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Research Article | Open Access

Galvanically induced potentials to enable minimal tribochemical wear of stainless steel lubricated with sodium chloride and ionic liquid aqueous solution

Tobias AMANN1( ), Felix GATTI1,2, Natalie OBERLE1, Andreas KAILER1, Jürgen RÜHE3
 Fraunhofer Institute for Mechanics of Materials IWM, Woehlerstr. 11, Freiburg 79108, Germany
 Institute for Macromolecular Chemistry, University of Freiburg, Freiburg 79104, Germany
 IMTEK - Department of Microsystems Engineering, University of Freiburg, Georges-Koehler-Allee 103, Freiburg 79110, Germany
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Abstract

The effect of galvanically induced potentials on the friction and wear behavior of a 1RK91 stainless steel regarding to tribocorrosion was investigated using an oscillating ball-on-disk tribometer equipped with an electrochemical cell. The aim of this investigation is to develop a water-based lubricant. Therefore 1 molar sodium chloride (NaCl) and 1% 1-ethyl-3-methylimidazolium chloride [C2mim][Cl] water solutions were used. Tribological performance at two galvanically induced potentials was compared with the non-polarized state: cathodic potential-coupling with pure aluminum- and anodic potential-coupling with pure copper. Frictional and electrochemical response was recorded during the tests. In addition, wear morphology and chemical composition of the steel were analyzed using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively.

The galvanically induced cathodic polarization of the stainless steel surface results in electrochemical corrosion protection and the formation of a tribolayer. Cations from the electrolyte (sodium Na+ and 1-ethyl- 3-methylimidazolium [C2mim]+) interact and adhere on the surface. These chemical interactions lead to considerably reduced wear using 1 NaCl (86%) and 1% 1-ethyl-3-methylimidazolium chloride [C2mim][Cl] (74%) compared to the nonpolarized system. In addition, mechanical and corrosive part of wear was identified using this electrochemical technique. Therefore this method describes a promising method to develop water-based lubricants for technical applications.

Keywords

sliding weartribochemistrypotential controlled friction and weargalvanic couplingionic liquidstribolayer formation

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Friction
Volume 6 Issue 2,
June 2018
Pages 230-242
DOI: 10.1007/s40544-017-0198-y
Cite this article:
AMANN T, GATTI F, OBERLE N, et al. Galvanically induced potentials to enable minimal tribochemical wear of stainless steel lubricated with sodium chloride and ionic liquid aqueous solution. Friction, 2018, 6(2): 230-242. https://doi.org/10.1007/s40544-017-0198-y

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Received: 07 July 2017
Revised: 30 October 2017
Accepted: 17 November 2017
Published: 26 February 2018
© The author(s) 2017

This article is published with open access at Springerlink.com

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