AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (1.1 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Field-driven merging of polarizations and enhanced electrocaloric effect in BaTiO3-based lead-free ceramics

Xiang NIUa,†, Xiaodong JIANa,c,†( ), Weiping GONGb, Wei LIANGa, Xuetian GONGe, Guangzu ZHANGe, Shenglin JIANGe, Kun YUa, Xiaobo ZHAOa,d, Yingbang YAOa,d, Tao TAOa,d, Bo LIANGa,d, Sheng-Guo LUa,d( )
Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, China
Science and Technology on Reliability Physics and Application of Electronic Component Laboratory, The 5th Electronics Research Institute of the Ministry of Industry and Information Technology, Guangzhou 510610, China
Dongguan South China Design Innovation Institute, Dongguan 523808, China
School of Optical and Electronic Information, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China

† Xiang Niu and Xiaodong Jian contributed equally to this work.

Show Author Information

Graphical Abstract

Abstract

Solid-state cooling technology based on electrocaloric effect (ECE) has been advanced as an alternative to replace the vapour-compression approach to overcome the releasing of the global warming gases. However, the development in high ECE materials is still a challenge. In this work, polarization merging strategy was proposed to achieve a large ECE in xBa(Sn0.07Ti0.93)O3–(1−x)Ba(Hf0.1Ti0.9)O3 ferroelectric ceramics, where x = 0, 0.2, 0.4, 0.6, 0.8, and 1. Ba(Sn0.07Ti0.93)O3 with an orthorhombic phase and Ba(Hf0.1Ti0.9)O3 with a rhombohedral phase at room temperature were prepared beforehand as precursors, and phase-coexisted xBSnT–(1−x)BHfT ceramics were formed via a solid-state reaction approach. Phase coexisting structures were confirmed using the X-ray diffraction. The merged polarization was confirmed by the dielectric and ferroelectric properties. Optimal ECEs were obtained for 0.2BSnT–0.8BHfT ceramics, i.e., adiabatic temperature change ΔT = 2.16±0.08 K at 80 ℃ and 5 MV/m, and ΔT = 3.35±0.09 K at 80 ℃ and 7 MV/m.

Keywords

lead-free ferroelectricmicrostructurepermittivitypolarizationelectrocaloric effect (ECE)

Electronic Supplementary Material

Download File(s)
40145_0647_ESM.pdf (2.5 MB)

References

[1]
Pakhomov OV, Karmanenko SF, Semenov AA, et al. Thermodynamic estimation of cooling efficiency using an electrocaloric solid-state line. Tech Phys 2010, 55: 1155–1160.
Google Scholar
[2]
Li ZN, Shen B, Gluesenkamp KR. Multi-objective optimization of low-GWP mixture composition and heat exchanger circuitry configuration for improved system performance and reduced refrigerant flammability. Int J Refrig 2021, 126: 133–142.
Google Scholar
[3]
Mischenko AS, Zhang Q, Scott JF, et al. Giant electrocaloric effect in thin-film PbZr0.95Ti0.05O3. Science 2006, 311: 1270–1271.
Google Scholar
[4]
Neese B, Chu BJ, Lu SG, et al. Large electrocaloric effect in ferroelectric polymers near room temperature. Science 2008, 321: 821–823.
Google Scholar
[5]
Shi JY, Han DL, Li ZC, et al. Electrocaloric cooling materials and devices for zero-global-warming-potential, high-efficiency refrigeration. Joule 2019, 3: 1200–1225.
Google Scholar
[6]
Ma RJ, Zhang ZY, Tong K, et al. Highly efficient electrocaloric cooling with electrostatic actuation. Science 2017, 357: 1130–1134.
Google Scholar
[7]
Rožič B, Kutnjak Z, Neese B, et al. Electrocaloric effect in the relaxor ferroelectric polymer composition P(VDF–TrFE–CFE)0.90–P(VDF–CTFE)0.10. Phase Transit 2010, 83: 819–823.
Google Scholar
[8]
Lu SG, Rožič B, Zhang QM, et al. Enhanced electrocaloric effect in ferroelectric poly(vinylidene-fluoride/trifluoroethylene) 55/45 mol% copolymer at ferroelectric–paraelectric transition. Appl Phys Lett 2011, 98: 122906.
Google Scholar
[9]
Li XY, Qian XS, Gu HM, et al. Giant electrocaloric effect in ferroelectric poly(vinylidenefluoride-trifluoroethylene) copolymers near a first-order ferroelectric transition. Appl Phys Lett 2012, 101: 132903.
Google Scholar
[10]
Sebald G, Seveyrat L, Capsal JF, et al. Differential scanning calorimeter and infrared imaging for electrocaloric characterization of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) terpolymer. Appl Phys Lett 2012, 101: 022907.
Google Scholar
[11]
Nair B, Usui T, Crossley S, et al. Large electrocaloric effects in oxide multilayer capacitors over a wide temperature range. Nature 2019, 575: 468–472.
Crossref Google Scholar
[12]
Yin RW, Li JJ, Su XP, et al. Emergent enhanced electrocaloric effect within wide temperature span in laminated composite ceramics. Adv Funct Mater 2022, 32: 2108182.
Crossref Google Scholar
[13]
Qian XS, Han DL, Zheng LR, et al. High-entropy polymer produces a giant electrocaloric effect at low fields. Nature 2021, 600: 664–669.
Crossref Google Scholar
[14]
Chen X, Li SQ, Jian XD, et al. Maxwell relation, giant (negative) electrocaloric effect, and polarization hysteresis. Appl Phys Lett 2021, 118: 122904.
Crossref Google Scholar
[15]
Lu B, Jian XD, Lin XW, et al. Enhanced electrocaloric effect in 0.73Pb(Mg1/3Nb2/3)O3–0.27PbTiO3 single crystals via direct measurement. Crystals 2020, 10: 451.
Crossref Google Scholar
[16]
Li JJ, Li JT, Qin SQ, et al. Effects of long- and short-range ferroelectric order on the electrocaloric effect in relaxor ferroelectric ceramics. Phys Rev Appl 2019, 11: 044032.
Crossref Google Scholar
[17]
Li F, Li K, Long MS, et al. Ferroelectric-relaxor crossover induce large electrocaloric effect with ultrawide temperature span in NaNbO3-based lead-free ceramics. Appl Phys Lett 2021, 118: 043902.
Crossref Google Scholar
[18]
Li F, Chen GR, Liu X, et al. Phase-composition and temperature dependence of electrocaloric effect in lead-free Bi0.5Na0.5TiO3–BaTiO3–(Sr0.7Bi0.2□0.1)TiO3 ceramics. J Eur Ceram Soc 2017, 37: 4732–4740.
Google Scholar
[19]
Li F, Li JH, Zhai JW, et al. Influence of structural evolution on electrocaloric effect in Bi0.5Na0.5TiO3–SrTiO3 ferroelectric ceramics. J Appl Phys 2018, 124: 164108.
Google Scholar
[20]
Kimmel AV, Gindele OT, Duffy DM, et al. Giant electrocaloric effect at the antiferroelectric-to-ferroelectric phase boundary in Pb(ZrxTi1−x)O3. Appl Phys Lett 2019, 115: 023902.
Crossref Google Scholar
[21]
Wu HH, Cohen RE. Electric-field-induced phase transition and electrocaloric effect in PMN–PT. Phys Rev B 2017, 96: 054116.
Crossref Google Scholar
[22]
Zhu Z, Tang XG, Jiang YP, et al. Giant electrocaloric effect in lead zinc niobate titanate single crystal. J Alloys Compd 2017, 710: 297–301.
Crossref Google Scholar
[23]
Wang HL, Zhang FF, Chen Y, et al. Giant piezoelectric coefficient of PNN–PZT-based relaxor piezoelectric ceramics by constructing an R–T MPB. Ceram Int 2021, 47: 12284–12291.
Crossref Google Scholar
[24]
Gao B, Yao ZH, Lai DY, et al. Unexpectedly high piezoelectric response in Sm-doped PZT ceramics beyond the morphotropic phase boundary region. J Alloys Compd 2020, 836: 155474.
Crossref Google Scholar
[25]
Soares MR, Senos AMR, Mantas PQ. Phase coexistence region and dielectric properties of PZT ceramics. J Eur Ceram Soc 2000, 20: 321–334.
Crossref Google Scholar
[26]
Zhao XY, Fang BJ, Cao H, et al. Dielectric and piezoelectric performance of PMN–PT single crystals with compositions around the MPB: Influence of composition, poling field and crystal orientation. Mater Sci Eng B 2002, 96: 254–262.
Crossref Google Scholar
[27]
Kumar P, Sharma S, Thakur OP, et al. Dielectric, piezoelectric and pyroelectric properties of PMN–PT (68:32) system. Ceram Int 2004, 30: 585–589.
Crossref Google Scholar
[28]
Li Q, Zhang YL, Xia ZG, et al. MPB design and crystal growth of PMN–PT–PZ relaxor ferroelectrics. J Cryst Growth 2011, 318: 851–855.
Crossref Google Scholar
[29]
Kumar P, Singh S, Thakur OP, et al. Effect of compositional modifications on dielectric, ferroelectric and pyroelectric response of PMN–PT solid solutions near MPB. Mod Phys Lett B 2006, 20: 1335–1342.
Crossref Google Scholar
[30]
Heitmann AA, Rossetti GA. Thermodynamics of ferroelectric solid solutions with morphotropic phase boundaries. J Am Ceram Soc 2014, 97: 1661–1685.
Crossref Google Scholar
[31]
Jian XD, Lu B, Li DD, et al. Direct measurement of large electrocaloric effect in Ba(ZrxTi1−x)O3 ceramics. ACS Appl Mater Interfaces 2018, 10: 4801–4807.
Crossref Google Scholar
[32]
Yao YG, Zhou C, Lv DC, et al. Large piezoelectricity and dielectric permittivity in BaTiO3–xBaSnO3 system: The role of phase coexisting. EPL-Europhys Lett 2012, 98: 27008.
Crossref Google Scholar
[33]
Xu GY, Zhong Z, Bing Y, et al. Electric-field-induced redistribution of polar nano-regions in a relaxor ferroelectric. Nat Mater 2006, 5: 134–140.
Crossref Google Scholar
[34]
Sanlialp M, Shvartsman VV, Lupascu DC, et al. Direct electrocaloric measurements using a differential scanning calorimeter. In: Proceedings of the 2015 Joint IEEE International Symposium on the Applications of Ferroelectric (ISAF), International Symposium on Integrated Functionalities (ISIF), and Piezoelectric Force Microscopy Workshop (PFM). Singapore: IEEE, 2015: 159–162.
Crossref
[35]
Sanlialp M, Molin C, Shvartsman VV, et al. Modified differential scanning calorimeter for direct electrocaloric measurements. IEEE Trans Ultrason Ferroelectr Freq Control 2016, 63: 1690–1696.
Crossref Google Scholar
[36]
Lu SG, Li DD, Lin XW, et al. Influence of electric field on the phenomenological coefficient and electrocaloric strength in ferroelectrics. Acta Phys Sin 2020, 69: 127701.
Crossref Google Scholar
[37]
Niu X, Jian XD, Chen XY, et al. Enhanced electrocaloric effect at room temperature in Mn2+ doped lead-free (BaSr)TiO3 ceramics via a direct measurement. J Adv Ceram 2021, 10: 482–492.
Crossref Google Scholar
[38]
Tang H, Niu X, Zhao PF, et al. Large energy-storage density and positive electrocaloric effect in xBiFeO3–(1−x)BaTiO3 relaxor ferroelectric ceramics. J Mater Chem C 2022, 10: 1302–1312.
Crossref Google Scholar
[39]
Qian XS, Ye HJ, Zhang YT, et al. Giant electrocaloric response over a broad temperature range in modified BaTiO3 ceramics. Adv Funct Mater 2014, 24: 1300–1305.
Crossref Google Scholar
[40]
Jian XD, Lu B, Li DD, et al. Enhanced electrocaloric effect in Sr2+-modified lead-free BaZrxTi1−xO3 ceramics. ACS Appl Mater Interfaces 2019, 11: 20167–20173.
Crossref Google Scholar
[41]
Zhang L, Zhao CL, Zheng T, et al. Large electrocaloric effect in (Bi0.5Na0.5)TiO3-based relaxor ferroelectrics. ACS Appl Mater Interfaces 2020, 12: 33934–33940.
Crossref Google Scholar
[42]
Le Goupil F, McKinnon R, Koval V, et al. Tuning the electrocaloric enhancement near the morphotropic phase boundary in lead-free ceramics. Sci Rep 2016, 6: 28251.
Crossref Google Scholar
[43]
Rožič B, Malič B, Uršič H, et al. Direct measurements of the electrocaloric effect in bulk PbMg1/3Nb2/3O3 (PMN) ceramics. Ferroelectrics 2011, 421: 103–107.
Crossref Google Scholar
[44]
Zhang GZ, Chen M, Fan BY, et al. High electrocaloric effect in hot-pressed Pb0.85La0.1(Zr0.65Ti0.35)O3 ceramics with a wide operating temperature range. J Am Ceram Soc 2017, 100: 4581–4589.
Crossref Google Scholar
[45]
Lu B, Yao YB, Jian XD, et al. Enhancement of the electrocaloric effect over a wide temperature range in PLZT ceramics by doping with Gd3+ and Sn4+ ions. J Eur Ceram Soc 2019, 39: 1093–1102.
Crossref Google Scholar
[46]
Yang JL, Zhao Y, Lou XJ, et al. Synergistically optimizing electrocaloric effects and temperature span in KNN-based ceramics utilizing a relaxor multiphase boundary. J Mater Chem C 2020, 8: 4030–4039.
Crossref Google Scholar
[47]
Yang JL, Hao XH. Electrocaloric effect and pyroelectric performance in (K,Na)NbO3-based lead-free ceramics. J Am Ceram Soc 2019, 102: 6817–6826.
Crossref Google Scholar
[48]
Rožič B, Koruza J, Kutnjak Z, et al. The electrocaloric effect in lead-free K0.5Na0.5NbO3–SrTiO3 ceramics. Ferroelectrics 2013, 446: 39–45.
Crossref Google Scholar
[49]
Tao H, Yin J, Zhao CL, et al. Large electrocaloric effect under electric field behavior in potassium sodium niobate ceramics with incompletely overlapped phase boundaries. J Mater Chem A 2022, 10: 5262–5272.
Crossref Google Scholar
[50]
Zhu HF, Yang YL, Ren W, et al. Rhombohedral BiFeO3 thick films integrated on Si with a giant electric polarization and prominent piezoelectricity. Acta Mater 2020, 200: 305–314.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 11,
November 2022
Pages 1777-1788
DOI: 10.1007/s40145-022-0647-6
Cite this article:
NIU X, JIAN X, GONG W, et al. Field-driven merging of polarizations and enhanced electrocaloric effect in BaTiO3-based lead-free ceramics. Journal of Advanced Ceramics, 2022, 11(11): 1777-1788. https://doi.org/10.1007/s40145-022-0647-6

1058

Views

76

Downloads

17

Crossref

22

Web of Science

24

Scopus

4

CSCD

Altmetrics
Received: 08 May 2022
Revised: 04 August 2022
Accepted: 17 August 2022
Published: 05 November 2022
© The Author(s) 2022.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return