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Research Article | Open Access

Fabrication and properties of non-stoichiometric Tb2(Hf1–xTbx)2O7–x magneto-optical ceramics

Lixuan ZHANGa,b, Xiaoying LIa,b, Dianjun HUa,b, Ziyu LIUa,b, Tengfei XIEa, Lexiang WUa, Zhaoxiang YANGa, Jiang LIa,b( )
Transparent Ceramics Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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Graphical Abstract

Abstract

Non-stoichiometric Tb2(Hf1−xTbx)2O7−x (x = −0.07–0.45) magneto-optical ceramics were fabricated by solid-state reactive sintering in vacuum combined with hot isostatic pressing (HIP) post-treatment without any sintering aids. The phase composition, densification process, microstructure, optical transmittance, and Verdet constant of Tb2(Hf1−xTbx)2O7−x ceramics were investigated. The in-line transmittance of (Tb0.93Hf0.07)2Hf2O7.07 ceramics with a thickness of 2.0 mm reaches 74.6% at 1064 nm. The Verdet constant of Tb2(Hf1−xTbx)2O7−x ceramics is −153.4, −155.8, and −181.2 rad/(T·m) at the wavelength of 633 nm when x = −0.07, 0, and 0.1, respectively. The Verdet constant increases with the increase of Tb content, and these values are higher than that of the commercial Tb3Ga5O12 crystal, indicating that non-stoichiometric Tb2(Hf1−xTbx)2O7−x ceramics have a great potential for the application in Faraday isolators.

Keywords

magneto-optical ceramicsTb2(Hf1−xTbx)2O7−x ceramicsreactive sinteringVerdet constant

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Journal of Advanced Ceramics
Volume 11 Issue 5,
May 2022
Pages 784-793
DOI: 10.1007/s40145-022-0571-9
Cite this article:
ZHANG L, LI X, HU D, et al. Fabrication and properties of non-stoichiometric Tb2(Hf1–xTbx)2O7–x magneto-optical ceramics. Journal of Advanced Ceramics, 2022, 11(5): 784-793. https://doi.org/10.1007/s40145-022-0571-9

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Received: 02 November 2021
Revised: 09 January 2022
Accepted: 11 January 2022
Published: 02 April 2022
© The Author(s) 2022.

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