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Research Article | Open Access

Efficient photocatalytic hydrogen evolution coupled with benzaldehyde production over 0D Cd0.5Zn0.5S/2D Ti3C2 Schottky heterojunction

Junnan TAOa,†, Mingyuan WANGb,†, Guiwu LIUa( ), Qinqin LIUa, Lei LUa, Neng WANb, Hua TANGc( ), Guanjun QIAOa
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
SEU-FEI Nano-Pico Center, Key Laboratory of MEMS of Ministry of Education, School of Electrical Science and Engineering, Southeast University, Nanjing 210096, China
School of Environmental Science and Engineering, Qingdao University, Qingdao 266071, China

† Junnan Tao and Mingyuan Wang contributed equally to this work.

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Abstract

Converting water into hydrogen fuel and oxidizing benzyl alcohol to benzaldehyde simultaneously under visible light illumination is of great significance, but the fast recombination of photogenerated carriers in photocatalysts seriously decreases the conversion efficiency. Herein, a novel dual-functional 0D Cd0.5Zn0.5S/2D Ti3C2 hybrid was fabricated by a solvothermally in-situ generated assembling method. The Cd0.5Zn0.5S nano-spheres with a fluffy surface completely and uniformly covered the ultrathin Ti3C2 nanosheets, leading to the increased Schottky barrier (SB) sites due to a large contact area, which could accelerate the electron-hole separation and improve the light utilization. The optimized Cd0.5Zn0.5S/Ti3C2 hybrid simultaneously presents a hydrogen evolution rate of 5.3 mmol/(g·h) and a benzaldehyde production rate of 29.3 mmol/(g·h), which are ~3.2 and 2 times higher than those of pristine Cd0.5Zn0.5S, respectively. Both the multiple experimental measurements and the density functional theory (DFT) calculations further demonstrate the tight connection between Cd0.5Zn0.5S and Ti3C2, formation of Schottky junction, and efficient photogenerated electron-hole separation. This paper suggests a dual-functional composite catalyst for photocatalytic hydrogen evolution and benzaldehyde production, and provides a new strategy for preventing the photogenerated electrons and holes from recombining by constructing a 0D/2D heterojunction with increased SB sites.

Keywords

Cd0.5Zn0.5STi3C2photocatalysishydrogenbenzaldehydeSchottky heterojunction

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References

[1]
Wang L, Jin PX, Huang JW, et al. Integration of copper(II)-porphyrin zirconium metal-organic framework and titanium dioxide to construct Z-scheme system for highly improved photocatalytic CO2 reduction. ACS Sustain Chem Eng 2019, 7: 15660-15670.
Crossref Google Scholar
[2]
Jiang ZF, Wan WM, Li HM, et al. A hierarchical Z-scheme α-Fe2O3/g-C3N4 hybrid for enhanced photocatalytic CO2 reduction. Adv Mater 2018, 30: 1706108.
Crossref Google Scholar
[3]
Wu XJ, Luo NC, Xie SJ, et al. Photocatalytic transformations of lignocellulosic biomass into chemicals. Chem Soc Rev 2020, 49: 6198-6223.
Crossref Google Scholar
[4]
Shimura K, Yoshida H. Heterogeneous photocatalytic hydrogen production from water and biomass derivatives. Energy Environ Sci 2011, 4: 2467-2481.
Crossref Google Scholar
[5]
Yu HG, Yuan RR, Gao DD, et al. Ethyl acetate-induced formation of amorphous MoSx nanoclusters for improved H2-evolution activity of TiO2 photocatalyst. Chem Eng J 2019, 375: 121934.
Crossref Google Scholar
[6]
Huang YC, Guo ZJ, Liu H, et al. Heterojunction architecture of N-doped WO3 nanobundles with Ce2S3 nanodots hybridized on a carbon textile enables a highly efficient flexible photocatalyst. Adv Funct Mater 2019, 29: 1903490.
Crossref Google Scholar
[7]
Wu LY, Mu YF, Guo XX, et al. Encapsulating perovskite quantum dots in iron-based metal-organic frameworks (MOFs) for efficient photocatalytic CO2 reduction. Angew Chem Int Ed 2019, 58: 9491-9495.
Crossref Google Scholar
[8]
Liu XY, Chen H, Wang RL, et al. 0D-2D quantum dot: Metal dichalcogenide nanocomposite photocatalyst achieves efficient hydrogen generation. Adv Mater 2017, 29: 1605646.
Crossref Google Scholar
[9]
Huang JR, Tao JN, Liu GW, et al. In situ construction of 1D CdS/2D Nb2CTx MXene Schottky heterojunction for enhanced photocatalytic hydrogen production activity. Appl Surf Sci 2022, 573: 151491.
Crossref Google Scholar
[10]
Ye W, Chen SM, Lin Y, et al. Precisely tuning the number of Fe atoms in clusters on N-doped carbon toward acidic oxygen reduction reaction. Chem 2019, 5: 2865-2878.
Crossref Google Scholar
[11]
Tao JN, Yu XH, Liu QQ, et al. Internal electric field induced S-scheme heterojunction MoS2/CoAl LDH for enhanced photocatalytic hydrogen evolution. J Colloid Interface Sci 2021, 585: 470-479.
Crossref Google Scholar
[12]
Xu QL, Zhang LY, Cheng B, et al. S-scheme heterojunction photocatalyst. Chem 2020, 6: 1543-1559.
Crossref Google Scholar
[13]
Liao GF, Gong Y, Zhang L, et al. Semiconductor polymeric graphitic carbon nitride photocatalysts: The “holy grail” for the photocatalytic hydrogen evolution reaction under visible light. Energy Environ Sci 2019, 12: 2080-2147.
Crossref Google Scholar
[14]
Ismael M, Wark M. Photocatalytic activity of CoFe2O4/ g-C3N4 nanocomposite toward degradation of different organic pollutants and their inactivity toward hydrogen production: The role of the conduction band position. FlatChem 2022, 32: 100337.
Crossref Google Scholar
[15]
Zhang Y, Liu ZR, Guo CY, et al. CdS(ZB)/CdS(WZ)/ Ni-BTC photocatalytic selective oxidation of benzyl alcohol to benzaldehyde coupled with hydrogen evolution. Appl Surf Sci 2022, 571: 151284.
Crossref Google Scholar
[16]
Li PX, Yan XY, Gao SY, et al. Boosting photocatalytic hydrogen production coupled with benzyl alcohol oxidation over CdS/metal-organic framework composites. Chem Eng J 2021, 421: 129870.
Crossref Google Scholar
[17]
Shen MC, Shi YZ, Wang ZW, et al. Enhanced photocatalytic benzyl alcohol oxidation over Bi4Ti3O12 ultrathin nanosheets. J Colloid Interface Sci 2022, 608: 2529-2538.
Crossref Google Scholar
[18]
Hu Y, Yu XH, Liu QQ, et al. Highly metallic Co-doped MoS2 nanosheets as an efficient cocatalyst to boost photoredox dual reaction for H2 production and benzyl alcohol oxidation. Carbon 2022, 188: 70-80.
Crossref Google Scholar
[19]
Hao HC, Zhang L, Wang WZ, et al. Photocatalytic hydrogen evolution coupled with efficient selective benzaldehyde production from benzyl alcohol aqueous solution over ZnS-NixSy composites. ACS Sustain Chem Eng 2019, 7: 10501-10508.
Crossref Google Scholar
[20]
Liu JF, Zheng XZ, Pan LL, et al. Efficient photocatalytic H2 production coupling with selective oxidation of aromatic alcohol under carbon neutrality. Appl Catal B: Environ 2021, 298: 120619.
Crossref Google Scholar
[21]
Shen RC, Ding YN, Li SB, et al. Constructing low-cost Ni3C/twin-crystal Zn0.5Cd0.5S heterojunction/homojunction nanohybrids for efficient photocatalytic H2 evolution. Chin J Catal 2021, 42: 25-36.
Crossref Google Scholar
[22]
Yang HL, Tang JQ, Luo Y, et al. MOFs-derived fusiform In2O3 mesoporous nanorods anchored with ultrafine CdZnS nanoparticles for boosting visible-light photocatalytic hydrogen evolution. Small 2021, 17: 2102307.
Crossref Google Scholar
[23]
Liu H, Su P, Jin ZL, et al. Enhanced hydrogen evolution over sea-urchin-structure NiCoP decorated ZnCdS photocatalyst. Catal Lett 2020, 150: 2937-2950.
Crossref Google Scholar
[24]
Song LM, Zhang SJ, Liu D, et al. High-performance hydrogen evolution of NiB/ZnCdS under visible light irradiation. Int J Hydrogen Energy 2020, 45: 8234-8242.
Crossref Google Scholar
[25]
Gong HM, Zhang XJ, Wang GR, et al. Dodecahedron ZIF-67 anchoring ZnCdS particles for photocatalytic hydrogen evolution. Mol Catal 2020, 485: 110832.
Crossref Google Scholar
[26]
Zeng GC, Cao Y, Wu YX, et al. Cd0.5Zn0.5S/Ti3C2 MXene as a Schottky catalyst for highly efficient photocatalytic hydrogen evolution in seawater. Appl Mater Today 2021, 22: 100926.
Crossref Google Scholar
[27]
Fu JW, Zhu BC, You W, et al. A flexible bio-inspired H2-production photocatalyst. Appl Catal B: Environ 2018, 220: 148-160.
Crossref Google Scholar
[28]
Shao YQ, Feng KK, Guo J, et al. Electronic structure and enhanced photoelectrocatalytic performance of RuxZn1-xO/Ti electrodes. J Adv Ceram 2021, 10: 1025-1041.
Crossref Google Scholar
[29]
Liu X, Zhao YX, Yang XF, et al. Porous Ni5P4 as a promising cocatalyst for boosting the photocatalytic hydrogen evolution reaction performance. Appl Catal B: Environ 2020, 275: 119144.
Crossref Google Scholar
[30]
Ganguly P, Harb M, Cao Z, et al. 2D nanomaterials for photocatalytic hydrogen production. ACS Energy Lett 2019, 4: 1687-1709.
Crossref Google Scholar
[31]
Zheng ZX, Wu W, Yang T, et al. In situ reduced MXene/AuNPs composite toward enhanced charging/ discharging and specific capacitance. J Adv Ceram 2021, 10: 1061-1071.
Crossref Google Scholar
[32]
Anasori B, Lukatskaya MR, Gogotsi Y. 2D metal carbides and nitrides (MXenes) for energy storage. Nat Rev Mater 2017, 2: 16098.
Crossref Google Scholar
[33]
Hou HL, Shao G, Yang WY. Recent advances in g-C3N4-based photocatalysts incorporated by MXenes and their derivatives. J Mater Chem A 2021, 9: 13722-13745.
Crossref Google Scholar
[34]
Cao SW, Shen BJ, Tong T, et al. 2D/2D heterojunction of ultrathin MXene/Bi2WO6 nanosheets for improved photocatalytic CO2 reduction. Adv Funct Mater 2018, 28: 1800136.
Crossref Google Scholar
[35]
Liu SW, Wang MY, Liu GW, et al. Enhanced NO2 gas-sensing performance of 2D Ti3C2/TiO2 nanocomposites by in-situ formation of Schottky barrier. Appl Surf Sci 2021, 567: 150747.
Crossref Google Scholar
[36]
Zhou AG, Liu Y, Li SB, et al. From structural ceramics to 2D materials with multi-applications: A review on the development from MAX phases to MXenes. J Adv Ceram 2021, 10: 1194-1242.
Crossref Google Scholar
[37]
Peng JH, Chen XZ, Ong WJ, et al. Surface and heterointerface engineering of 2D MXenes and their nanocomposites: Insights into electro- and photocatalysis. Chem 2019, 5: 18-50.
Crossref Google Scholar
[38]
Li ZP, Huang WX, Liu JX, et al. Embedding CdS@Au into ultrathin Ti3-xC2Ty to build dual Schottky barriers for photocatalytic H2 production. ACS Catal 2021, 11: 8510-8520.
Crossref Google Scholar
[39]
Li JM, Zhao L, Wang SM, et al. In situ fabrication of 2D/3D g-C3N4/Ti3C2 (MXene) heterojunction for efficient visible-light photocatalytic hydrogen evolution. Appl Surf Sci 2020, 515: 145922.
Crossref Google Scholar
[40]
Cheng L, Chen Q, Li J, et al. Boosting the photocatalytic activity of CdLa2S4 for hydrogen production using Ti3C2 MXene as a co-catalyst. Appl Catal B: Environ 2020, 267: 118379.
Crossref Google Scholar
[41]
Lin PY, Shen J, Yu XH, et al. Construction of Ti3C2 MXene/O-doped g-C3N4 2D-2D Schottky-junction for enhanced photocatalytic hydrogen evolution. Ceram Int 2019, 45: 24656-24663.
Crossref Google Scholar
[42]
Yang WX, Ma GZ, Fu Y, et al. Rationally designed Ti3C2 MXene@TiO2/CuInS2 Schottky/S-scheme integrated heterojunction for enhanced photocatalytic hydrogen evolution. Chem Eng J 2022, 429: 132381.
Crossref Google Scholar
[43]
Li JY, Wang ZY, Chen HY, et al. A surface-alkalinized Ti3C2 MXene as an efficient cocatalyst for enhanced photocatalytic CO2 reduction over ZnO. Catal Sci Technol 2021, 11: 4953-4961.
Crossref Google Scholar
[44]
Hu JM, Ding J, Zhong Q. Ultrathin 2D Ti3C2 MXene co-catalyst anchored on porous g-C3N4 for enhanced photocatalytic CO2 reduction under visible-light irradiation. J Colloid Interface Sci 2021, 582: 647-657.
Crossref Google Scholar
[45]
Zhong T, Yu ZB, Jiang RH, et al. Surface-activated Ti3C2Tx MXene cocatalyst assembled with CdZnS-formed 0D/2D CdZnS/Ti3C2-A40 Schottky heterojunction for enhanced photocatalytic hydrogen evolution. Sol RRL 2022, 6: 2100863.
Crossref Google Scholar
[46]
Ding MY, Xiao R, Zhao CX, et al. Evidencing interfacial charge transfer in 2D CdS/2D MXene Schottky heterojunctions toward high-efficiency photocatalytic hydrogen production. Sol RRL 2021, 5: 2000414.
Crossref Google Scholar
[47]
Liu QQ, Huang JX, Tang H, et al. Construction 0D TiO2 nanoparticles/2D CoP nanosheets heterojunctions for enhanced photocatalytic H2 evolution activity. J Mater Sci Technol 2020, 56: 196-205.
Crossref Google Scholar
[48]
Kresse G, Furthmüller J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B 1996, 54: 11169-11186.
Crossref Google Scholar
[49]
Perdew JP, Burke K, Ernzerhof M. Generalized gradient approximation made simple. Phys Rev Lett 1996, 77: 3865-3868.
Crossref Google Scholar
[50]
Kresse G, Joubert D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys Rev B 1999, 59: 1758-1775.
Crossref Google Scholar
[51]
Ismael M, Elhaddad E, Wark M. Construction of SnO2/g-C3N4 composite photocatalyst with enhanced interfacial charge separation and high efficiency for hydrogen production and Rhodamine B degradation. Colloid Surface A 2022, 638: 128288.
Crossref Google Scholar
[52]
Liu YP, Li YH, Li XY, et al. Regulating electron-hole separation to promote photocatalytic H2 evolution activity of nanoconfined Ru/MXene/TiO2 catalysts. ACS Nano 2020, 14: 14181-14189.
Crossref Google Scholar
[53]
Wang H, Sun YM, Wu Y, et al. Electrical promotion of spatially photoinduced charge separation via interfacial-built-in quasi-alloying effect in hierarchical Zn2In2S5/ Ti3C2(O,OH)x hybrids toward efficient photocatalytic hydrogen evolution and environmental remediation. Appl Catal B: Environ 2019, 245: 290-301.
Crossref Google Scholar
[54]
Peng C, Yang XF, Li YH, et al. Hybrids of two-dimensional Ti3C2 and TiO2 exposing {001} facets toward enhanced photocatalytic activity. ACS Appl Mater Interfaces 2016, 8: 6051-6060.
Crossref Google Scholar
[55]
Low JX, Zhang LY, Tong T, et al. TiO2/MXene Ti3C2 composite with excellent photocatalytic CO2 reduction activity. J Catal 2018, 361: 255-266.
Crossref Google Scholar
[56]
Fiqar Z, Tao JN, Yang T, et al. Designing 0D/2D CdS nanoparticles/g-C3N4 nanosheets heterojunction as efficient photocatalyst for improved H2-evolution. Surf Interfaces 2021, 26: 101312.
Crossref Google Scholar
[57]
Ismael M. Highly effective ruthenium-doped TiO2 nanoparticles photocatalyst for visible-light-driven photocatalytic hydrogen production. New J Chem 2019, 43: 9596-9605.
Crossref Google Scholar
[58]
Hao XQ, Xiang DZ, Jin ZL. Amorphous Co3O4 quantum dots hybridizing with 3D hexagonal CdS single crystals to construct a 0D/3D p-n heterojunction for a highly efficient photocatalytic H2 evolution. Dalton Trans 2021, 50: 10501-10514.
Crossref Google Scholar
[59]
Xu JX, Yan XM, Qi YH, et al. Novel phosphidated MoS2 nanosheets modified CdS semiconductor for an efficient photocatalytic H2 evolution. Chem Eng J 2019, 375: 122053.
Crossref Google Scholar
[60]
Xiang DZ, Hao XQ, Jin ZL. Cu/CdS/MnOx nanostructure-based photocatalyst for photocatalytic hydrogen evolution. ACS Appl Nano Mater 2021, 4: 13848-13860.
Crossref Google Scholar
[61]
Li DG, Huang JX, Li RB, et al. Synthesis of a carbon dots modified g-C3N4/SnO2 Z-scheme photocatalyst with superior photocatalytic activity for PPCPs degradation under visible light irradiation. J Hazard Mater 2021, 401: 123257.
Crossref Google Scholar
[62]
Lei XF, Xu TH, Yao WF, et al. Hollow hydroxyapatite microspheres modified by CdS nanoparticles for efficiently photocatalytic degradation of tetracycline. J Taiwan Inst Chem Eng 2020, 106: 148-158.
Crossref Google Scholar
[63]
Gao JF, Zhang FD, Xue HQ, et al. In-situ synthesis of novel ternary CdS/PdAg/g-C3N4 hybrid photocatalyst with significantly enhanced hydrogen production activity and catalytic mechanism exploration. Appl Catal B: Environ 2021, 281: 119509.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 7,
July 2022
Pages 1117-1130
DOI: 10.1007/s40145-022-0598-y
Cite this article:
TAO J, WANG M, LIU G, et al. Efficient photocatalytic hydrogen evolution coupled with benzaldehyde production over 0D Cd0.5Zn0.5S/2D Ti3C2 Schottky heterojunction. Journal of Advanced Ceramics, 2022, 11(7): 1117-1130. https://doi.org/10.1007/s40145-022-0598-y

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Received: 21 January 2022
Revised: 30 March 2022
Accepted: 07 April 2022
Published: 04 June 2022
© The Author(s) 2022.

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