AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Friction Article
PDF (1.2 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Dispersion-tribological property relationship in mineral oils containing 2D layered α-zirconium phosphate nanoplatelets

Feng JIANG1, Haoyang SUN1, Lei CHEN1, Fan LEI1, Dazhi SUN1( )
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China
Show Author Information

Abstract

Inorganic nanomaterials exhibit superior friction-reduction and anti-wear properties in oils. In this study, 2D layered α-zirconium phosphate (α-ZrP) nanosheets intercalated with different amines have been synthesized to study their dispersion stabilities in lubricating oil and tribological applications. The intercalated amines should be sufficiently long and lipophilic to provide stabilization to α-ZrP nanosheets in mineral oil. The results of tribological tests illustrate that with the addition of well-dispersed nanosheets, the coefficient of friction (COF) and pin volume loss reduce by ~47% and 75%, respectively. The excellent dispersion stability enables the nanosheets to flow into the contact area at the beginning, and thereby protect the rubbing surface. A reduction in the van der Waals forces between the adjacent layers induced by the intercalated amines transforms the friction between adjacent layers from pin disk to sliding, leading to a decrease in the COF under hydrodynamic lubrication. The study provides a new method to enhance the tribological properties via tuning the dispersion stabilities of nanomaterials in oils.

Keywords

friction-reduction and anti-wearnanoadditivelayered nanosheetα-zirconium phosphate (α-ZrP)dispersiontribology

References

[1]
K Holmberg, P Andersson, A Erdemir. Global energy consumption due to friction in passenger cars. Tribol Int 47: 221-234 (2012)
Crossref Google Scholar
[2]
M R Cai, R S Guo, F Zhou, W M Liu. Lubricating a bright future: Lubrication contribution to energy saving and low carbon emission. Sci China Technol Sci 56(12): 2888-2913 (2013)
Crossref Google Scholar
[3]
J Byerlee. Friction of rocks. Pure Appl Geophys 116(4-5): 615-626 (1978)
Crossref Google Scholar
[4]
X L He, X P Xiao, H Choi, A Díaz, B Mosby, A Clearfield, H Liang. α-Zirconium phosphate nanoplatelets as lubricant additives. Colloids Surf A Physicochem Eng Aspects 452: 32-38 (2014)
Crossref Google Scholar
[5]
Z L Tang, S H Li. A review of recent developments of friction modifiers for liquid lubricants (2007-present). Curr Opin Solid State Mater Sci 18(3): 119-139 (2014)
Crossref Google Scholar
[6]
S A Mäkiharju, M Perlin, S L Ceccio. On the energy economics of air lubrication drag reduction. Int J Nav Arch Ocean Eng 4(4): 412-422 (2012)
Crossref Google Scholar
[7]
P Boerzel, K Bronstert, F Hovemann. Oil additives, maleic anhydride product. U.S. Patent 4 152 499, May, 1979.
[8]
J Qu, J J Truhan, S Dai, H Luo, P J Blau. Ionic liquids with ammonium cations as lubricants or additives. Tribol Lett 22(3): 207-214 (2006)
Crossref Google Scholar
[9]
M D Bermúdez, A E Jiménez, J Sanes, F J Carrión. Ionic liquids as advanced lubricant fluids. Molecules 14(8): 2888-2908 (2009)
Crossref Google Scholar
[10]
Y Y Wu, W C Tsui, T C Liu. Experimental analysis of tribological properties of lubricating oils with nanoparticle additives. Wear 262(7-8): 819-825 (2007)
Crossref Google Scholar
[11]
H Spikes. Low- and zero-sulphated ash, phosphorus and sulphur anti-wear additives for engine oils. Lubricat Sci 20(2): 103-136 (2008)
Crossref Google Scholar
[12]
Y Xu, E Z Hu, K H Hu, Y F Xu, X G Hu. Formation of an adsorption film of MoS2 nanoparticles and dioctyl sebacate on a steel surface for alleviating friction and wear. Tribol Int 92: 172-183 (2015)
Crossref Google Scholar
[13]
L Yadgarov, V Petrone, R Rosentsveig, Y Feldman, R Tenne, A Senatore. Tribological studies of rhenium doped fullerene-like MoS2 nanoparticles in boundary, mixed and elasto-hydrodynamic lubrication conditions. Wear 297(1-2): 1103-1110 (2013)
Crossref Google Scholar
[14]
B Bhushan, J N Israelachvili, U Landman. Nanotribology: Friction, wear and lubrication at the atomic scale. Nature 374(6523): 607-616 (1995)
Crossref Google Scholar
[15]
Y F Chen, Y J Zhang, S M Zhang, L G Yu, P Y Zhang, Z J Zhang. Preparation of nickel-based nanolubricants via a facile in situ one-step route and investigation of their tribological properties. Tribol Lett 51(1): 73-83 (2013)
Crossref Google Scholar
[16]
G Liu, X Li, B Qin, D Xing, Y Guo, R Fan. Investigation of the mending effect and mechanism of copper Nano-particles on a tribologically stressed surface. Tribol Lett 17(4): 961-966 (2004)
Crossref Google Scholar
[17]
I Popa, G Gillies, G Papastavrou, M Borkovec. Attractive and repulsive electrostatic forces between positively charged latex particles in the presence of anionic linear polyelectrolytes. J Phys Chem B 114(9): 3170-3177 (2010)
Crossref Google Scholar
[18]
W Yu, H Q Xie. A review on nanofluids: Preparation, stability mechanisms, and applications. J Nanomater 2012: 435873 (2012)
Crossref Google Scholar
[19]
H J Song, B Wang, Q Zhou, J X Xiao, X H Jia. Preparation and tribological properties of MoS2/graphene oxide composites. Appl Surf Sci 419: 24-34 (2017)
Crossref Google Scholar
[20]
C G Lee, Y J Hwang, Y M Choi, J K Lee, C Choi, J M Oh. A study on the tribological characteristics of graphite nano lubricants. Int J Precis Eng Manuf 10(1): 85-90 (2009)
Crossref Google Scholar
[21]
A Clearfield, J A Stynes. The preparation of crystalline zirconium phosphate and some observations on its ion exchange behaviour. J Inorg Nucl Chem 26(1): 117-129 (1964)
Crossref Google Scholar
[22]
A Díaz, V Saxena, J González, A David, B Casañas, C Carpenter, J D Batteas, J L Colón, A Clearfield, M D Hussain. Zirconium phosphate nano-platelets: A novel platform for drug delivery in cancer therapy. Chem Commun 48(12): 1754-1756 (2012)
Crossref Google Scholar
[23]
V Saxena, A Diaz, A Clearfield, J D Batteas, M D Hussain. Zirconium phosphate nanoplatelets: A biocompatible nanomaterial for drug delivery to cancer. Nanoscale 5(6): 2328-2336 (2013)
Crossref Google Scholar
[24]
L Y Sun, W J Boo, D Z Sun, A Clearfield, H J Sue. Preparation of exfoliated epoxy/α-zirconium phosphate nanocomposites containing high aspect ratio nanoplatelets. Chem Mater 19(7): 1749-1754 (2007)
Crossref Google Scholar
[25]
H Zhang, L Chen, X Han, F Jiang, H Y Sun, D Z Sun. Enhanced mechanical properties of Nylon6 nanocomposites containing pristine α-zirconium phosphate nanoplatelets of various sizes by melt-compounding. RSC Adv 7(52): 32682-32691 (2017)
Crossref Google Scholar
[26]
L Chen, D Z Sun, J Li, G D Zhu. Exfoliation of layered zirconium phosphate nanoplatelets by melt compounding. Mater Des 122: 247-254 (2017)
Crossref Google Scholar
[27]
D D Li, Y C Xie, H S Yong, D Z Sun. Surfactant-assisted preparation of Y2O3-stabilized ZrO2 nanoparticles and their tribological performance in mineral and commercial lubricating oils. RSC Adv 7(7): 3727-3735 (2017)
Crossref Google Scholar
[28]
H J Ma, X S Zhang, H Xu. Tribological properties of layered A-zirconium phosphate as lithium grease additive. Asian J Chem 27(3): 1133-1137 (2015)
Crossref Google Scholar
[29]
R M Tindwa, D K Ellis, G Z Peng, A Clearfield. Intercalation of n-alkylamines by α-zirconium phosphate. J Chem Soc Faraday Trans 81(2): 545-552 (1985)
Crossref Google Scholar
[30]
G Alberti. Syntheses, crystalline structure, and ion-exchange properties of insoluble acid salts of tetravalent metals and their salt forms. Acc Chem Res 11(4): 163-170 (1978)
Crossref Google Scholar
[31]
X S Zhang, H Xu, Z J Zuo, Z Lin, S Ferdov, J X Dong. Hydrothermal synthesis of copper zirconium phosphate hydrate [Cu(OH)2Zr(HPO4)2∙2H2O] and an investigation of its lubrication properties in grease. ACS Appl Mater Interfaces 5(16): 7989-7994 (2013)
Crossref Google Scholar
[32]
L Y Sun, W J Boo, H J Sue, A Clearfield. Preparation of α-zirconium phosphate nanoplatelets with wide variations in aspect ratios. New J Chem 31(1): 39-43 (2007)
Crossref Google Scholar
[33]
G Alberti, U Costantino. Recent progress in the intercalation chemistry of layered α-zirconium phosphate and its derivatives, and future perspectives for their use in catalysis. J Mol Catal 27(1-2): 235-250 (1984)
Crossref Google Scholar
[34]
ASTM. ASTM Standard G 99 Standard test method for wear testing with a pin-on-disk apparatus. West Conshohocken (USA): ASTM, 2005.
[35]
Z Cao, L X Sun, X Q Cao, Y H He. Synthesis and characterization of the layered zirconium phosphate and its intercalation study. Adv Mater Res 233-235: 1809-1813 (2011)
Crossref Google Scholar
[36]
H N Kim, S W Keller, T E Mallouk. Characterization of zirconium phosphate/polycation thin films grown by sequential adsorption reactions. Chem Mater 9(6): 1414-1421 (1997)
Crossref Google Scholar
[37]
A E Saunders, A Ghezelbash, D M Smilgies, M B Sigman, B A Korgel. Columnar self-assembly of colloidal nanodisks. Nano Lett 6(12): 2959-2963 (2006)
Crossref Google Scholar
[38]
S Z Wen, P Huang. Principles of Tribology. Singapore: John Wiley & Sons Inc., 2012: 647-648.
Crossref
[39]
K M Hou, P W Gong, J Q Wang, Z G Yang, Z F Wang, S R Yang. Structural and tribological characterization of fluorinated graphene with various fluorine contents prepared by liquid- phase exfoliation. RSC Adv 4(100): 56543-56551 (2014)
Crossref Google Scholar
[40]
X Tao, J Z Zhao, K Xu. The ball-bearing effect of diamond nanoparticles as an oil additive. J Phys D-Appl Phys 29(11): 2932-2937 (1996)
Crossref Google Scholar
[41]
R L Fusaro, H E Sliney. Graphite fluoride (CFx)n—A new solid lubricant. A S L E Trans 13(1): 56-65 (1970)
Crossref Google Scholar
[42]
B A Hills. Graphite-like lubrication of mesothelium by oligolamellar pleural surfactant. J Appl Physiol 73(3): 1034-1039 (1992)
Crossref Google Scholar
[43]
X Han, H S Yong, D Z Sun. Tuning tribological performance of layered zirconium phosphate nanoplatelets in oil by surface and interlayer modifications. Nanoscale Res Lett 12: 542 (2017)
Crossref Google Scholar
Friction
Volume 8 Issue 4,
August 2020
Pages 695-707
DOI: 10.1007/s40544-019-0294-2
Cite this article:
JIANG F, SUN H, CHEN L, et al. Dispersion-tribological property relationship in mineral oils containing 2D layered α-zirconium phosphate nanoplatelets. Friction, 2020, 8(4): 695-707. https://doi.org/10.1007/s40544-019-0294-2

713

Views

14

Downloads

26

Crossref

N/A

Web of Science

25

Scopus

4

CSCD

Altmetrics
Received: 06 June 2018
Revised: 07 August 2018
Accepted: 07 April 2019
Published: 16 July 2019
© The author(s) 2019

Open Access: This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return