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Research Article | Open Access

Electrochemically-stimulated nanoscale mechanochemical wear of silicon

Chen XIAO1,2, Stefan VAN VLIET1, Roland BLIEM1,2, Bart WEBER1,2, Steve FRANKLIN1,3( )
Advanced Research Center for Nanolithography (ARCNL), Amsterdam 1098XG, the Netherlands
Van der Waals–Zeeman Institute, Institute of Physics, University of Amsterdam (UvA), Amsterdam 1098XG, the Netherlands
Department of Materials Science and Engineering, The University of Sheffield, Sheffield S13JD, UK
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Abstract

Mechanochemical reactions at the sliding interface between a single-crystalline silicon (Si) wafer and a silica (SiO2) microsphere were studied in three environmental conditions: humid air, potassium chloride (KCl) solution, and KCl solution with an applied voltage. Compared to that from humid air, mechanochemical material removal from the silicon surface increased substantially in the KCl-immersed condition, and further increased when electrochemistry was introduced into the tribological system. By measuring the load dependence of the material removal rate and analyzing the results using a mechanically assisted Arrhenius-type kinetic model, the activation energy (Ea) and the mechanical energy (Em), by which this energy is reduced by mechanical activation, were compared qualitatively under different environmental conditions. In the KCl-immersed condition, mechanochemistry may decrease the required effective energy of reactions (Eeff = Ea − Em) and promote material removal mainly through improved catalysis of the mechanochemical reactions facilitated by greater availability of water molecules compared to the humid air condition. Thus, the effectiveness of the mechanochemistry is improved. In the electrochemical condition, electrochemically-accelerated oxidation of the silicon surface was confirmed by the X-ray photoelectron spectroscopy (XPS) characterization. The results strongly suggest that electrochemistry further stimulates mechanochemical reactions primarily by increasing the initial energy state of the surface via the facilitated formation of interfacial bonding bridges, i.e., a surface oxidation/hydroxylation process.

Keywords

spherical contactadhesive wearnormal loadingpower law

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References

[1]
Xue Y R, Li X, Li H B, Zhang W K. Quantifying thiol–gold interactions towards the efficient strength control. Nat Commun 5: 4348 (2014)
Crossref Google Scholar
[2]
Zhai W Z, Bai L C, Zhou R H, Fan X L, Kang G Z, Liu Y, Zhou K. Recent progress on wear-resistant materials: Designs, properties, and applications. Adv Sci 8(11): 2003739 (2021)
Crossref Google Scholar
[3]
James S L, Friščić T. Mechanochemistry. Chem Soc Rev 42(18): 7494–7496 (2013)
Crossref Google Scholar
[4]
Martini A, Eder S J, Dörr N. Tribochemistry: A review of reactive molecular dynamics simulations. Lubricants 8(4): 44 (2020)
Crossref Google Scholar
[5]
Guo J, Gao J, Xiao C, Chen L, Qian L M. Mechanochemical reactions of GaN–Al2O3 interface at the nanoasperity contact: Roles of crystallographic polarity and ambient humidity. Friction 10(7): 1005–1018 (2022)
Crossref Google Scholar
[6]
Leriche C, Franklin S, Weber B. Measuring multi-asperity wear with nanoscale precision. Wear 498–499: 204284 (2022)
Crossref Google Scholar
[7]
Xiao C, Hsia F C, Sutton-Cook A, Weber B, Franklin S. Polishing of polycrystalline diamond using synergies between chemical and mechanical inputs: A review of mechanisms and processes. Carbon 196: 29–48 (2022)
Crossref Google Scholar
[8]
Kim S H, Asay D B, Dugger M T. Nanotribology and MEMS. Nano Today 2(5): 22–29 (2007)
Crossref Google Scholar
[9]
Zhang L F, Lu D, Deng H. Study on material removal mechanisms in electrochemical etching-enhanced polishing of GaN. J Manuf Process 73: 903–913 (2022)
Crossref Google Scholar
[10]
Chen Z J, Zhao Y H. Investigation into electrochemical oxidation behavior of 4H-SiC with varying anodizing conditions. Electrochem Commun 109: 106608 (2019)
Crossref Google Scholar
[11]
Zhai W J. Research progress in tribo-electrochemistry and tribo-electrochemical polishing. Front Mech Eng-PRC 2(4): 463–467 (2007)
Crossref Google Scholar
[12]
Lingwall B A, Sexton T N, Cooley C H. Polycrystalline diamond bearing testing for marine hydrokinetic application. Wear 302(1–2): 1514–1519 (2013)
Crossref Google Scholar
[13]
Conlisk A T. Essentials of Micro- and Nanofluidics: With Applications to the Biological and Chemical Sciences. Cambridge (UK): Cambridge University Press, 2012.
Crossref
[14]
Berradja A. Metallic glasses for triboelectrochemistry systems. In: Metallic Glasses—Properties and Processing. Huang H, Ed. London (UK): IntechOpen, 2018: 77–109.
Crossref
[15]
Zhou F, Ma Q, Wang Q Z, Zhou Z F, Li L K Y. Electrochemical and tribological properties of CrBCN coatings with various B concentrations in artificial seawater. Tribol Int 116: 19–25 (2017)
Crossref Google Scholar
[16]
Fu Y Q, Zhou F, Zhang M D, Wang Q Z, Zhou Z F. Structure and tribocorrosion behavior of CrMoSiCN nanocomposite coating with low C content in artificial seawater. Friction 9(6): 1599–1615 (2021)
Crossref Google Scholar
[17]
Zhang X G, Zhang Y L, Jin Z M. A review of the bio-tribology of medical devices. Friction 10(1): 4–30 (2022)
Crossref Google Scholar
[18]
Xiao C, Deng C B, Zhang P, Qian L M, Kim S H. Interplay between solution chemistry and mechanical activation in friction-induced material removal of silicon surface in aqueous solution. Tribol Int 148: 106319 (2020)
Crossref Google Scholar
[19]
Xiao C, Chen C, Guo J, Zhang P, Chen L, Qian L M. Threshold contact pressure for the material removal on monocrystalline silicon by SiO2 microsphere. Wear 376–377(A): 188–193 (2017)
Crossref Google Scholar
[20]
Xiao C, Xin X J, He X, Wang H B, Chen L, Kim S H, Qian L M. Surface structure dependence of mechanochemical etching: Scanning probe-based nanolithography study on Si(100), Si(110), and Si(111). ACS Appl Mater Interfaces 11(23): 20583–20588 (2019)
Crossref Google Scholar
[21]
Wen J L, Ma T B, Zhang W W, Psofogiannakis G, van Duin A C T, Chen L, Qian L M, Hu Y Z, Lu X C. Atomic insight into tribochemical wear mechanism of silicon at the Si/SiO2 interface in aqueous environment: Molecular dynamics simulations using ReaxFF reactive force field. Appl Surf Sci 390: 216–223 (2016)
Crossref Google Scholar
[22]
Yeon J, van Duin A C T, Kim S H. Effects of water on tribochemical wear of silicon oxide interface: Molecular dynamics (MD) study with reactive force field (ReaxFF). Langmuir 32(4): 1018–1026 (2016)
Crossref Google Scholar
[23]
Chen L, Wen J L, Zhang P, Yu B J, Chen C, Ma T B, Lu X C, Kim S H, Qian L M. Nanomanufacturing of silicon surface with a single atomic layer precision via mechanochemical reactions. Nat Commun 9: 1542 (2018)
Crossref Google Scholar
[24]
Luo C S, Jiang Y L, Liu Y Q, Wang Y, Sun J H, Qian L M, Chen L. Role of interfacial bonding in tribochemical wear. Front Chem 10: 852371 (2022)
Crossref Google Scholar
[25]
Jacobs T D B, Carpick R W. Nanoscale wear as a stress- assisted chemical reaction. Nat Nanotechnol 8(2): 108–112 (2013)
Crossref Google Scholar
[26]
Martini A, Kim S H. Activation volume in shear-driven chemical reactions. Tribol Lett 69(4): 150 (2021)
Crossref Google Scholar
[27]
Fernández-Bertran J F. Mechanochemistry: An overview. Pure Appl Chem 71(4): 581–586 (1999)
Crossref Google Scholar
[28]
Beyer M K, Clausen-Schaumann H. Mechanochemistry: The mechanical activation of covalent bonds. Chem Rev 105(8): 2921–2948 (2005)
Crossref Google Scholar
[29]
Gosvami N N, Bares J A, Mangolini F, Konicek A R, Yablon D G, Carpick R W. Mechanisms of antiwear tribofilm growth revealed in situ by single-asperity sliding contacts. Science 348(6230): 102–106 (2015)
Crossref Google Scholar
[30]
Chen L, Xiao C, He X, Yu B J, Kim S H, Qian L M. Friction and tribochemical wear behaviors of native oxide layer on silicon at nanoscale. Tribol Lett 65(4): 139 (2017)
Crossref Google Scholar
[31]
Yeon J, He X, Martini A, Kim S H. Mechanochemistry at solid surfaces: Polymerization of adsorbed molecules by mechanical shear at tribological interfaces. ACS Appl Mater Interfaces 9(3): 3142–3148 (2017)
Crossref Google Scholar
[32]
Beyer M K. The mechanical strength of a covalent bond calculated by density functional theory. J Chem Phys 112(17): 7307–7312 (2000)
Crossref Google Scholar
[33]
Gotsmann B, Lantz M A. Atomistic wear in a single asperity sliding contact. Phys Rev Lett 101(12): 125501 (2008)
Crossref Google Scholar
[34]
Spikes H. Stress-augmented thermal activation: Tribology feels the force. Friction 6(1): 1–31 (2018)
Crossref Google Scholar
[35]
Tysoe W. On stress-induced tribochemical reaction rates. Tribol Lett 65(2): 48 (2017)
Crossref Google Scholar
[36]
He X, Kim S H. Surface chemistry dependence of mechanochemical reaction of adsorbed molecules—An experimental study on tribopolymerization of α-pinene on metal, metal oxide, and carbon surfaces. Langmuir 34(7): 2432–2440 (2018)
Crossref Google Scholar
[37]
Xiao C, Li J, Guo J, Zhang P, Yu B J, Chen L, Qian L M. Role of mechanically-driven distorted microstructure in mechanochemical removal of silicon. Appl Surf Sci 520: 146337 (2020)
Crossref Google Scholar
[38]
Xiao C, Chen C, Wang H B, Chen L, Jiang L, Yu B J, Qian L M. Effect of counter-surface chemistry on defect-free material removal of monocrystalline silicon. Wear 426–427(B): 1233–1239 (2019)
Crossref Google Scholar
[39]
Xiao C, Elam F, van Vliet S, Bliem R, Lépinay S, Shahidzadeh N, Weber B, Franklin S. Intercrystallite boundaries dominate the electrochemical corrosion behavior of polycrystalline diamond. Carbon 200: 1–9 (2022)
Crossref Google Scholar
[40]
Schwarz U D. A generalized analytical model for the elastic deformation of an adhesive contact between a sphere and a flat surface. J Colloid Interf Sci 261(1): 99–106 (2003)
Crossref Google Scholar
[41]
Hsia F C, Elam F M, Bonn D, Weber B, Franklin S E. Wear particle dynamics drive the difference between repeated and non-repeated reciprocated sliding. Tribol Int 142: 105983 (2020)
Crossref Google Scholar
[42]
Hsia F C, Franklin S, Audebert P, Brouwer A M, Bonn D, Weber B. Rougher is more slippery: How adhesive friction decreases with increasing surface roughness due to the suppression of capillary adhesion. Phys Rev Res 3(4): 043204 (2021)
Crossref Google Scholar
[43]
Hsia F C, Hsu C C, Peng L, Elam F M, Xiao C, Franklin S, Bonn D, Weber B. Contribution of capillary adhesion to friction at macroscopic solid–solid interfaces. Phys Rev Appl 17(3): 034034 (2022)
Crossref Google Scholar
[44]
Luo Y R. Comprehensive Handbook of Chemical Bond Energies. Boca Raton (USA): CRC Press, 2007.
Crossref
[45]
Felts J R, Oyer A J, Hernández S C, Whitener K E, Robinson J T, Walton S G, Sheehan P E. Direct mechanochemical cleavage of functional groups from graphene. Nat Commun 6: 6467 (2015)
Crossref Google Scholar
[46]
Carpick R W, Salmeron M. Scratching the surface: Fundamental investigations of tribology with atomic force microscopy. Chem Rev 97(4): 1163–1194 (1997)
Crossref Google Scholar
[47]
Chen L, Qian L M. Role of interfacial water in adhesion, friction, and wear—A critical review. Friction 9(1): 1–28 (2021)
Crossref Google Scholar
[48]
Jensen D S, Kanyal S S, Madaan N, Vail M A, Dadson A E, Engelhard M H, Linford M R. Silicon (100)/SiO2 by XPS. Surf Sci Spectra 20(1): 36–42 (2013)
Crossref Google Scholar
[49]
Xiao C, Chen C, Yao Y Y, Liu H S, Chen L, Qian L M, Kim S H. Nanoasperity adhesion of the silicon surface in humid air: The roles of surface chemistry and oxidized layer structures. Langmuir 36(20): 5483–5491 (2020)
Crossref Google Scholar
[50]
Ma H R, Bennewitz R. Nanoscale friction and growth of surface oxides on a metallic glass under electrochemical polarization. Tribol Int 158: 106925 (2021)
Crossref Google Scholar
[51]
Dziaduszewska M, Shimabukuro M, Seramak T, Zielinski A, Hanawa T. Effects of micro-arc oxidation process parameters on characteristics of calcium-phosphate containing oxide layers on the selective laser melted Ti13Zr13Nb alloy. Coatings 10(8): 745 (2020)
Crossref Google Scholar
Friction
Volume 11 Issue 11,
November 2023
Pages 2142-2152
DOI: 10.1007/s40544-023-0764-4
Cite this article:
XIAO C, VAN VLIET S, BLIEM R, et al. Electrochemically-stimulated nanoscale mechanochemical wear of silicon. Friction, 2023, 11(11): 2142-2152. https://doi.org/10.1007/s40544-023-0764-4

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Received: 24 December 2022
Revised: 15 February 2023
Accepted: 21 March 2023
Published: 22 June 2023
© The author(s) 2023.

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