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Research Article | Open Access

Evolution of electromechanical properties in Fe-doped (Pb,Sr)(Zr,Ti)O3 piezoceramics

Chuan CHENa, Yan WANGa, Zong-Yue LIb, Chun LIUc, Wen GONGd,e( ), Qing TANf( ), Bing HANg ( ), Fang-Zhou YAOe,h,i( ), Ke WANGd
Joint Laboratory of Electric Power Intelligent Sensing Technology and Application, Department of Sensing Technology for Electric Power, Global Energy Interconnection Research Institute Co., Ltd., Future Science Park, Beijing 102209, China
China Aerospace Science and Industry Corporation, Beijing 100048, China
Naqu Branch of Tibet Electric Limited Company, Naqu 852000, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
Center of Advanced Ceramic Materials and Devices, Yangtze Delta Region Institute of Tsinghua University, Zhejiang 314006, China
Beijing Advanced Innovation Center for Materials Genome Engineering, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
Department of Orthodontics & National Engineering Laboratory for Digital and Material Technology, Peking University School and Hospital of Stomatology, Beijing 100081, China
State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China
Foshan (Southern China) Institute for New Materials, Foshan 528200, China
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Abstract

Defects in acceptor-doped perovskite piezoelectric materials have a significant impact on their electrical properties. Herein, the defect mediated evolution of piezoelectric and ferroelectric properties of Fe-doped (Pb,Sr)(Zr,Ti)O3 (PSZT–Fe) piezoceramics with different treatments, including quenching, aging, de-aging, and poling, was investigated systematically. Oxygen vacancies with a cubic symmetry are preserved in the quenched PSZT–Fe ceramics, rendering them robust ferroelectric behaviors. In the aged PSZT–Fe polycrystals, defect dipole between Fe dopant and oxygen vacancy has the same orientation with spontaneous polarization PS, which enables the reversible domain switching and hence leads to the emergence of pinched polarization hysteresis and recoverable strain effect. And the defect dipoles can be gradually disrupted by bipolar electric field cycling, once again endowing the aged materials with representative ferroelectric properties. For the poled PSZT–Fe polycrystals, the defect dipoles are reoriented to be parallel to the applied poling field, and an internal bias field aligning along the same direction emerges simultaneously, being responsible for asymmetric hysteresis loops.

Keywords

lead–zirconate–titanate (PZT)piezoelectricacceptordefect engineeringelectromechanical properties

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Journal of Advanced Ceramics
Volume 10 Issue 3,
June 2021
Pages 587-595
DOI: 10.1007/s40145-021-0460-7
Cite this article:
CHEN C, WANG Y, LI Z-Y, et al. Evolution of electromechanical properties in Fe-doped (Pb,Sr)(Zr,Ti)O3 piezoceramics. Journal of Advanced Ceramics, 2021, 10(3): 587-595. https://doi.org/10.1007/s40145-021-0460-7

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Received: 16 October 2020
Revised: 18 December 2020
Accepted: 12 January 2021
Published: 24 February 2021
© The Author(s) 2021

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