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Research Article | Open Access

Effects of annealing treatment on tribological behavior of tungsten-doped diamond-like carbon film under lubrication (Part 2): Tribological behavior under MoDTC lubrication

Shaojun ZHANG1, Lina ZHU1,2( ), Yanyan WANG1, Jiajie KANG1,2, Haidou WANG3,4, Guozheng MA4, Haipeng HUANG5, Guang’an ZHANG6, Wen YUE1,2( )
School of Engineering and Technology, China University of Geosciences (Beijing), Beijing 100083, China
Zhengzhou Research Institute, China University of Geosciences (Beijing), Zhengzhou 451283, China
National Engineering Research Center for Remanufacturing, Beijing 100072, China
National Key Lab for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072, China
Beijing Research Institute, Sinopec Lubricant Co., Ltd., Beijing 100085, China
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
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Abstract

Molybdenum dialkyldithiocarbamate (MoDTC) is widely used as a friction modifier in engine lubricating oil. Under MoDTC lubrication, the friction and wear behaviors of tungsten-doped diamond-like carbon (W-DLC) films annealed at 100–400 °C were discussed and evaluated using scanning electron microscopy (SEM), atomic force microscopy (AFM), and Raman spectroscopy. Under (polymerized alpha olefin) PAO + MoDTC lubrication, the coefficient of friction of all samples decreased, but the wear rates of the W-DLC films annealed at 300 °C increased significantly. By interacting with zinc dialkyldithiophosphate (ZDDP), the wear rates of W-DLC films annealed at different temperatures declined significantly owing to the formation of dense phosphate tribofilms on the worn surfaces.

Keywords

annealingdiamond-like carbon (DLC)zinc dialkyldithiophosphate (ZDDP)friction and wear behaviorsmolybdenum dialkyldithiocarbamate (MoDTC)

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Friction
Volume 10 Issue 7,
July 2022
Pages 1061-1077
DOI: 10.1007/s40544-021-0514-4
Cite this article:
ZHANG S, ZHU L, WANG Y, et al. Effects of annealing treatment on tribological behavior of tungsten-doped diamond-like carbon film under lubrication (Part 2): Tribological behavior under MoDTC lubrication. Friction, 2022, 10(7): 1061-1077. https://doi.org/10.1007/s40544-021-0514-4

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Received: 16 July 2020
Revised: 16 December 2020
Accepted: 30 March 2021
Published: 05 August 2021
© The author(s) 2021.

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