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Research Article | Open Access

Enhanced thermal and cycling reliabilities in (K,Na)(Nb,Sb)O3-CaZrO3-(Bi,Na)HfO3 ceramics

Yi FANa,†, Zhenxing WANGa,†, Yu HUANa( ), Tao WEIa( ), Xiaohui WANGb
School of Material Science and Engineering, University of Jinan, Jinan 250022, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

† Yi Fan and Zhenxing Wang contributed equally to this work.

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Abstract

The thermal stability and fatigue resistance of piezoelectric ceramics are of great importance for industrialized application. In this study, the electrical properties of (0.99-x)(K0.48Na0.52)(Nb0.975Sb0.025)O3- 0.01CaZrO3-x(Bi0.5Na0.5)HfO3 ceramics are investigated. When x = 0.03, the ceramics exhibit the optimal electrical properties at room temperature and high Curie temperature (TC = 253 ℃). In addition, the ceramic has outstanding thermal stability (d3*3 ≈ 301 pm/V at 160 ℃) and fatigue resistance (variation of Pr and d3*3 ~10% after 104 electrical cycles). Subsequently, the defect configuration and crystal structure of the ceramics are studied by X-ray diffraction, temperature- dielectric property curves and impedance analysis. On one hand, the doping (Bi0.5Na0.5)HfO3 makes the dielectric constant peaks flatten. On the other hand, the defect concentration and migration are obviously depressed in the doped ceramics. Both of them can enhance the piezoelectrical properties and improve the temperature and cycling reliabilities. The present study reveals that the good piezoelectric properties can be obtained in 0.96(K0.48Na0.52)(Nb0.975Sb0.025)O3-0.01CaZrO3-0.03(Bi0.5Na0.5) HfO3 ceramics.

Keywords

(Na,K)NbO3 (KNN)-based ceramicsthermal stabilityfatigue resistancecrystal structuredefect structure

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Journal of Advanced Ceramics
Volume 9 Issue 3,
June 2020
Pages 349-359
DOI: 10.1007/s40145-020-0374-9
Cite this article:
FAN Y, WANG Z, HUAN Y, et al. Enhanced thermal and cycling reliabilities in (K,Na)(Nb,Sb)O3-CaZrO3-(Bi,Na)HfO3 ceramics. Journal of Advanced Ceramics, 2020, 9(3): 349-359. https://doi.org/10.1007/s40145-020-0374-9

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Received: 19 December 2019
Revised: 09 March 2020
Accepted: 10 March 2020
Published: 05 June 2020
© The Author(s) 2020

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