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Research Article | Open Access

Layer-structured Cr/CrxN coating via electroplating-based nitridation achieving high deuterium resistance as the hydrogen permeation barrier

Liyu ZHENG1, Heping LI1( ), Jun ZHOU1, Xinluo TIAN1, Zhongyang ZHENG1, Long WANG2, Xinyun WANG1, Youwei YAN1
State Key Laboratory of Materials Processing and Die & Mould Technology, International Joint Research Laboratory of Magnetic Confinement Fusion and Plasma Physics, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Southwestern Institute of Physics, Chengdu 610225, China
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Graphical Abstract

Abstract

Hydrogen isotope permeation through structural materials is a key issue for developing nuclear fusion energy, which will cause fuel loss and radioactive pollution. Developing ceramic coatings with high thermal shock and hydrogen resistance is an effective strategy to solve this issue. In this work, a layer-structured Cr/CrxN coating was successfully fabricated by a facile electroplating-based nitridation technique, which is easy, facile, and applicable to coating complex-shaped substrates. The Cr/CrxN coating, composed of a bottom Fe/Cr interdiffusion zone, a middle Cr layer, and a top CrxN layer, exhibits high bonding strength, high anti-thermal-shock ability, and high deuterium permeation resistance. Its bonding strength achieves 43.6 MPa. The Cr/CrxN coating remains intact even after suffering 300 thermal shock cycles under a 600 ℃–water condition. Through optimizing the nitridation temperature, the Cr/CrxN coating achieves a deuterium permeation reduction factor (PRF) as high as 3599 at 500 ℃. Considering its scalable fabrication technique and considerable properties, the developed Cr/CrxN coating may serve as a novel high-performance hydrogen permeation barrier in various fields.

Keywords

hydrogen permeationCrxNCrelectrodepositionthermal shock resistance

References

[1]
Oshiro K, Fujimori S. Role of hydrogen-based energy carriers as an alternative option to reduce residual emissions associated with mid-century decarbonization goals. Appl Energy 2022, 313: 118803.
Crossref Google Scholar
[2]
Feitosa FEB, Costa AL. Application of a multicriteria methodology for evaluation of energy alternatives for hydrogen production for the automotive sector—Case study. Int J Hydrogen Energ 2021, 46: 20799–20814.
Crossref Google Scholar
[3]
Dwivedi SK, Vishwakarma M. Hydrogen embrittlement in different materials: A review. Int J Hydrogen Energ 2018, 43: 21603–21616.
Crossref Google Scholar
[4]
Liu LF, Zhai CQ, Lu C, et al. Study of the effect of δ phase on hydrogen embrittlement of Inconel 718 by notch tensile tests. Corros Sci 2005, 47: 355–367.
Crossref Google Scholar
[5]
Hollenberg GW, Simonen EP, Kalinin G, et al. Tritium/ hydrogen barrier development. Fusion Eng Des 1995, 28: 190–208.
Crossref Google Scholar
[6]
Zhang Y, Sun SK, Guo WM, et al. Optimal preparation of high-entropy boride–silicon carbide ceramics. J Adv Ceram 2021, 10: 173–180.
Crossref Google Scholar
[7]
Lu CX, Li HP, Liu XB, et al. Facile fabrication and microstructure of α-Al2O3/TiC composite coating as tritium permeation barrier. Int J Appl Ceram Technol 2015, 12: E215–E221.
Crossref Google Scholar
[8]
Li FJ, Zheng ZY, Wang XY, et al. Horizontally aligned BN nanosheet array for nanometer-thick ZrO2 coating with greatly enhanced anticorrosion and hydrogen isotope resistance property. Chem Eng J 2022, 440: 135920.
Crossref Google Scholar
[9]
Cao W, Ge S, Song JF, et al. A deuterium permeation barrier by hot-dipping aluminizing on AISI321 steel. Int J Hydrogen Energ 2016, 41: 23125–23131.
Crossref Google Scholar
[10]
Zheng ZY, Li HP, Li FJ, et al. An efficient PDA/Al2O3 nanosheets reinforced ultra-thin ZrO2 coating with attractive anti-corrosion and deuterium resistance property. Chem Eng J 2022, 450: 138307.
Crossref Google Scholar
[11]
Zhou QY, Ling YH, Lu ZX, et al. Effect of helium implantation on the hydrogen retention of Cr2O3 films formed in an ultra-low oxygen environment. Int J Hydrogen Energ 2019, 44: 26685–26697.
Crossref Google Scholar
[12]
Tanaka T, Chikada T, Hishinuma Y, et al. Formation of Cr2O3 layers on coolant duct materials for suppression of hydrogen permeation. Fusion Eng Des 2017, 124: 1046–1051.
Crossref Google Scholar
[13]
Yang JY, Chen H, Zhang JS, et al. Preparation of Er2O3 coating on a low activation martensitic steel substrate via the route of sol–gel. Surf Coat Technol 2011, 205: 5497–5501.
Crossref Google Scholar
[14]
Li Q, Wang J, Xiang QY, et al. Novel nano-crystalline Er2O3 hydrogen isotopes permeation barriers. J Eur Ceram Soc 2017, 37: 249–254.
Crossref Google Scholar
[15]
Chikada T, Matsunaga M, Horikoshi S, et al. Fabrication technology development and characterization of tritium permeation barriers by a liquid phase method. Fusion Eng Des 2018, 136: 215–218.
Crossref Google Scholar
[16]
Engels J, Houben A, Hansen P, et al. Influence of the grain structure of yttria thin films on the hydrogen isotope permeation. Int J Hydrogen Energ 2018, 43: 22976–22985.
Crossref Google Scholar
[17]
Sun YN, Xiang HM, Dai FZ, et al. Preparation and properties of CMAS resistant bixbyite structured high-entropy oxides RE2O3 (RE = Sm, Eu, Er, Lu, Y, and Yb): Promising environmental barrier coating materials for Al2O3f/Al2O3 composites. J Adv Ceram 2021, 10: 596–613.
Crossref Google Scholar
[18]
Wang L, Wu YY, Luo XF, et al. Effects of Ar/O2 ratio on preparation and properties of multilayer Cr2O3/α-Al2O3 tritium permeation barrier. Surf Coat Technol 2018, 339: 132–138.
Crossref Google Scholar
[19]
Zhong XC, Liu F, Li XF. Transient response of a magnetoelectroelastic solid with two collinear dielectric cracks under impacts. Int J Solids Struct 2009, 46: 2950–2958.
Crossref Google Scholar
[20]
Crisan O, Crisan AD. Incipient low-temperature formation of MAX phase in Cr–Al–C films. J Adv Ceram 2018, 7: 143–151.
Crossref Google Scholar
[21]
Xiang HM, Xing Y, Dai FZ, et al. High-entropy ceramics: Present status, challenges, and a look forward. J Adv Ceram 2021, 10: 385–441.
Crossref Google Scholar
[22]
Lu W, Wang J, Pu WJ, et al. Corrosion resistance of ceramic candidates for tritium permeation barriers exposed to molten lithium. Corros Sci 2019, 160: 108172.
Crossref Google Scholar
[23]
Obrosov A, Sutygina AN, Volinsky AA, et al. Effect of hydrogen exposure on mechanical and tribological behavior of CrxN coatings deposited at different pressures on IN718. Materials 2017, 10: 563.
Crossref Google Scholar
[24]
Sidelev DV, Syrtanov MS, Ruchkin SE, et al. Protection of Zr alloy under high-temperature air oxidation: A multilayer coating approach. Coatings 2021, 11: 227.
Crossref Google Scholar
[25]
Shen HY, Wang L, Sun JC. Characteristics and properties of CrN compound layer produced by plasma nitriding of Cr-electroplated of AISI 304 stainless steel. Surf Coat Technol 2020, 385: 125450.
Crossref Google Scholar
[26]
Liu LL, Ruan QD, Xiao S, et al. Fabrication and hydrogen permeation resistance of dense CrN coatings. Surf Coat Technol 2022, 437: 128326.
Crossref Google Scholar
[27]
Matějíček J, Veverka J, Nemanič V, et al. Characterization of less common nitrides as potential permeation barriers. Fusion Eng Des 2019, 139: 74–80.
Crossref Google Scholar
[28]
Hu LL, Wei G, Yin R, et al. Significant hydrogen isotopes permeation resistance via nitride nano-multilayer coating. Int J Hydrogen Energ 2020, 45: 19583–19589.
Crossref Google Scholar
[29]
Wulf SE, Lorenz J, Holstein N, et al. Electrochemical techniques as innovative tools for fabricating divertor and blanket components in fusion technology. Fusion Eng Des 2019, 146: 460–464.
Crossref Google Scholar
[30]
Wang Y, Di J, Xue LH, et al. Fabrication and characterization of a dense Cr2O3–Al phosphate double coating as tritium permeation barrier. Fusion Eng Des 2017, 125: 127–133.
Crossref Google Scholar
[31]
Di J, Liu W, Xue LH, et al. A dense Cr2O3/Al2O3 composite ceramic coating prepared by electrodeposition and sealing with Al2O3. Coatings 2019, 9: 14.
Crossref Google Scholar
[32]
Mayr W, Lengauer W, Ettmayer P, et al. Phase equilibria and multiphase reaction diffusion in the Cr–C and Cr–N systems. J Phase Equilib 1999, 20: 35–44.
Crossref Google Scholar
[33]
Yang SM, Huang YT, Chang YY, et al. Oxidation resistance of Cr2N and (Cr,W)2N coatings deposited on ferritic stainless steel. Surf Coat Technol 2017, 325: 7–13.
Crossref Google Scholar
[34]
Guan XY, Wang YX, Xue QJ, et al. Toward high load bearing capacity and corrosion resistance Cr/Cr2N nano-multilayer coatings against seawater attack. Surf Coat Technol 2015, 282: 78–85.
Crossref Google Scholar
[35]
Ehrlich A, Kühn M, Richter F, et al. Complex characterisation of vacuum arc-deposited chromium nitride thin films. Surf Coat Technol 1995, 76–77: 280–286.
Crossref Google Scholar
[36]
Ajikumar PK, Sankaran A, Kamruddin M, et al. Morphology and growth aspects of Cr(N) phases on gas nitridation of electroplated chromium on AISI 316 LN stainless steel. Surf Coat Technol 2006, 201: 102–107.
Crossref Google Scholar
[37]
Maetz JY, Douillard T, Cazottes S, et al. M23C6 carbides and Cr2N nitrides in aged duplex stainless steel: A SEM, TEM and FIB tomography investigation. Micron 2016, 84: 43–53.
Crossref Google Scholar
[38]
Skiba O, Redjaïmia A, Dulcy J, et al. A proper assessment of TEM diffraction patterns originating from CrN nitrides in a ferritic matrix. Mater Charact 2018, 144: 671–677.
Crossref Google Scholar
[39]
Muhammad M, Hu SH, Ma RN, et al. Enhancing the corrosion resistance of Q235 mild steel by incorporating poly(dopamine) modified h-BN nanosheets on zinc phosphate–silane coating. Surf Coat Technol 2020, 390: 125682.
Crossref Google Scholar
[40]
Li HP, Ke ZQ, Xue LH, et al. A novel low-temperature approach for fabricating α-Al2O3-based ceramic coating as tritium permeation barrier. Fusion Eng Des 2017, 125: 567–572.
Crossref Google Scholar
[41]
Zhang XM, Mu Y, Dodaran M, et al. Mechanical failure of CrN/Cu/CrN interfacial regions under tensile loading. Acta Mater 2018, 160: 1–13.
Crossref Google Scholar
[42]
Iadicicco D, Bassini S, Vanazzi M, et al. Efficient hydrogen and deuterium permeation reduction in Al2O3 coatings with enhanced radiation tolerance and corrosion resistance. Nucl Fusion 2018, 58: 126007.
Crossref Google Scholar
[43]
Chikada T, Suzuki A, Adelhelm C, et al. Surface behaviour in deuterium permeation through erbium oxide coatings. Nucl Fusion 2011, 51: 063023.
Crossref Google Scholar
[44]
Forcey KS, Ross DK, Simpson JCB, et al. Hydrogen transport and solubility in 316L and 1.4914 steels for fusion reactor applications. J Nucl Mater 1988, 160: 117–124.
Crossref Google Scholar
[45]
Zhang GK, Wang XL, Xiong YF, et al. Mechanism for adsorption, dissociation and diffusion of hydrogen in hydrogen permeation barrier of α-Al2O3: A density functional theory study. Int J Hydrogen Energ 2013, 38: 1157–1165.
Crossref Google Scholar
[46]
Zhao ZR, Li HP, Zheng ZY, et al. Improved thermal shock and corrosion resistance of α-Al2O3/AlPO4 coating with PAA addition. Surf Coat Technol 2021, 414: 127115.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 12,
December 2022
Pages 1944-1955
DOI: 10.1007/s40145-022-0658-3
Cite this article:
ZHENG L, LI H, ZHOU J, et al. Layer-structured Cr/CrxN coating via electroplating-based nitridation achieving high deuterium resistance as the hydrogen permeation barrier. Journal of Advanced Ceramics, 2022, 11(12): 1944-1955. https://doi.org/10.1007/s40145-022-0658-3

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Received: 21 April 2022
Revised: 03 September 2022
Accepted: 06 September 2022
Published: 29 November 2022
© The Author(s) 2022.

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