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Research Article | Open Access

Influence of binder systems on sintering characteristics, microstructures, and mechanical properties of PcBN composites fabricated by SPS

Shuna CHENa,b, Hengzhong FANa, Yunfeng SUa( ), Wensheng LIc, Jicheng LIa,b, Bing YANc, Junjie SONGa, Litian HUa, Yongsheng ZHANGa( )
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
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Abstract

Cubic boron nitride (cBN) with high hardness, thermal conductivity, wear resistance, and chemical inertness has become the most promising abrasive and machining material. Due to the difficulty of fabricating pure cBN body, generally, some binders are incorporated among cBN particles to prepare polycrystalline cubic boron nitride (PcBN). Hence, the binders play a critical factor to the performances of PcBN composites. In this study, the PcBN composites with three binder systems containing ceramic and metal phases were fabricated by spark plasma sintering (SPS) from 1400 to 1700 ℃. The sintering behaviors and mechanical properties of the composites were investigated. Results show that the effect of binder formulas on mechanical properties mainly related to the compactness, mechanical performances, and thermal expansion coefficient of binder phases, which affect the carrying capacity of the composites and the bonding strength between binder phases and cBN particles. The PcBN composite with SiAlON phase as binder presented optimal flexural strength (465±29 MPa) and fracture toughness (5.62±0.37 MPa·m1/2), attributing to the synergistic effect similar to transgranular and intergranular fractures. Meanwhile, the excellent mechanical properties can be maintained a comparable level when the temperature even rises to 800 ℃. Due to the weak bonding strength and high porosity, the PcBN composites with Al2O3-ZrO2(3Y) and Al-Ti binder systems exhibited inferior mechanical properties. The possible mechanisms to explain these results were also analyzed.

Keywords

polycrystalline cubic boron nitride (PcBN)binder systemsintering characteristichigh temperature mechanical propertyfracture mechanism

References

[1]
Denkena B, Grove T, Müller-Cramm D, et al. Influence of the cutting direction angle on the tool wear behavior in face plunge grinding of PcBN. Wear 2020, 454-455: 203325.
Crossref Google Scholar
[2]
McKie A, Winzer J, Sigalas I, et al. Mechanical properties of cBN-Al composite materials. Ceram Int 2011, 37: 1-8.
Crossref Google Scholar
[3]
Mo P, Chen C, Jia G, et al. Effect of tungsten content on microstructure and mechanical properties of PCBN synthesized in cBN-Ti-Al-W system. Int J Refract Met Hard Mat 2020, 87: 105138.
Crossref Google Scholar
[4]
Klimczyk P, Cura ME, Vlaicu AM, et al. Al2O3-cBN composites sintered by SPS and HPHT methods. J Eur Ceram Soc 2016, 36: 1783-1789.
Crossref Google Scholar
[5]
Ji H, Li Z, Sun K, et al. Effect of Y2O3 additive on properties of cBN composites with Si3N4-Al2O3-Al as binder by high temperature and high pressure sintering. Ceram Int 2019, 45: 20478-20483.
Crossref Google Scholar
[6]
Rong XZ, Tsurumi T, Fukunaga O, et al. High-pressure sintering of cBN-TiN-Al composite for cutting tool application. Diamond Relat Mater 2002, 11: 280-286.
Crossref Google Scholar
[7]
Taniguchi T, Akaishi M, Yamaoka S. Sintering of cubic boron nitride without additives at 7.7 GPa and above 2000 ℃. J Mater Res 1999, 14: 162-169.
Crossref Google Scholar
[8]
Mo P, Chen C, Chen J, et al. Effect of sintering temperature on synthesis of PCBN in cBN-Ti-Al-W system. Diam Relat Mater 2020, 103: 107714.
Crossref Google Scholar
[9]
Angseryd J, Elfwing M, Olsson E, et al. Detailed microstructure of a cBN based cutting tool material. Int J Refract Met Hard Mater 2009, 27: 249-255.
Crossref Google Scholar
[10]
Liu Y, Sun A, Zhong S, et al. Effect of Al-Ti content on mechanical properties of in-situ synthesized PcBN composites. Diam Relat Mat 2020, 109: 108068.
Crossref Google Scholar
[11]
Yu R, Melnichuk I, Garashchenko V, et al. Influence of cBN content, Al2O3 and Si3N4 additives and their morphology on microstructure, properties, and wear of PCBN with NbN binder. Ceram Int 2020, 46: 22230-22238.
Crossref Google Scholar
[12]
Klimczyk P, Wyżga P, Cyboroń J, et al. Phase stability and mechanical properties of Al2O3-cBN composites prepared via spark plasma sintering. Diam Relat Mater 2020, 104: 107762.
Crossref Google Scholar
[13]
Rampai T, Lang CI, Sigalas I. Investigation of MAX phase/c-BN composites. Ceram Int 2013, 39: 4739-4748.
Crossref Google Scholar
[14]
Zhang Z, Duan XM, Qiu BF, et al. Preparation and anisotropic properties of textured structural ceramics: A review. J Adv Ceram 2019, 8: 289-332.
Crossref Google Scholar
[15]
Hotta M, Goto T. Effect of time on microstructure and hardness of β-SiAlON-cubic boron nitride composites during spark plasma sintering. Ceram Int 2011, 37: 521-524.
Crossref Google Scholar
[16]
Dai JW, Mu RD, Wang X, et al. Effects of ZrO2 doping on mechanical and thermo-physical properties of La2Ce2O7 ceramics. Equip Environ Eng 2019, 16: 21-26. (in Chinese)
Google Scholar
[17]
Wang X, Ma Z, Sun X, et al. Effects of ZrO2 and Y2O3 on physical and mechanical properties of ceramic bond and ceramic CBN composites. Int J Refract Met Hard Mater 2018, 75: 18-24.
Crossref Google Scholar
[18]
Yuan Y, Cheng X, Chang R, et al. Reactive sintering cBN-Ti-Al composites by spark plasma sintering. Diam Relat Mater 2016, 69: 138-143.
Crossref Google Scholar
[19]
Permin DA, Boldin MS, Belyaev AV, et al. IR-transparent MgO-Gd2O3 composite ceramics produced by self- propagating high-temperature synthesis and spark plasma sintering. J Adv Ceram 2021, 10: 237-246.
Crossref Google Scholar
[20]
Ahmed BA, Laoui T, Hakeem AS. Development of calcium stabilized nitrogen rich α-SiAlON ceramics along the Si3N4:1/2Ca3N2:3AlN line using spark plasma sintering. J Adv Ceram 2020, 9: 606-616.
Crossref Google Scholar
[21]
Garrett JC, Sigalas I, Herrmann M, et al. cBN reinforced Y-α-SiAlON composites. J Eur Ceram Soc 2013, 33: 2191-2198.
Crossref Google Scholar
[22]
Ren XJ, Yang QX, James RD, et al. Cutting temperatures in hard turning chromium hardfacings with PCBN tooling. J Mater Process Technol 2004, 147: 38-44.
Crossref Google Scholar
[23]
Vel L, Demazeau G, Etourneau J. Cubic boron nitride: Synthesis, physicochemical properties and applications. Mater Sci Eng: B 1991, 10: 149-164.
Crossref Google Scholar
[24]
Harris TK, Brookes EJ, Taylor CJ. The effect of temperature on the hardness of polycrystalline cubic boron nitride cutting tool materials. Int J Refract Met Hard Mater 2004, 22: 105-110.
Crossref Google Scholar
[25]
Dou YW, Kou ZL, Qi L, et al. Turning hardened bearing steel with PcBN tool. Daimond & Abrasives Eng 2010, 30: 54-57. (in Chinese)
Google Scholar
[26]
Gan L, Mao ZY, Zhang YQ, et al. Effect of composition variation on phases and photoluminescence properties of β-SiAlON:Ce3+ phosphor. Ceram Int 2013, 39: 4633-4637.
Crossref Google Scholar
[27]
Acikbas NC, Demir O. The effect of cation type, intergranular phase amount and cation mole ratios on z value and intergranular phase crystallization of SiAlON ceramics. Ceram Int 2013, 39: 3249-3259.
Crossref Google Scholar
[28]
Barick P, Jana DC, Saha BP. Load-dependent indentation behavior of β-SiAlON and α-silicon carbide. J Adv Ceram 2013, 2: 185-192.
Crossref Google Scholar
[29]
Sun X, Li JG, Guo S, et al. Intragranular particle residual stress strengthening of Al2O3-SiC nanocomposites. J Am Ceram Soc 2005, 88: 1536-1543.
Crossref Google Scholar
[30]
Sun Q, Yang J, Yu Y, et al. The novel SiAlON-Sn composite with high toughness and wear resistance prepared at a lower-temperature. Tribol Int 2020, 147: 106239.
Crossref Google Scholar
[31]
Sun QC, Wang ZX, Yang J, et al. High-performance TiN reinforced SiAlON matrix composites: A good combination of excellent toughness and tribological properties at a wide temperature range. Ceram Int 2018, 44: 17258-17265.
Crossref Google Scholar
[32]
Klemm H, Herrmann M, Reich T, et al. High-temperature properties of mixed α′/β′-SiAlON materials. J Am Ceram Soc 2005, 81: 1141-1148.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 2,
February 2022
Pages 321-330
DOI: 10.1007/s40145-021-0536-4
Cite this article:
CHEN S, FAN H, SU Y, et al. Influence of binder systems on sintering characteristics, microstructures, and mechanical properties of PcBN composites fabricated by SPS. Journal of Advanced Ceramics, 2022, 11(2): 321-330. https://doi.org/10.1007/s40145-021-0536-4

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Received: 28 May 2021
Revised: 25 August 2021
Accepted: 11 September 2021
Published: 11 January 2022
© The Author(s) 2021.

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