashimoto, et al. Microwave-hydrothermal synthesis of nano-sized Sn2+-doped BaTiO3 powders and dielectric properties of corresponding ceramics obtained by spark plasma sintering method. J Mater Sci 2009, 44: 4834-4839.
Crossref Google Scholar
[26]
XL Chen, XX Li, GF Liu, et al. Super wide thermal stability and giant dielectric response of (Ba1-xBi0.5xSr0.5x) (Ti1−xBi0.5xSn0.5x)O3 ceramics. Mater Lett 2018, 223: 112-115.
Crossref Google Scholar
[27]
G Rohrer. Ionic radii for halides and chalcogenides. In: Structure and Bonding in Crystalline Materials. Cambridge: Cambridge University Press, 2001: 521-525.
Crossref
[28]
XX Li, XL Chen, X Yan, et al. Excellent thermal stability and low dielectric loss of (Ba1−xBi0.5xSr0.5x)(Ti1−xBi0.5xZr0.5x)O3 solid solution ceramics in a broad temperature range applied in X8R. Appl Phys A 2018, 124: 771.
Google Scholar
[29]
V Pal, P Thakur, K Dwivedi. Investigation of MPB region in lead free BLNT-BCT system through XRD and Raman spectroscopy. J Phys D: Appl Phys 2015, 48: 055301.
Crossref Google Scholar
[30]
X Huang, H Liu, Z Song, et al. Structure-property relationships in BaTiO3-(Na1/4Bi3/4)(Mg1/4Ti3/4)O3 lead-free ceramics. J Eur Ceram Soc 2016, 36: 533-540.
Google Scholar
[31]
A Scalabrin, AS Chaves, DS Shim, et al. Temperature dependence of the A1 and E optical phonons in BaTiO3. Phys Stat Sol (b) 1977, 79: 731-742.
Crossref Google Scholar
[32]
DY Lu, XY Sun, M Toda. A novel high-K ‘Y5V’ barium titanate ceramics co-doped with lanthanum and cerium. J Phys Chem Solids 2007, 68: 650-664.
Crossref Google Scholar
[33]
J Kreisel, P Bouvier, M Maglione, et al. High-pressure Raman investigation of the Pb-free relaxor BaTi0.65Zr0.35O3. Phys Rev B 2004, 69: 092104.
Crossref Google Scholar
[34]
Z Sun, LX Li, SH Yu, et al. Energy storage properties and relaxor behavior of lead-free Ba1−xSm2x/3Zr0.15Ti0.85O3 ceramics. Dalton Trans 2017, 46: 14341-14347.
Crossref Google Scholar
[35]
XL Chen, J Chen, DD Ma, et al. Thermally stable BaTiO3-Bi(Zn0.75W0.25)O3 solid solution with high relative permittivity and low dielectric loss. J Mater Sci: Mater Electron 2015, 26: 1413-1418.
Crossref Google Scholar
[36]
JM Deng, XJ Sun, SS Liu, et al. Influence of interface point defect on the dielectric properties of Y doped CaCu3Ti4O12 ceramics. J Adv Dielect 2016, 6: 1650009.
Crossref Google Scholar
[37]
BK Barick, RNP Choudhary, DK Pradhan. Dielectric and impedance spectroscopy of zirconium modified (Na0.5Bi0.5)TiO3 ceramics. Ceram Int 2013, 39: 5695-5704.
Crossref Google Scholar
[38]
XL Chen, XX Li, X Yan, et al. (Ba1−xBix)(Ti1−xNi0.5xSn0.5x)O3 solid solution: Phase evolution, microstructure, dielectric properties, and impedance analysis. J Electron Mater 2018, 47: 2576-2583.
Crossref Google Scholar
[39]
ZZ Cao, XY Cao, XT Liu, et al. Effect of Sb-Ba codoping on the ionic conductivity of Li7La3Zr2O12 ceramic. Ceram Int 2015, 41: 6232-6236.
Crossref Google Scholar
[40]
X Yan, XL Chen, XX Li, et al. Good electrical performances and impedance analysis of (1-x)KNN-xBMM lead-free ceramics. J Mater Sci: Mater Electron 2018, 29: 4538-4546.
Crossref Google Scholar
[41]
MX Zhou, RH Liang, ZY Zhou, et al. Combining high energy efficiency and fast charge-discharge capability in novel BaTiO3-based relaxor ferroelectric ceramic for energy-storage. Ceram Int 2019, 45: 3582-3590.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 8 Issue 3,
September 2019
Pages 427-437
DOI: 10.1007/s40145-019-0326-4
Cite this article:
CHEN X, LI X, ZHOU H, et al. Phase evolution, microstructure, electric properties of (Ba1-xBi0.67xNa0.33x)(Ti1-xBi0.33xSn0.67x)O3 ceramics. Journal of Advanced Ceramics, 2019, 8(3): 427-437. https://doi.org/10.1007/s40145-019-0326-4

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Received: 28 December 2018
Revised: 08 March 2019
Accepted: 22 March 2019
Published: 05 August 2019
© The author(s) 2019

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