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Research Article | Open Access

Enhanced tribological properties of aligned graphene-epoxy composites

Yuefeng DU1Zhenyu ZHANG1 ( )Dong WANG2Lezhen ZHANG3Junfeng CUI1Yapeng CHEN4Mingliang WU1Ruiyang KANG1Yunxiang LU4Jinhong YU4Nan JIANG4( )
Key Laboratory for Precision and Non-Traditional Machining Technology of Ministry of Education, Dalian University of Technology, Dalian 116024, China
Beijing Spacecrafts Manufacturing Factory Co., Ltd., China Academy of Space Technology, Beijing 100094, China
Weichai Power Co., Ltd., Weifang 261061, China
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences, Ningbo 315201, China
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Abstract

The random distribution of graphene in epoxy matrix hinders the further applications of graphene-epoxy composites in the field of tribology. Hence, in order to fully utilize the anisotropic properties of graphene, highly aligned graphene-epoxy composites (AGEC) with horizontally oriented structure have been fabricated via an improved vacuum filtration freeze-drying method. The frictional tests results indicated that the wear rate of AGEC slowly increased from 5.19×10-6 mm3/(N·m) to 2.87×10-5 mm3/(N·m) with the increasing of the normal load from 2 to 10 N, whereas the friction coefficient (COF) remained a constant of 0.109. Compared to the neat epoxy and random graphene-epoxy composites (RGEC), the COF of AGEC was reduced by 87.5% and 71.2%, and the reduction of wear rate was 86.6% and 85.4% at most, respectively. Scanning electron microscope (SEM) observations illustrated that a compact graphene self-lubricant film was formed on the worn surface of AGEC, which enables AGEC to possess excellent tribological performance. Finally, in light of the excellent tribological properties of AGEC, this study highlights a pathway to expand the tribological applications of graphene-epoxy composites.

References

[1]
Rahsepar M, Mohebbi F. Enhancement of the wear resistance of epoxy coating in presence of MBT-loaded mesoporous silica nanocontainers. Tribol Int 118: 148-156 (2018)
[2]
Khafidh M, Schipper D J, Masen M A, Vleugels N, Dierkes W K, Noordermeer J W M. Validity of Amontons’ law for run-in short-cut aramid fiber reinforced elastomers: The effect of epoxy coated fibers. Friction 8(3): 613-625 (2020)
[3]
Zhang L, Xie G X, Wu S, Peng S G, Zhang X Q, Guo D, Wen S Z, Luo J B. Ultralow friction polymer composites incorporated with monodispersed oil microcapsules. Friction 9(1): 29-40 (2021)
[4]
Huang Z P, Zhao W J, Zhao W C, Ci X J, Li W T. Tribological and anti-corrosion performance of epoxy resin composite coatings reinforced with differently sized cubic boron nitride (CBN) particles. Friction 9(1): 104-118 (2021)
[5]
Yan L, Wang H Y, Wang C, Sun L Y, Liu D J, Zhu Y J. Friction and wear properties of aligned carbon nanotubes reinforced epoxy composites under water lubricated condition. Wear 308(1-2): 105-112 (2013)
[6]
Khun N W, Zhang H, Lim L H, Yue C Y, Hu X, Yang J L. Tribological properties of short carbon fibers reinforced epoxy composites. Friction 2(3): 226-239 (2014)
[7]
Sakka M M, Antar Z, Elleuch K, Feller J F. Tribological response of an epoxy matrix filled with graphite and/or carbon nanotubes. Friction 5(2): 171-182 (2017)
[8]
Chen H Y, Jacobs O, Wu W, Rüdiger G, Schädel B. Effect of dispersion method on tribological properties of carbon nanotube reinforced epoxy resin composites. Polym Test 26(3): 351-360 (2007)
[9]
Wang H Y, Yan L, Liu D J, Wang C, Zhu Y J, Zhu J H. Investigation of the tribological properties: Core-shell structured magnetic Ni@NiO nanoparticles reinforced epoxy nanocomposites. Tribol Int 83: 139-145 (2015)
[10]
Wetzel B, Haupert F, Zhang M Q. Epoxy nanocomposites with high mechanical and tribological performance. Compos Sci Technol 63(14): 2055-2067 (2003)
[11]
Chang L, Zhang Z, Ye L, Friedrich K. Tribological properties of epoxy nanocomposites: III. Characteristics of transfer films. Wear 62(5-6): 699-706 (2007)
[12]
Chang L, Zhang Z, Breidt C, Friedrich K. Tribological properties of epoxy nanocomposites I. Enhancement of the wear resistance by nano-TiO2 particles. Wear 258(1-4): 141-148 (2005)
[13]
Shi G, Zhang M Q, Rong M Z, Wetzel B, Friedrich K. Friction and wear of low nanometer Si3N4 filled epoxy composites. Wear 254(7-8): 784-796 (2003)
[14]
Huang L, Zhu P L, Li G, Lu D Q, Sun R, Wong C P. Core-shell SiO2@RGO hybrids for epoxy composites with low percolation threshold and enhanced thermo-mechanical properties. J Mater Chem A 2(43): 18246-18255 (2014)
[15]
Tang L C, Wan Y J, Yan D, Pei Y B, Zhao L, Li Y B, Wu L B, Jiang J X, Lai G Q. The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites. Carbon 60: 16-27 (2013)
[16]
Naebe M, Wang J, Amini A, Khayyam H, Hameed N, Li L H, Chen Y, Fox B. Mechanical property and structure of covalent functionalised graphene/epoxy nanocomposites. Sci Rep 4: 4375 (2014)
[17]
Lee C, Wei X D, Kysar J W, Hone J. Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887): 385-388 (2008)
[18]
Balandin A A, Ghosh S, Bao W Z, Calizo I, Teweldebrhan D, Miao F, Lau C N. Superior thermal conductivity of single-layer graphene. Nano Lett 8(3): 902-907 (2008)
[19]
Tang J J, Yang J, Zhou L, Xie J, Chen G H, Zhou X Y. Layer-by-layer self-assembly of a sandwich-like graphene wrapped SnOx@graphene composite as an anode material for lithium ion batteries. J Mater Chem A 2(18): 6292-6295 (2014)
[20]
Yu S Y, Li N, Higgins D, Li D Y, Li Q, Xu H, Spendelow J S, Wu G. Self-assembled reduced graphene oxide/ polyacrylamide conductive composite films. ACS Appl Mater Inter 6(22): 19783-19790 (2014)
[21]
Liu C, Yan H X, Lv Q, Li S, Niu S. Enhanced tribological properties of aligned reduced graphene oxide-Fe3O4@polyphosphazene/bismaleimides composites. Carbon 102: 145-153 (2016)
[22]
Liu C, Yan H X, Chen Z Y, Yuan L X, Liu T Y. Enhanced tribological properties of bismaleimides filled with aligned graphene nanosheets coated with Fe3O4 nanorods. J Mater Chem A 3(19): 10559-10565 (2015)
[23]
Yao B W, Chen J, Huang L, Zhou Q Q, Shi G Q. Base-induced liquid crystals of graphene oxide for preparing elastic graphene foams with long-range ordered microstructures. Adv Mater 8(28): 1623-1629 (2016)
[24]
Lian G, Tuan C C, Li L Y, Jiao S L, Wang Q L, Moon K S, Cui D L, Wong C P. Vertically aligned and interconnected graphene networks for high thermal conductivity of epoxy composites with ultralow loading. Chem Mater 28(17): 6096-6104 (2016)
[25]
Li Q, Guo Y F, Li W W, Qiu S Q, Zhu C, Wei X F, Chen M L, Liu C J, Liao S T, Gong Y P, et al. Ultrahigh thermal conductivity of assembled aligned multilayer graphene/epoxy composite. Chem Mater 15(26): 4459-4465 (2014)
[26]
Dai W, Lv L, Lu J B, Hou H, Yan Q W, Alam F E, Li Y F, Zeng X L, Yu J H, Wei Q P, et al. A paper-like inorganic thermal interface material composed of hierarchically structured graphene/silicon carbide nanorods. ACS Nano 13(2): 1547-1554 (2019)
[27]
Liang Q Z, Yao X X, Wang W, Liu Y, Wong C P. A Three-Dimensional Vertically Aligned Functionalized Multilayer Graphene Architecture: An Approach for Graphene-Based Thermal Interfacial Materials. ACS Nano 5(3): 2392-2401 (2011)
[28]
Qiu L, Liu J Z, Chang S L Y, Wu Y, Li D. Biomimetic superelastic graphene-based cellular monoliths. Nat Commun 3: 1241 (2012)
[29]
Hou H, Dai W, Yan Q W, Lv L, Alam F E, Yang M H, Yao Y G, Zeng X L, Xu J B, Yu J H, et al. Graphene size-dependent modulation of graphene frameworks contributing to the superior thermal conductivity of epoxy composites. J Mater Chem A 6(25): 12091-12097 (2018)
[30]
Wang F, Wang H Y, Mao J. Aligned-graphene composites: A review. J Mater Sci 54(1): 36-61 (2019)
[31]
Huang X, Qi X Y, Boey F, Zhang H. Graphene-based composites. Chem Soc Rev 41(2): 666-686 (2012)
[32]
Shen X J, Pei X Q, Fu S Y, Friedrich K. Significantly modified tribological performance of epoxy nanocomposites at very low graphene oxide content. Polymer 54(3): 1234-1242 (2013)
[33]
Bassani R, Levita G, Meozzi M, Palla G. Friction and wear of epoxy resin on inox steel: Remarks on the influence of velocity, load and induced thermal state. Wear 214(2): 125-132 (2001)
[34]
Hutchings I, Shipway P. Tribology-friction and wear of engineering materials. Oxford (UK): Butterworth-Heinemann Press, 2017.
[35]
Shimbo M, Ochi M, Ohoyama N. Frictional behaviour of cured epoxide resins. Wear 91(1): 89-101 (1983)
[36]
Campo M, Jiménez-Suárez A, Ureña A. Effect of type, percentage and dispersion method of multi-walled carbon nanotubes on tribological properties of epoxy composites. Wear 324-325: 100-108 (2015)
[37]
Malard L M, Pimenta M A, Dresselhaus G, Dresselhaus M S. Raman spectroscopy in graphene. Phys Rep 473(5-6): 51-87 (2009)
[38]
Cancado L G, Jorio A, Ferreira E H, Stavale F, Achete C A, Capaz R B, Moutinho M V O, Lombardo, A, Kulmala T S, Ferrari A C. Quantifying defects in graphene via Raman spectroscopy at different excitation energies. Nano Lett 11(8): 3190-3196 (2011)
[39]
Scharf T W, Prasad S V. Solid lubricants: A review. J Mater Sci 48(2): 511-531 (2012)
[40]
Bowden F P, Tabor D F. The friction and lubrication of solids. AM J Phys 19(7): 428-429 (1954)
[41]
Berman D, Erdemir A, Sumant AV. Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54: 454-459 (2013)
[42]
Berman D, Erdemir A, Sumant AV. Graphene: A new emerging lubricant. Mater Today 17(1): 31-42 (2014)
[43]
Stachowiak G W, Batchelor A W. Engineering Tribology. Oxford (UK): Butterworth-Heinemann Press, 2000.
[44]
Huang T, Xin Y S S, Nutt S, Su C, Chen H M, Liu P, Lai Z L. Modified graphene/polyimide nanocomposites: Reinforcing and tribological effects. ACS Appl Mater Inter 5(11): 4878-4891 (2013)
Friction
Pages 854-865
Cite this article:
DU Y, ZHANG Z, WANG D, et al. Enhanced tribological properties of aligned graphene-epoxy composites. Friction, 2022, 10(6): 854-865. https://doi.org/10.1007/s40544-021-0496-2

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Received: 11 October 2020
Revised: 29 December 2020
Accepted: 25 January 2021
Published: 28 April 2021
© The author(s) 2021.

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