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Review | Open Access

Garnet-type solid electrolyte: Advances of ionic transport performance and its application in all-solid-state batteries

P. M. GONZALEZ PUENTEa, Shangbin SONGb, Shiyu CAOb, Leana Ziwen RANNALTERa, Ziwen PANb, Xing XIANGa, Qiang SHENa, Fei CHENa,b( )
State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
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Abstract

All-solid-state lithium batteries (ASSLBs), which use solid electrolytes instead of liquid ones, have become a hot research topic due to their high energy and power density, ability to solve battery safety issues, and capabilities to fulfill the increasing demand for energy storage in electric vehicles and smart grid applications. Garnet-type solid electrolytes have attracted considerable interest as they meet all the properties of an ideal solid electrolyte for ASSLBs. The garnet-type Li7La3Zr2O12 (LLZO) has excellent environmental stability; experiments and computational analyses showed that this solid electrolyte has a high lithium (Li) ionic conductivity (10-4-10-3 S·cm-1), an electrochemical window as wide as 6 V, stability against Li metal anode, and compatibility with most of the cathode materials. In this review, we present the fundamentals of garnet-type solid electrolytes, preparation methods, air stability, some strategies for improving the conductivity based on experimental and computational results, interfacial issues, and finally applications and challenges for future developments of LLZO solid electrolytes for ASSLBs.

Keywords

Li7La3Zr2O12 (LLZO)solid electrolyteslithium ionic conductivitylithium concentrationmobility of lithium-ionair stabilitysolid-state batteries

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Journal of Advanced Ceramics
Volume 10 Issue 5,
October 2021
Pages 933-972
DOI: 10.1007/s40145-021-0489-7
Cite this article:
GONZALEZ PUENTE PM, SONG S, CAO S, et al. Garnet-type solid electrolyte: Advances of ionic transport performance and its application in all-solid-state batteries. Journal of Advanced Ceramics, 2021, 10(5): 933-972. https://doi.org/10.1007/s40145-021-0489-7
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Received: 01 January 2021
Revised: 04 April 2021
Accepted: 27 April 2021
Published: 27 September 2021
© The Author(s) 2021

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