AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (4.7 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

One-step synthesis and electromagnetic absorption properties of high entropy rare earth hexaborides (HE REB6) and high entropy rare earth hexaborides/borates (HE REB6/HE REBO3) composite powders

Weiming ZHANGa, Biao ZHAOb, Huimin XIANGa, Fu-Zhi DAIa, Shijiang WUc, Yanchun ZHOUa( )
Science and Technology on Advanced Functional Composite Laboratory, Aerospace Research Institute of Materials & Processing Technology, Beijing 100076, China
Henan Key Laboratory of Aeronautical Materials and Application Technology, School of Material Science and Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450046, China
Zibo Firststar New Material Incorporated Co. Ltd., Zibo 255000, China
Show Author Information

Abstract

Considering the emergence of severe electromagnetic interference problems, it is vital to develop electromagnetic (EM) wave absorbing materials with high dielectric, magnetic loss and optimized impedance matching. However, realizing the synergistic dielectric and magnetic losses in a single phase material is still a challenge. Herein, high entropy (HE) rare earth hexaborides (REB6) powders with coupling of dielectric and magnetic losses were designed and successfully synthesized through a facial one-step boron carbide reduction method, and the effects of high entropy borates intermedia phases on the EM wave absorption properties were investigated. Five HE REB6 ceramics including (Ce0.2Y0.2Sm0.2Er0.2Yb0.2)B6, (Ce0.2Eu0.2Sm0.2Er0.2Yb0.2)B6, (Ce0.2Y0.2Eu0.2Er0.2Yb0.2)B6, (Ce0.2Y0.2Sm0.2 Eu0.2Yb0.2)B6, and (Nd0.2Y0.2Sm0.2Eu0.2 Yb0.2)B6 possess CsCl-type cubic crystal structure, and their theoretical densities range from 4.84 to 5.25 g/cm3. (Ce0.2Y0.2Sm0.2Er0.2 Yb0.2)B6 powders with the average particle size of 1.86 μm were found to possess the best EM wave absorption properties among these hexaborides. The RLmin value of (Ce0.2Y0.2Sm0.2Er0.2Yb0.2)B6 reaches -33.4 dB at 11.5 GHz at thickness of 2 mm; meanwhile, the optimized effective absorption bandwidth (EAB) is 3.9 GHz from 13.6 to 17.5 GHz with a thickness of 1.5 mm. The introduction of HE REBO3 (RE = Ce, Y, Sm, Eu, Er, Yb) as intermediate phase will give rise to the mismatching impedance, which will further lead to the reduction of reflection loss. Intriguingly, the HEREB6/HEREBO3 still possess wide effective absorption bandwidth of 4.1 GHz with the relative low thickness of 1.7 mm. Considering the better stability, low density, and good EM wave absorption properties, HE REB6 ceramics are promising as a new type of EM wave absorbing materials.

Keywords

high entropy rare earth hexaborides (HE REB6)one-step synthesiselectromagnetic wave absorbing propertiessynergistic dielectric and magnetic losseswide effective absorption bandwidth

References

[1]
DDL Chung. Electromagnetic interference shielding effectiveness of carbon materials. Carbon 2001, 39: 279-285.
Crossref Google Scholar
[2]
CL Holloway, RR DeLyser, RF German, et al. Comparison of electromagnetic absorber used in anechoic and semi-anechoic chambers for emissions and immunity testing of digital devices. IEEE Trans Electromagn Compat 1997, 39: 33-47.
Crossref Google Scholar
[3]
C Wang, V Murugadoss, J Kong, et al. Overview of carbon nanostructures and nanocomposites for electromagnetic wave shielding. Carbon 2018, 140: 696-733.
Crossref Google Scholar
[4]
YJ Jia, MAR Chowdhury, DJ Zhang, et al. Wide-band tunable microwave-absorbing ceramic composites made of polymer-derived SiOC ceramic and in situ partially surface-oxidized ultra-high-temperature ceramics. ACS Appl Mater Interfaces 2019, 11: 45862-45874.
Crossref Google Scholar
[5]
ZR Jia, KJ Lin, GL Wu, et al. Recent progresses of high-temperature microwave-absorbing materials. Nano 2018, 13: 1830005.
Crossref Google Scholar
[6]
JL Wallace. Broadband magnetic microwave absorbers: Fundamental limitations. IEEE Trans Magn 1993, 29: 4209-4214.
Crossref Google Scholar
[7]
LL Adebayo, H Soleimani, N Yahya, et al. Recent advances in the development of Fe3O4-based microwave absorbing materials. Ceram Int 2020, 46: 1249-1268.
Crossref Google Scholar
[8]
NN Wu, C Liu, DM Xu, et al. Enhanced electromagnetic wave absorption of three-dimensional porous Fe3O4/C composite flowers. ACS Sustainable Chem Eng 2018, 6: 12471-12480.
Crossref Google Scholar
[9]
YJ Li, M Yu, PG Yang, et al. Enhanced microwave absorption property of Fe nanoparticles encapsulated within reduced graphene oxide with different thicknesses. Ind Eng Chem Res 2017, 56: 8872-8879.
Crossref Google Scholar
[10]
Q Liu, H Liu, M Han, et al. Nanometer-sized nickel hollow spheres. Adv Mater 2005, 17: 1995-1999.
Crossref Google Scholar
[11]
Y Zhang, Y Huang, TF Zhang, et al. Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam. Adv Mater 2015, 27: 2049-2053.
Crossref Google Scholar
[12]
LL Yan, XX Wang, SC Zhao, et al. Highly efficient microwave absorption of magnetic nanospindle-conductive polymer hybrids by molecular layer deposition. ACS Appl Mater Interfaces 2017, 9: 11116-11125.
Crossref Google Scholar
[13]
P Zhang, XJ Han, LL Kang, et al. Synthesis and characterization of polyaniline nanoparticles with enhanced microwave absorption. RSC Adv 2013, 3: 12694-12701.
Crossref Google Scholar
[14]
S Kumar, R Chatterjee. Complex permittivity, permeability, magnetic and microwave absorbing properties of Bi3+ substituted U-type hexaferrite. J Magn Magn Mater 2018, 448: 88-93.
Crossref Google Scholar
[15]
K Park, S Lee, C Kim, et al. Fabrication and electromagnetic characteristics of electromagnetic wave absorbing sandwich structures. Compos Sci Technol 2006, 66: 576-584.
Crossref Google Scholar
[16]
M Zong, Y Huang, X Ding, et al. One-step hydrothermal synthesis and microwave electromagnetic properties of RGO/NiFe2O4 composite. Ceram Int 2014, 40: 6821-6828.
Crossref Google Scholar
[17]
VM Petrov, VV Gagulin. Microwave absorbing materials. Inorg Mater 2001, 37: 93-98.
Crossref Google Scholar
[18]
J Etourneau, P Hagenmuller. Structure and physical features of the rare-earth borides. Philos Mag B 1985, 52: 589-610.
Crossref Google Scholar
[19]
HC Longuet-Higgins, MDV Roberts. The electronic structure of the borides MB6. Proc R Soc Lond A 1954, 224: 336-347.
Crossref Google Scholar
[20]
M Yamazaki. Group-theoretical treatment of the energy bands in metal borides MeB6. J Phys Soc Jpn 1957, 12: 1-6.
Crossref Google Scholar
[21]
MC Aronson, JL Sarrao, Z Fisk, et al. Fermi surface of the ferromagnetic semimetal, EuB6. Phys Rev B 1999, 59: 4720-4724.
Crossref Google Scholar
[22]
PF Walch, DE Ellis, FM Mueller. Energy bands and bonding in LaB6 and YB6. Phys Rev B 1977, 15: 1859-1866.
Crossref Google Scholar
[23]
SS Kher, JT Spencer. Chemical vapor deposition of metal borides. J Phys Chem Solids 1998, 59: 1343-1351.
Crossref Google Scholar
[24]
KE Spear. Phase behavior and related properties of rare-earth borides. In Phase Diagrams: Materials Science and Technology. AM Alper, Ed. New York: Academic Press, 1976: 91-159.
Crossref
[25]
JP Mercurio, J Etourneau, R Naslain, et al. Electrical and magnetic properties of some rare-earth hexaborides. J Less-Common Met 1976, 47: 175-180.
Crossref Google Scholar
[26]
IDR MacKinnon, JA Alarco, PC Talbot. Metal hexaborides with Sc, Ti or Mn. Model Numer Simul Mater Sci 2013, 3: 158-169.
Crossref Google Scholar
[27]
R Bachmann, KN Lee, TH Geballe, et al. Spin scattering and magnetic ordering in EuB6. J Appl Phys 1970, 41: 1431-1432.
Crossref Google Scholar
[28]
TH Geballe, BT Matthias, K Andres, et al. Magnetic ordering in the rare-earth hexaborides. Science 1968, 160: 1443-1444.
Crossref Google Scholar
[29]
Jr Hacker. H, Shimada Y, Chung KS. Magnetic properties of CeB6, PrB6, EuB6, and GdB6. Phys Stat Sol (a) 1971, 4: 459-465.
Crossref Google Scholar
[30]
K Matsubayashi, M Maki, T Tsuzuki, et al. Parasitic ferromagnetism in a hexaboride? Nature 2002, 420: 143-144.
Crossref Google Scholar
[31]
BT Matthias, TH Geballe, K Andres, et al. Superconductivity and antiferromagnetism in boron-rich lattices. Science 1968, 159: 530.
Crossref Google Scholar
[32]
DP Young, D Hall, ME Torelli, et al. High-temperature weak ferromagnetism in a low-density free-electron gas. Nature 1999, 397: 412-414.
Crossref Google Scholar
[33]
GH Olsen, AV Cafiero. Single-crystal growth of mixed (La, Eu, Y, Ce, Ba, Cs) hexaborides for thermionic emission. J Cryst Growth 1978, 44: 287-290.
Crossref Google Scholar
[34]
Y Liu, WJ Lu, JN Qin, et al. A new route for the synthesis of NdB6 powder from Nd2O3-B4C system. J Alloys Compd 2007, 431: 337-341.
Crossref Google Scholar
[35]
M Hasan, H Sugo, E Kisi. Low temperature carbothermal and boron carbide reduction synthesis of LaB6. J Alloys Compd 2013, 578: 176-182.
Crossref Google Scholar
[36]
CM Rost, E Sachet, T Borman, et al. Entropy-stabilized oxides. Nat Commun 2015, 6: 8485.
Crossref Google Scholar
[37]
JL Braun, CM Rost, M Lim, et al. Charge-induced disorder controls the thermal conductivity of entropy-stabilized oxides. Adv Mater 2018, 30: 1805004.
Crossref Google Scholar
[38]
ZF Zhao, HM Xiang, FZ Dai, et al. (TiZrHf)P2O7: An equimolar multicomponent or high entropy ceramic with good thermal stability and low thermal conductivity. J Mater Sci Technol 2019, 35: 2227-2231.
Crossref Google Scholar
[39]
H Chen, HM Xiang, FZ Dai, et al. High porosity and low thermal conductivity high entropy (Zr0.2Hf0.2Ti0.2Nb0.2Ta0.2)C. J Mater Sci Technol 2019, 35: 1700-1705.
Google Scholar
[40]
H Chen, HM Xiang, FZ Dai, et al. High entropy (Yb0.25Y0.25Lu0.25Er0.25)2SiO5 with strong anisotropy in thermal expansion. J Mater Sci Technol 2020, 36: 134-139.
Crossref Google Scholar
[41]
ZF Zhao, H Chen, HM Xiang, et al. (Y0.25Yb0.25Er0.25Lu0.25)2(Zr0.5Hf0.5)2O7: A defective fluorite structured high entropy ceramic with low thermal conductivity and close thermal expansion coefficient to Al2O3. J Mater Sci Technol 2020, 39: 167-172.
Google Scholar
[42]
ZF Zhao, H Chen, HM Xiang, et al. High entropy defective fluorite structured rare-earth niobates and tantalates for thermal barrier applications. J Adv Ceram 2020, 9: 303-311.
Crossref Google Scholar
[43]
H Chen, B Zhao, ZF Zhao, et al. Achieving strong microwave absorption capability and wide absorption bandwidth through a combination of high entropy rare earth silicide carbides/rare earth oxides. J Mater Sci Technol 2020, 47: 216-222.
Crossref Google Scholar
[44]
RD Shannon. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst A 1976, 32: 751-767.
Crossref Google Scholar
[45]
A Sarkar, C Loho, L Velasco, et al. Multicomponent equiatomic rare earth oxides with a narrow band gap and associated praseodymium multivalency. Dalton Trans 2017, 46: 12167-12176.
Crossref Google Scholar
[46]
PA Miles, WB Westphal, A von Hippel. Dielectric spectroscopy of ferromagnetic semiconductors. Rev Mod Phys 1957, 29: 279-307.
Crossref Google Scholar
[47]
M Green, Z Liu, P Xiang, et al. Ferric metal-organic framework for microwave absorption. Mater Today Chem 2018, 9: 140-148.
Crossref Google Scholar
[48]
YC Zhou, FZ Dai, HM Xiang, et al. Shear anisotropy: Tuning high temperature metal hexaborides from soft to extremely hard. J Mater Sci Technol 2017, 33: 1371-1377.
Crossref Google Scholar
[49]
YC Zhou, B Liu, HM Xiang, et al. YB6: A ‘ductile’ and soft ceramic with strong heterogeneous chemical bonding for ultrahigh-temperature applications. Mater Res Lett 2015, 3: 210-215.
Crossref Google Scholar
[50]
GE Grechnev, AE Baranovskiy, VD Fil, et al. Electronic structure and bulk properties of MB6 and MB12 borides. Low Temp Phys 2008, 34: 921-929.
Crossref Google Scholar
[51]
JP Mercurio, J Etourneau, R Naslain, et al. Electrical and magnetic properties of some rare-earth hexaborides. J Less-Common Met 1976, 47: 175-180.
Crossref Google Scholar
[52]
J Kuneš, WE Pickett. Kondo and anti-Kondo coupling to local moments in EuB6. Phys Rev B 2004, 69: 165111.
Crossref Google Scholar
[53]
LH Tian, XD Yan, JL Xu, et al. Effect of hydrogenation on the microwave absorption properties of BaTiO3 nanoparticles. J Mater Chem A 2015, 3: 12550-12556.
Crossref Google Scholar
[54]
YP Duan, Z Liu, H Jing, et al. Novel microwave dielectric response of Ni/Co-doped manganese dioxides and their microwave absorbing properties. J Mater Chem 2012, 22: 18291-18299.
Crossref Google Scholar
[55]
F Ye, Q Song, ZC Zhang, et al. Direct growth of edge-rich graphene with tunable dielectric properties in porous Si3N4 ceramic for broadband high-performance microwave absorption. Adv Funct Mater 2018, 28: 1707205.
Crossref Google Scholar
[56]
T Prodromakis, C Papavassiliou. Engineering the Maxwell-Wagner polarization effect. Appl Surf Sci 2009, 255: 6989-6994.
Crossref Google Scholar
[57]
D O’Neill, RM Bowman, JM Gregg. Dielectric enhancement and Maxwell-Wagner effects in ferroelectric superlattice structures. Appl Phys Lett 2000, 77: 1520-1522.
Crossref Google Scholar
[58]
NN Wang, F Wu, AM Xie, et al. One-pot synthesis of biomass-derived carbonaceous spheres for excellent microwave absorption at the Ku band. RSC Adv 2015, 5: 40531-40535.
Crossref Google Scholar
[59]
PH Fang. Cole-Cole diagram and the distribution of relaxation times. J Chem Phys 1965, 42: 3411-3413.
Crossref Google Scholar
[60]
P Wang, XM Wang, L Qiao, et al. High-frequency magnetic properties and microwave absorption performance of oxidized Pr2Co17 flakes/epoxy composite in X-band. J Magn Magn Mater 2018, 468: 193-199.
Crossref Google Scholar
[61]
YP Duan, HT Guan. Microwave Absorbing Materials. New York: Jenny Stanford, 2016.
Crossref
[62]
YX Li, JY Wang, RG Liu, et al. Dependence of gigahertz microwave absorption on the mass fraction of Co@C nanocapsules in composite. J Alloys Compd 2017, 724: 1023-1029.
Crossref Google Scholar
[63]
B Zhao, WY Zhao, G Shao, et al. Morphology-control synthesis of a core-shell structured NiCu alloy with tunable electromagnetic-wave absorption capabilities. ACS Appl Mater Interfaces 2015, 7: 12951-12960.
Crossref Google Scholar
[64]
FB Meng, R Zhao, YQ Zhan, et al. Preparation and microwave absorption properties of Fe-phthalocyanine oligomer/Fe3O4 hybrid microspheres. Appl Surf Sci 2011, 257: 5000-5006.
Crossref Google Scholar
[65]
NN Wu, C Liu, DM Xu, et al. Enhanced electromagnetic wave absorption of three-dimensional porous Fe3O4/C composite flowers. ACS Sustainable Chem Eng 2018, 6: 12471-12480.
Crossref Google Scholar
[66]
Y Liu, YW Fu, L Liu, et al. Low-cost carbothermal reduction preparation of monodisperse Fe3O4/C core-shell nanosheets for improved microwave absorption. ACS Appl Mater Interfaces 2018, 10: 16511-16520.
Crossref Google Scholar
[67]
M Almasi-Kashi, MH Mokarian, S Alikhanzadeh-Arani. Improvement of the microwave absorption properties in FeNi/PANI nanocomposites fabricated with different structures. J Alloys Compd 2018, 742: 413-420.
Crossref Google Scholar
[68]
XL Su, J Ning, Y Jia, et al. Flower-like MoS2 nanospheres: A promising material with good microwave absorption property in the frequency range of 8.2-12.4 GHz. Nano 2018, 13: 1850084.
Crossref Google Scholar
[69]
JH Chen, M Liu, T Yang, et al. Improved microwave absorption performance of modified SiC in the 2-18 GHz frequency range. CrystEngComm 2017, 19: 519-527.
Crossref Google Scholar
[70]
S Farhan, RM Wang, KZ Li. Electromagnetic interference shielding effectiveness of carbon foam containing in situ grown silicon carbide nanowires. Ceram Int 2016, 42: 11330-11340.
Crossref Google Scholar
[71]
MK Han, XW Yin, ZX Hou, et al. Flexible and thermostable graphene/SiC nanowire foam composites with tunable electromagnetic wave absorption properties. ACS Appl Mater Interfaces 2017, 9: 11803-11810.
Crossref Google Scholar
[72]
Y Jiang, Y Chen, YJ Liu, et al. Lightweight spongy bone-like graphene@SiC aerogel composites for high-performance microwave absorption. Chem Eng J 2018, 337: 522-531.
Crossref Google Scholar
[73]
A Kumar, V Agarwala, D Singh. Effect of milling on dielectric and microwave absorption properties of SiC based composites. Ceram Int 2014, 40: 1797-1806.
Crossref Google Scholar
[74]
CG Hu, ZY Mou, GW Lu, et al. 3D graphene-Fe3O4 nanocomposites with high-performance microwave absorption. Phys Chem Chem Phys 2013, 15: 13038-13043.
Crossref Google Scholar
[75]
YZ Wan, J Xiao, CZ Li, et al. Microwave absorption properties of FeCo-coated carbon fibers with varying morphologies. J Magn Magn Mater 2016, 399: 252-259.
Crossref Google Scholar
[76]
L Zhang, H Zhu, Y Song, et al. The electromagnetic characteristics and absorbing properties of multi-walled carbon nanotubes filled with Er2O3 nanoparticles as microwave absorbers. Mater Sci Eng: B 2008, 153: 78-82.
Crossref Google Scholar
[77]
DL Zhao, X Li, ZM Shen. Preparation and electromagnetic and microwave absorbing properties of Fe-filled carbon nanotubes. J Alloys Compd 2009, 471: 457-460.
Crossref Google Scholar
[78]
ZT Zhu, X Sun, GX Li, et al. Microwave-assisted synthesis of graphene-Ni composites with enhanced microwave absorption properties in Ku-band. J Magn Magn Mater 2015, 377: 95-103.
Crossref Google Scholar
[79]
M Green, LH Tian, P Xiang, et al. FeP nanoparticles: A new material for microwave absorption. Mater Chem Front 2018, 2: 1119-1125.
Crossref Google Scholar
[80]
WD Zhang, X Zhang, HJ Wu, et al. Impact of morphology and dielectric property on the microwave absorbing performance of MoS2-based materials. J Alloys Compd 2018, 751: 34-42.
Crossref Google Scholar
[81]
PB Liu, Y Huang, X Zhang. Cubic NiFe2O4 particles on graphene-polyaniline and their enhanced microwave absorption properties. Compos Sci Technol 2015, 107: 54-60.
Crossref Google Scholar
[82]
W She, H Bi, ZW Wen, et al. Tunable microwave absorption frequency by aspect ratio of hollow polydopamine@α-MnO2 microspindles studied by electron holography. ACS Appl Mater Interfaces 2016, 8: 9782-9789.
Crossref Google Scholar
[83]
HB Yang, T Ye, Y Lin, et al. Excellent microwave absorption property of ternary composite: Polyaniline-BaFe12O19-CoFe2O4 powders. J Alloys Compd 2015, 653: 135-139.
Crossref Google Scholar
[84]
YC Qing, WC Zhou, F Luo, et al. Optimization of electromagnetic matching of carbonyl iron/BaTiO3 composites for microwave absorption. J Magn Magn Mater 2011, 323: 600-606.
Crossref Google Scholar
[85]
Y Yang, CL Xu, YX Xia, et al. Synthesis and microwave absorption properties of FeCo nanoplates. J Alloys Compd 2010, 493: 549-552.
Crossref Google Scholar
[86]
SB Ni, XL Sun, XH Wang, et al. Low temperature synthesis of Fe3O4 micro-spheres and its microwave absorption properties. Mater Chem Phys 2010, 124: 353-358.
Crossref Google Scholar
[87]
T Wu, Y Liu, X Zeng, et al. Facile hydrothermal synthesis of Fe3O4/C core-shell nanorings for efficient low-frequency microwave absorption. ACS Appl Mater Interfaces 2016, 8: 7370-7380.
Crossref Google Scholar
[88]
Z Xiang, YM Song, J Xiong, et al. Enhanced electromagnetic wave absorption of nanoporous Fe3O4@carbon composites derived from metal-organic frameworks. Carbon 2019, 142: 20-31.
Crossref Google Scholar
[89]
DL Zhao, Q Lv, ZM Shen. Fabrication and microwave absorbing properties of Ni-Zn spinel ferrites. J Alloys Compd 2009, 480: 634-638.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 10 Issue 1,
February 2021
Pages 62-77
DOI: 10.1007/s40145-020-0417-2
Cite this article:
ZHANG W, ZHAO B, XIANG H, et al. One-step synthesis and electromagnetic absorption properties of high entropy rare earth hexaborides (HE REB6) and high entropy rare earth hexaborides/borates (HE REB6/HE REBO3) composite powders. Journal of Advanced Ceramics, 2021, 10(1): 62-77. https://doi.org/10.1007/s40145-020-0417-2

2013

Views

520

Downloads

106

Crossref

N/A

Web of Science

114

Scopus

1

CSCD

Altmetrics
Received: 29 July 2020
Revised: 23 August 2020
Accepted: 30 August 2020
Published: 21 October 2020
© The Author(s) 2020

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return