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Research Article | Open Access

Tribological study of N-containing borate derivatives and their synergistic antioxidation effects with T531

Liping XIONG1, Zhongyi HE1( ), Jian LIU1, Jianqiang HU2, Xu XIN2, Sheng HAN3, Yinglei WU4, Shaoming YANG1( )
School of Materials Science and Engineering, East China Jiaotong University, Nanchang 330013, China
Department of Aviation Oil and Material, Air Force Logistics College, Xuzhou 222100, China
Shanghai Applied Technology University, Shanghai 201418, China
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
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Abstract

Two N-containing borates, BTES and BMES, were synthesized with dodecyl phenol, 2-(N-containing heterocyclic) ethan-1-ol, boric acid, and dibutylamine, and their tribological properties in rapeseed oil (RSO) were investigated using a four-ball tester. The results showed that the load-carrying ability (PB value) of RSO can be improved by 40.9% and 67.9%, respectively, when using 0.5 wt% BTES and BMES. Moreover, the antiwear and friction-reducing performances of the additive-containing oils increased with the additive concentration. The X-ray photoelectron spectroscopy results of the worn steel ball surfaces showed that BTES and BMES formed protective films, which contained boron oxide, iron oxide, ferrous sulfate, ferrous sulfide (for BMES), and other organic nitrogen compounds, on the metal surfaces. The better load-carrying and antiwear performances of BMES than those of BTES might be due to their different sulfur contents, which result in different tribochemical reaction films on the contact surfaces. The oxidation stability tests showed that BTES and BMES possessed synergistic antioxidation activity with N-phenyl-α-naphthylamine (T531), and consequently, the oxidation activation energy of the oil sample increased by 77.85% and 82.19%, respectively, compared with that of RSO when the oil sample contained 0.05 wt% BTES/BMES and 0.25% T531.

Keywords

tribological propertyN-containing boratesynergistic antioxidation effectT531

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Friction
Volume 7 Issue 5,
October 2019
Pages 417-431
DOI: 10.1007/s40544-018-0216-8
Cite this article:
XIONG L, HE Z, LIU J, et al. Tribological study of N-containing borate derivatives and their synergistic antioxidation effects with T531. Friction, 2019, 7(5): 417-431. https://doi.org/10.1007/s40544-018-0216-8

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Received: 25 October 2017
Revised: 08 January 2018
Accepted: 12 March 2018
Published: 19 July 2018
© The author(s) 2018

This article is published with open access at Springerlink.com

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