AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Home Friction Article
PDF (2 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Comparative study on corrosion resistance and lubrication function of lithium complex grease and polyurea grease

Guanlin REN1Pengfei ZHANG1Xiangyuan YE2Wen LI1Xiaoqiang FAN3( )Minhao ZHU1,3
Tribology Research Institute, School of Mechanical Engineering, Southwest Jiaotong University, Chengdu 610031, China
Shaanxi Key Laboratory of Phytochemistry, College of Chemistry & Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721013, China
Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
Show Author Information

Abstract

In this study, lithium complex grease (LCG) and polyurea grease (PUG) were synthesized using mineral oil (500SN) and polyalphaolefin (PAO40) as base oil, adsorbed onto lithium complex soap and polyurea as thickeners, respectively. The effects of grease formulation (thickener and base oil with different amounts (80, 85, and 90 wt%) on the corrosion resistance and lubrication function were investigated in detail. The results have verified that the as-prepared greases have good anti-corrosion ability, ascribed to good salt-spray resistance and sealing function. Furthermore, the increase in the amount of base oil reduces the friction of the contact interface to some extent, whereas the wear resistance of these greases is not consistent with the friction reduction, because the thickener has a significant influence on the tribological property of greases, especially load-carrying capacity. PUG displays better physicochemical performance and lubrication function than LCG under the same conditions, mainly depending on the component/structure of polyurea thickener. The polyurea grease with 90 wt% PAO displays the best wear resistance owing to the synergistic lubrication of grease-film and tribochemical film, composed of Fe2O3, FeO(OH), and nitrogen oxide.

References

[1]
A K Arora, V S Jaswal, K Singh, R Singh. Applications of metal/mixed metal oxides as photocatalyst: (A review). Orient J Chem 32(4): 2035-2042 (2016)
[2]
Q J Chen, W Jiang, F B Zhang, Y H Dong, X L Zhou. Research on salt spray and electrochemical corrosion of FeCo-based bulk amorphous alloys. Rare Metal Mater Eng 45(9): 2322-2326 (2016)
[3]
G A El-Mahdy, A Nishikata, T Tsuru. Electrochemical corrosion monitoring of galvanized steel under cyclic wet-dry conditions. Corros Sci 42(1): 183-194 (2000)
[4]
M M Sharma, J D Tomedi, J M Parks. A microscopic study on the corrosion fatigue of ultra-fine grained and conventional Al-Mg alloy. Corros Sci 93: 180-190 (2015)
[5]
Y M Panchenko, A I Marshakov. Long-term prediction of metal corrosion losses in atmosphere using a power-linear function. Corros Sci 109: 217-229 (2016)
[6]
G A El-Mahdy, K B Kim. Monitoring the atmospheric corrosion loss of copper during wet/dry cyclic conditions in oxalic acid solutions. Corrosion 63(2): 171-177 (2007)
[7]
S K Yeong, P F Luckham, T F Tadros. Steady flow and viscoelastic properties of lubricating grease containing various thickener concentrations. J Colloid Interface Sci 274(1): 285-293 (2004)
[8]
A Rezasoltani, M M Khonsari. On the correlation between mechanical degradation of lubricating grease and entropy. Tribol Lett 56(2): 197-204 (2014)
[9]
J G Chen. Synthesis, characterization, and tribological behavior of neopentyl polyol ester-based and mixed oil-based titanium complex grease. Tribol Lett 40(1): 149-154 (2010)
[10]
L Salomonsson, G Stang, B Zhmud. Oil/thickener interactions and rheology of lubricating greases. Tribol Trans 50(3): 302-309 (2007)
[11]
L Huang, D Guo, X Liu, G X Xie, G T Y Wan, S Z Wen. Effects of nano thickener deposited film on the behaviour of starvation and replenishment of lubricating greases. Friction 4(4): 313-323 (2016)
[12]
P Lugt. Modern advancements in lubricating grease technology. Tribol Int 97: 467-477 (2016)
[13]
P Baart, B der Vorst, P M Lugt, R A J van Ostayen. Oil-bleeding model for lubricating grease based on viscous flow through a porous microstructure. Tribol Trans 53(3): 340-348 (2010)
[14]
H Cen, P M Lugt, G Morales-Espejel. On the film thickness of grease-lubricated contacts at low speeds. Tribol Trans 57(4): 668-678 (2014)
[15]
M A Delgado, C Valencia, M C Sánchez, J M Franco, C Gallegos. Thermorheological behaviour of a lithium lubricating grease. Tribol Lett 23(1): 47-54 (2006)
[16]
P M Lugt. A review on grease lubrication in rolling bearings. Tribol Trans 52(4): 470-480 (2009)
[17]
N De Laurentis, P Cann, P M Lugt, A Kadiric. The influence of base oil properties on the friction behaviour of lithium greases in rolling/sliding concentrated contacts. Tribol Lett 65(4): 128 (2017)
[18]
D H Mao, H Feng, X Y Sun. Preparation of hyperthermal lithium complex grease. Trans Nonferr Metals Soc China 15(6): 1361-1366 (2005)
[19]
A Skibińska, M Żółty. Determination of thermal-oxidation stability of lubricating greases. Part 3-Lithium-complex greases. Nafta-Gaz 74(1): 61-66 (2018)
[20]
J Shu, K Harris, B Munavirov, R Westbroek, J Leckner, S Glavatskih. Tribology of polypropylene and li-complex greases with ZDDP and MoDTC additives. Tribol Int 118: 189-195 (2018)
[21]
Q Zhao, G Q Zhao, M Zhang, X B Wang, W M Liu. Tribological behavior of protic ionic liquids with dodecylamine salts of dialkyldithiocarbamate as additives in lithium complex grease. Tribol Lett 48(2): 133-144 (2012)
[22]
X Z Dai, P Guo, D M Hong, J D Hui, Z M Hui, F Geng. The effect of preparation and characterisation of polyurea grease. Mater Res Innov 19(S5): S5-588-S5-591 (2015)
[23]
M V Garshin, Y V Porfiryev, V A Zaychenko, S A Shuvalov, D S Kolybelsky, P A Gushchin, V A Vinokurov. Effect of base oil composition on the low-temperature properties of polyurea greases. Pet Chem 57(12): 1177-1181 (2017)
[24]
A S Lyadova, Y M Maksimova, A S Shakhmatova, V V Kirillov, O P Parenago. Urea (Polyurea) Greases. Russ J Appl Chem 91(6): 885-894 (2018)
[25]
Z Y Wang, W Wu. The tribological properties of the polyurea greases based on oil-miscible phosphonium-based ionic liquids. Lubr Sci 30(1): 16-22 (2018)
[26]
Y M Maksimova, A S Shakhmatova, S O Ilyin, O A Pakhmanova, A S Lyadov, S V Antonov, O P Parenago. Rheological and tribological properties of lubricating greases based on esters and polyurea thickeners. Pet Chem 58(12): 1064-1069 (2018)
[27]
L Liu, H W Sun. Impact of polyurea structure on grease properties. Lubr Sci 22(9): 405-413 (2010)
[28]
G D Hao, Z P Yao, Z H Jiang. Salt spray corrosion test of micro-plasma oxidation ceramic coatings on Ti alloy. Rare Metals 26(6): 560-564 (2007)
[29]
Y Tang, A M Song. Effect of salt spray conditions on test results. Microelectronics 39(2): 289-292 (2009)
[30]
C H Xiong, H Y Mi, Q Feng, B J Wu. Comparative studies on low noise greases operating under high temperature oxidation conditions. China Pet Process Petrochem Technol 16(4): 100-106 (2014)
[31]
J C Yan, H Zeng, T Liu, J H Mai, H B Ji. Tribological performance and surface analysis of a borate calcium as additive in lithium and polyurea greases. Tribol Trans 60(4): 621-628 (2017)
[32]
X H Wu, X B Wang, W M Liu. Tribological properties of naphthyl phenyl diphosphates as antiwear additive in polyalkylene glycol and polyurea grease for steel/steel contacts at elevated temperature. RSC Adv 4(12): 6047-6082 (2014)
[33]
Z Y Wang, Y Q Xia, Z L Liu, T C Hu. Friction and wear behaviour of laser-textured surfaces under the lubrication of polyurea grease containing various additives. Proc Inst Mech Eng, Part J: J Eng Tribol 225(3): 139-150 (2011)
[34]
J Singh, D Kumar, N Tandon. Tribological and vibration studies on newly developed nanocomposite greases under boundary lubrication regime. J Tribol 140(3): 032001 (2018)
[35]
A Saatchi, P J Shiller, S A Eghtesadi, T B Liu, G L Doll. A fundamental study of oil release mechanism in soap and non-soap thickened greases. Tribol Int 110: 333-340 (2017)
[36]
M Paszkowski, R Wróblewski, A Walaszczyk. Studies of the influence of temperature and the energy state of the surface layer of adsorbents on wall effects in soap-based greases. Tribol Lett 65(1): 19 (2017)
[37]
S S Rawat, A P Harsha, D P Agarwal, S Kumari, O P Khatri. Pristine and alkylated MoS2 nanosheets for enhancement of tribological performance of paraffin grease under boundary lubrication regime. J Tribol 141(7): 072102 (2019)
Friction
Pages 75-91
Cite this article:
REN G, ZHANG P, YE X, et al. Comparative study on corrosion resistance and lubrication function of lithium complex grease and polyurea grease. Friction, 2021, 9(1): 75-91. https://doi.org/10.1007/s40544-019-0325-z

731

Views

38

Downloads

27

Crossref

N/A

Web of Science

26

Scopus

4

CSCD

Altmetrics

Received: 02 July 2019
Revised: 06 August 2019
Accepted: 03 September 2019
Published: 13 December 2019
© The author(s) 2019

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Return