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Research Article | Open Access

Ultralow friction PTFE/PEEK heterolayer: A new solid lubrication approach toward simplicity

Wei SUN1Jiaxin YE2Qingrui SONG2Yi FENG1Xiaojun LIU2( )
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China
Institute of Tribology, School of Mechanical Engineering, Hefei University of Technology, Hefei 230009, China
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Abstract

Tribological applications of polytetrafluoroethylene (PTFE) are often limited by technological complexity to overcome its poor wear resistance. Here, a PTFE/polyetheretherketone (PEEK) heterolayer (HL) was proposed and evaluated as a new solid lubrication solution. Pin-on-disk tribometry found the lowest friction coefficient (μ) of 0.031 and ultralow wear for the PEEK/HL under typical conditions. The friction coefficient of the HL surpasses those of the state-of-the-art polymeric coatings/composites by at least 200%, and approaches that of highly lubricated interfaces. Mechanistic investigations revealed multi-length physical and chemical heterogeneity of the HL that best facilitates a tribofilm with high subsurface stability and surface instability. The technological simplicity and robustness of the HL’s high lubricity make it a promising new type of solid lubrication toward greater reliability and longevity.

References

[1]
Dhanumalayan E, Joshi G M. Performance properties and applications of polytetrafluoroethylene (PTFE)—A review. Adv Compos Hybrid Ma 1(2): 247268 (2018)
[2]
Scharf T W, Prasad S V. Solid lubricants: A review. J Mater Sci 48(2): 511531 (2013)
[3]
Puts G J, Crouse P, Ameduri B M. Polytetrafluoroethylene: Synthesis and characterization of the original extreme polymer. Chem Rev 119(3): 17631805 (2019)
[4]
Sinha S K, Briscoe B J. Polymer Tribology. London (UK): Imperial College Press, 2009.
[5]
Biswas S K, Vijayan K. Friction and wear of PTFE—A review. Wear 158(1–2): 193211 (1992)
[6]
Makinson K R, Tabor D. Friction and transfer of polytetrafluoroethylene. Nature 201(4918): 464466 (1964)
[7]
Krick B A, Hahn D W, Sawyer W G. Plasmonic diagnostics for tribology: In situ observations using surface plasmon resonance in combination with surface-enhanced Raman spectroscopy. Tribol Lett 49(1): 95102 (2013)
[8]
Ye J, Khare H S, Burris D L. Transfer film evolution and its role in promoting ultra-low wear of a PTFE nanocomposite. Wear 297(1–2): 10951102 (2013)
[9]
Xu Q, Zhang J, Li X, van Duin D M, Hu Y Z, van Duin A C T, Ma T B. How polytetrafluoroethylene lubricates iron: An atomistic view by reactive molecular dynamics. ACS Appl Mater Interfaces 14(4): 62396250 (2022)
[10]
Blanchet T A, Kennedy F E. Sliding wear mechanism of polytetrafluoroethylene (PTFE) and PTFE composites. Wear 153(1): 229243 (1992)
[11]
Sun W, Liu X J, Liu K, Zhang Y, Lu Y X, Ye J X. Suppression of wear in gallium nitride fibers reinforced fluoropolymer composites: Synergistic effects of load support and tribochemistry. Tribol Int 165: 107286 (2022)
[12]
Sawyer W G, Freudenberg K D, Bhimaraj P, Schadler L S. A study on the friction and wear behavior of PTFE filled with alumina nanoparticles. Wear 254(5–6): 573580 (2003)
[13]
Shen M X, Li B, Zhang Z N, Zhao L Z, Xiong G Y. Abrasive wear behavior of PTFE for seal applications under abrasive-atmosphere sliding condition. Friction 8(4): 755767 (2020)
[14]
Burris D L, Sawyer W G. Improved wear resistance in alumina–PTFE nanocomposites with irregular shaped nanoparticles. Wear 260(7–8): 915918 (2006)
[15]
Campbell K L, Sidebottom M A, Atkinson C C, Babuska T F, Kolanovic C A, Boulden B J, Junk C P, Krick B A. Ultralow wear PTFE-based polymer composites—The role of water and tribochemistry. Macromolecules 52(14): 52685277 (2019)
[16]
Sun W, Liu X J, Song Q R, Liu K, Wang W, Lu Y X, Ye J X. Mechanochemical effect of filler surface functionality on fluoropolymer tribology. Macromolecules 54(13): 64176429 (2021)
[17]
Alam K I, Burris D L. Ultralow wear poly(tetrafluoroethylene): A virtuous cycle of wear reduction and tribochemical accumulation. J Phys Chem C 125(35): 1941719427 (2021)
[18]
Bowden F P, Tabor D. The Friction and Lubrication of Solids. Oxford (UK): Oxford University Press, 2001.
[19]
Bahadur S. The development of transfer layers and their role in polymer tribology. Wear 245(1–2): 9299 (2000)
[20]
Pitenis A A, Harris K L, Junk C P, Blackman G S, Sawyer W G, Krick B A. Ultralow wear PTFE and alumina composites: It is all about tribochemistry. Tribol Lett 57(1): 4 (2015)
[21]
Sun W, Ye J X, Liu X J, Liu K. Atomistic insights into anti-wear mechanisms and protective tribofilm formation in polytetrafluoroethylene composites. J Tribol 144(9): 091701 (2022)
[22]
Ye J X, Wei J, Zeng J, Alam K I, Sun W, Liu X J, Liu K, Burris D L. Interfacial gradient and its role in ultralow wear sliding. J Phys Chem C 124(11): 61886196 (2020)
[23]
Ye J, Moore A C, Burris D L. Transfer film tenacity: A case study using ultra-low-wear alumina–PTFE. Tribol Lett 59(3): 50 (2015)
[24]
Van Meter K E, Junk C P, Campbell K L, Babuska T F, Krick B A. Ultralow wear self-mated PTFE composites. Macromolecules 55(10): 39243935 (2022)
[25]
Alam K I, Baratz A, Burris D. Leveraging trace nanofillers to engineer ultra-low wear polymer surfaces. Wear 482–483: 203965 (2021)
[26]
Alam K I, Bragaw P, Burris D L. Isolating the tribochemical and mechanical effects of nanofillers on PTFE wear. Wear 494–495: 204256 (2022)
[27]
Zhao K, Aghababaei R. Adhesive wear law at the single asperity level. J Mech Phys Solids 143: 104069 (2020)
[28]
Onodera T, Nunoshige J, Kawasaki K, Adachi K, Kurihara K, Kubo M. Structure and function of transfer film formed from PTFE/PEEK polymer blend. J Phys Chem C 121(27): 1458914596 (2017)
[29]
Burris D L, Sawyer W G. Measurement uncertainties in wear rates. Tribol Lett 36(1): 8187 (2009)
[30]
Burris D L, Sawyer W G. A low friction and ultra low wear rate PEEK/PTFE composite. Wear 261(3–4): 410418 (2006)
[31]
Xu Q, Zhang J, Hu Y Z, Ma T B. Tribological behavior of poly(tetrafluoroethylene) and its composites reinforced by carbon nanotubes and graphene sheets: Molecular dynamics simulation. Phys Status Solidi-R 16(3): 2100298 (2022)
[32]
Haidar D R, Alam K I, Burris D L. Tribological insensitivity of an ultralow-wear poly(etheretherketone)–polytetrafluoroethylene polymer blend to changes in environmental moisture. J Phys Chem C 122(10): 55185524 (2018)
[33]
Lin L Y, Pei X Q, Bennewitz R, Schlarb A K. Tribological response of PEEK to temperature induced by frictional and external heating. Tribol Lett 67(2): 52 (2019)
[34]
Burris D L, Perry S S, Sawyer W G. Macroscopic evidence of thermally activated friction with polytetrafluoroethylene. Tribol Lett 27(3): 323328 (2007)
[35]
Yang Y W, Zhu J Y, Hou K M, Ma L M, Li Z P, Jia W H, Wang H G, Wang J Q, Yang S R. Friction-induced construction of PTFE-anchored MXene heterogeneous lubricating coating and its in-situ tribological transfer mechanism. Chem Eng J 442: 136238 (2022)
[36]
Song W L, An L, Lu Y, Zhang X, Wang S J. Friction behavior of TiN–MoS2/PTFE composite coatings in dry sliding against SiC. Ceram Int 47(17): 2400324011 (2021)
[37]
Choudhury D, Niyonshuti I I, Chen J Y, Goss J A, Zou M. Tribological performance of polydopamine+Ag nanoparticles/ PTFE thin films. Tribol Int 144: 106097 (2020)
[38]
Bashandeh K, Lan P X, Polycarpou A A. Tribology of self-lubricating high performance ATSP, PI, and PEEK-based polymer composites up to 300 °C. Friction 11(1): 141153 (2023)
[39]
Ren Y L, Zhang L, Xie G X, Li Z B, Chen H, Gong H J, Xu W H, Guo D, Luo J B. A review on tribology of polymer composite coatings. Friction 9(3): 429470 (2021)
[40]
Zeng G S, Tan C K, Tansu N, Krick B A. Ultralow wear of gallium nitride. Appl Phys Lett 109(5): 051602 (2016)
[41]
Sawyer W G, Argibay N, Burris D L, Krick B A. Mechanistic studies in friction and wear of bulk materials. Annu Rev Mater Res 44: 395427 (2014)
[42]
Harris K L, Pitenis, A A, Sawyer W G, Krick B A, Blackman G S, Kasprzak D J, Junk C P. PTFE tribology and the role of mechanochemistry in the development of protective surface films. Macromolecules 48(11): 37393745 (2015)
[43]
Sun W, Liu X J, Liu K, Wang W, Ye J X. Ultralow wear PTFE composites filled with beryllia and germania particles. Wear 450–451: 203270 (2020)
[44]
Sun W, Liu X J, Liu K, Xu J M, Lu Y X, Ye J X. Mechanochemical functionality of graphene additives in ultralow wear polytetrafluoroethylene composites. Carbon 184: 312321 (2021)
[45]
Ullah S, Haque F M, Sidebottom M A. Maintaining low friction coefficient and ultralow wear in metal-filled PTFE composites. Wear 498–499: 204338 (2022)
[46]
Sidebottom M A, Atkinson C A, Campbell K L, Babuska T F, Junk C P, Burch H E, Krick B A. Perfluoroalkoxy (PFA)–α-alumina composites: Effect of environment on tribological performance. Tribol Lett 68(1): 14 (2020)
[47]
Mojet B L, Ebbesen S D, Lefferts L. Light at the interface: The potential of attenuated total reflection infrared spectroscopy for understanding heterogeneous catalysis in water. Chem Soc Rev 39(12): 46434655 (2010)
[48]
Ye J X, Sun W, Zhang Y, Liu X J, Liu K. Measuring evolution of transfer film–substrate interface using low wear alumina PTFE. Tribol Lett 66(3): 100 (2018)
[49]
Drobny J G. Technology of Fluoropolymers. Boca Raton (USA): CRC Press, 2008.
[50]
Borovsky B P, Garabedian N T, McAndrews G R, Wieser R J, Burris D L. Integrated QCM-microtribometry: Friction of single-crystal MoS2 and gold from μm/s to m/s. ACS Appl Mater Interfaces 11(43): 4096140969 (2019)
[51]
Rabinowicz E. Friction and Wear of Materials, 2nd edn. Hoboken (USA): Wiley-Interscience, 1995.
[52]
Beamson G, Clark D T, Deegan D E, Hayes N W, Law D S L, Rasmusson J R, Salaneck W R. Characterization of PTFE on silicon wafer tribological transfer films by XPS, imaging XPS and AFM. Surf Interface Anal 24(3): 204210 (1996)
[53]
Sun W, Song Q R, Liu K, Liu X J, Ye J X. The limit of adhesive debris retention: A case study using ultra-low wear alumina–PTFE. Wear 496–497: 204274 (2022)
[54]
Louette P, Bodino F, Pireaux J J. Poly(ether ether ketone) (PEEK) XPS reference core level and energy loss spectra. Surf Sci Spectra 12(1): 149153 (2005)
[55]
Kassis C M, Steehler J K, Linton R W. Characterization of 1,1-dihydroperfluorooctyl acrylate (PFOA) by XPS. Surf Sci Spectra 3(4): 299306 (1994)
[56]
Khare H S, Moore A C, Haidar D R, Gong L, Ye J, Rabolt J F, Burris D L. Interrelated effects of temperature and environment on wear and tribochemistry of an ultralow wear PTFE composite. J Phys Chem C 119(29): 1651816527 (2015)
Friction
Pages 120-135
Cite this article:
SUN W, YE J, SONG Q, et al. Ultralow friction PTFE/PEEK heterolayer: A new solid lubrication approach toward simplicity. Friction, 2024, 12(1): 120-135. https://doi.org/10.1007/s40544-023-0747-9

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Received: 11 November 2022
Revised: 03 January 2023
Accepted: 08 February 2023
Published: 22 June 2023
© The author(s) 2023.

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