AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (10.3 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

High-temperature oxidation behavior of SiBN fibers in air

Xin LONG( ), Zhenyu WU, Changwei SHAO( ), Xiaozhou WANG, Yingde WANG
Science and Technology on Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
Show Author Information

Abstract

SiBN fibers are one of the most admirable microwave-transparent reinforced materials for high Mach number aircrafts. Currently, the detailed high-temperature oxidation behavior of SiBN fibers has not been studied yet. In this work, we studied the high-temperature oxidation behavior of SiBN fibers with different boron contents at the temperature range of 1000-1400 ℃ in air. SiBN fibers started to be oxidized at 1100 ℃, with Si3N4 and BN phase oxidized to SiO2 and B2O3, respectively. Due to the gasification and the escape of molten B2O3 at high temperatures, amorphous SiO2 could be remained at the fiber surface. As the fiber further oxidized, the molten B2O3 at the inside may infiltrate into the fiber interior to react with Si3N4, causing the precipitation of hexagonal boron nitride (h-BN) nanoparticles and the formation of SiO2/BN layer. Finally, complex oxidation layers with two distinct concentric sublayers accompanied with two transition sublayers could be formed after the oxidizing treatment.

Keywords

microwave-transparentSiBN fibershigh-temperatureoxidation resistance

References

[1]
Padture NP. Advanced structural ceramics in aerospace propulsion. Nat Mater 2016, 15: 804-809.
Google Scholar
[2]
Khatavakar N, Balasubramanian K. Composite materials for supersonic aircraft radomes with ameliorated radio frequency transmission-a review. RSC Adv 2016, 6: 6709-6718.
Google Scholar
[3]
Zou CR, Li B, Wang SQ, et al. Fabrication and high-temperature mechanical properties of 2.5DSi3N4f/BN fiber-reinforced ceramic matrix composite. Mater Des 2016, 92: 335-344.
Google Scholar
[4]
Cheng ZL, Ye F, Liu YS, et al. Mechanical and dielectric properties of porous and wave-transparent Si3N4-Si3N4 composite ceramics fabricated by 3D printing combined with chemical vapor infiltration. J Adv Ceram 2019, 8: 399-407.
Google Scholar
[5]
Li B, Liu K, Zhang CR, et al. Fabrication and properties of borazine derived boron nitride bonded porous silicon aluminum oxynitride wave-transparent composite. J Eur Ceram Soc 2014, 34: 3591-3595.
Google Scholar
[6]
Zhao Z, Zhou GX, Yang ZH, et al. Direct ink writing of continuous SiO2 fiber reinforced wave-transparent ceramics. J Adv Ceram 2020, 9: 403-412.
Google Scholar
[7]
Peters PWM, Daniels B, Clemens F, et al. Mechanical characterisation of mullite-based ceramic matrix composites at test temperatures up to 1200 ℃. J Eur Ceram Soc 2000, 20: 531-535.
Google Scholar
[8]
Ma X, Liang YY, Qiu HP, et al. Preparation of high- performance 2D Si3N4f/SiBN ceramic matrix composites by precursor infiltration pyrolysis. IOP Conf Ser: Mater Sci Eng 2019, 678: 012044.
Google Scholar
[9]
Toury B, Miele P, Cornu D, et al. Boron nitride fibers prepared from symmetric and asymmetric alkylaminoborazines. Adv Funct Mater 2002, 12: 228-234.
Google Scholar
[10]
Tang Y, Wang J, Li XD, et al. Polymer-derived SiBN fiber for high-temperature structural/functional applications. Chem Eur J 2010, 16: 6458-6462.
Google Scholar
[11]
Li D, Zhang CR, Li B, et al. Mechanical properties of unidirectional SiBN fiber reinforced boron nitride matrix composites. Mater Lett 2012, 68: 222-224.
Google Scholar
[12]
Peng YQ, Han KQ, Zhao X, et al. Large-scale preparation of SiBN ceramic fibres from a single source precursor. Ceram Int 2014, 40: 4797-4804.
Google Scholar
[13]
Baldus HP, Jansen M. Novel high-performance ceramics— amorphous inorganic networks from molecular precursors. Angew Chem Int Ed Engl 1997, 36: 328-343.
Google Scholar
[14]
Li SW, Li YC, Xiao HR, et al. Oxidation behavior of Si3N4 fibers derived from polycarbosilane. Corros Sci 2018, 136: 9-17.
Google Scholar
[15]
Cinibulk MK, Parthasarathy TA. Characterization of oxidized polymer-derived SiBCN fibers. J Am Ceram Soc 2001, 84: 2197-2202.
Google Scholar
[16]
Long X, Shao CW, Wang YD. Effects of boron content on the microwave-transparent property and high-temperature stability of continuous SiBN fibers. J Am Ceram Soc 2020, 103: 4436-4444.
Google Scholar
[17]
Ji XY, Shao CW, Wang H, et al. A simple and efficient method for the synthesis of SiBNC ceramics with different Si/B atomic ratios. Ceram Int 2017, 43: 7469-7476.
Google Scholar
[18]
Lu L, Feng CX, Song YC. Curing polysilazane fibres by exposure to boron trichloride. J Mater Sci Lett 1998, 17: 481-484.
Google Scholar
[19]
Liu Y, Peng S, Cui YJ, et al. Fabrication and properties of precursor-derived SiBN ternary ceramic fibers. Mater Des 2017, 128: 150-156.
Google Scholar
[20]
Hou YB, Li B, Shao CW, et al. Effect of high-temperature annealing in air and N2 atmosphere on the mechanical properties of Si3N4 fibers. Mater Sci Eng: A 2018, 724: 502-508.
Google Scholar
[21]
Kong J, Wang MJ, Zou JH, et al. Soluble and meltable hyperbranched polyborosilazanes toward high-temperature stable SiBCN ceramics. ACS Appl Mater Interfaces 2015, 7: 6733-6744.
Google Scholar
[22]
Liu YS, Chai N, Li Z, et al. Effect of deposition temperature on deposition kinetics and mechanism of silicon boron nitride coating deposited from SiCl4-BCl3- NH3-H2-Ar mixture using low pressure chemical vapor deposition. Surf Coat Technol 2015, 261: 295-303.
Google Scholar
[23]
Li DX, Yang ZH, Jia DC, et al. High-temperature oxidation behavior of dense SiBCN monoliths: Carbon-content dependent oxidation structure, kinetics and mechanisms. Corros Sci 2017, 124: 103-120.
Google Scholar
[24]
Ji XY, Wang SS, Shao CW, et al. High-temperature corrosion behavior of SiBCN fibers for aerospace applications. ACS Appl Mater Interfaces 2018, 10: 19712-19720.
Google Scholar
Journal of Advanced Ceramics
Volume 10 Issue 4,
August 2021
Pages 768-777
DOI: 10.1007/s40145-021-0471-4
Cite this article:
LONG X, WU Z, SHAO C, et al. High-temperature oxidation behavior of SiBN fibers in air. Journal of Advanced Ceramics, 2021, 10(4): 768-777. https://doi.org/10.1007/s40145-021-0471-4

1452

Views

268

Downloads

21

Crossref

21

Web of Science

23

Scopus

5

CSCD

Altmetrics
Received: 02 December 2020
Revised: 20 February 2021
Accepted: 05 March 2021
Published: 05 August 2021
© The Author(s) 2021

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return