AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Home Friction Article
PDF (2.3 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

An approach of the internal friction-dependent temperature changes for conventional and pure biogenic lubricating greases

Leif AHME1( )Erik KUHN1Miguel Ángel DELGADO2
Department of Mechanical Engineering and Production Management, Hamburg University of Applied Sciences, Hamburg 20099, Germany
Department of Chemical Engineering, Research in Product Technology and Chemical Processes (Pro2TecS), University of Huelva, Huelva 21071, Spain
Show Author Information

Graphical Abstract

Abstract

This work investigated the temperature changes inside the bulk of lubricating greases under controlled high-shear stress conditions (250–500 s-1). For this purpose, a newly developed temperature-measuring cell called Calidus was successfully tested. The temperature changes (ΔT) have been related to the greases' components (thickener, base oil-type, and composition) and the structural degradation of the lubricating greases. Furthermore, a theoretical approach was proposed for calculating the internal temperature change of lubricating greases during shear stress. All greases showed an internal temperature profile characterised by a sudden rise in ΔT within the first 4 h from starting the test and subsequent ΔT decay until it reaches the steady state value. Furthermore, it was found that greases C1 and C5, formulated with lithium and calcium soap, respectively, with different soap content (16.1 wt% and 9.7 wt%, respectively), but the same base castor oil, showed the highest value of the maximum ΔT, c.a. 3.2 K, and the most drastic drop of ΔT. These greases showed both the highest specific densities and heat capacities. In addition, they showed the lowest ratio of expended energies (Rtee), which means more structural degradation in the stressed grease. On the contrary, the grease C3, with 13 wt% of Li-soap but the lowest base oil's viscosity, showed the lowest maximum ΔT and the temperature profile was characterised by a moderate variation of ΔT along the test. The biogenic grease B3 developed a low-temperature change in the group of pure bio-genic greases close to grease C3.

Electronic Supplementary Material

Download File(s)
40544_0818_ESM.pdf (891.1 KB)

References

[1]
Dresel W, Heckler R P. Lubricating Grease. In: Lubricants and Lubrication, 2nd Ed. Mang T, Dresel W, Eds. Weinheim: Wiley-VCH, 2007: 603646.
[2]
Kuhn E. Zur Tribologie der Schmierfette: Eine energetische Betrachtungsweise des Reibungs- und Verschleißprozesses, 2nd ed. Renningen: expert Verlag, 2017 (in German).
[3]
Bartz W J. Schmierfette: Zusammensetzung, Eigenschaften, Prüfung und Anwendung. Renningen-Malmsheim: expert-Verl., 2000 (in German).
[4]
Paszkowski M. Assessment of the effect of temperature, shear rate and thickener content on the thixot-ropy of lithium lubricating greases. Proc Inst Mech Eng Part J 227(3): 209219 (2013)
[5]
Sánchez R, Valencia C, Franco J M. Rheological and tribological characteriza-tion of a new acylated chitosan–based biodegradable lubricating grease: A compara-tive study with traditional lithium and calcium greases. Tribol Trans 57(3): 445454 (2014)
[6]
Rezasoltani A, Khonsari M M. On the correlation between mechanical degrada-tion of lubricating grease and entropy. Tribol Lett 56(2): 197204 (2014)
[7]
Zhou Y. On the mechanical ageing of lubricating greases. Ph.D. Thesis. Beijing (China): University of Twente, 2018.
[8]
Delgado M A, Franco J M, Kuhn E. Effect of rheological behaviour of lithium greases on the friction process. Ind Lubr Tribol 60(1): 3745 (2008)
[9]
Kuhn E. Correlation between system entropy and structural changes in lubricating grease. Lubricants 3(2): 332345 (2015)
[10]
Kuhn E. Application of a thermodynamic concept for the analysis of structural degradation of soap thickened lubricating greases. Lubricants 6(1): 7 (2018)
[11]
Kuhn E. Experimental grease investigations from an energy point of view. Ind Lubr Tribol 51(5): 246251 (1999)
[12]
Osara J, Bryant M. Thermodynamics of grease degradation. Tribol Int 137: 433445 (2019)
[13]
Rezasoltani A, Khonsari M. An engineering model to estimate consistency reduction of lubricating grease sub-jected to mechanical degradation under shear. Tribol Int 103: 465474 (2016)
[14]
Bryant M, Khonsari M, Ling F. On the thermodynamics of degradation. Proc R Soc A 464: 20012014 (2008)
[15]
Kuhn E. Tribological stress of lubricating greases in the light of system entropy. Lubricants 4(4): 37 (2016)
[16]
Adhvaryu A, Sung C, Erhan S Z. Fatty acids and antioxidant effects on grease microstructures. Ind Crops Prod 21(3): 285291 (2004)
[17]
Delgado M, Valencia C, Sánchez M C, Franco J, Gallegos C. Fatty acids and antioxidant effects on grease microstructures. Tribol Lett 23: 4754 (2006)
[18]
Pan J, Yanhai C, Yang J. Effect of Heat treatment on lubricating properties of lithium lubricating grease. RSC Adv 5: 5868658693 (2015)
[19]
Osara J, Bryant M. A temperature-only system degradation analysis based on thermal entropy and the degradation-entropy generation methodology. Int J Heat Mass Transfer 158: 120051 (2020)
[20]
Zhou Y, Bosman R, Lugt P. A master curve for the shear degradation of lubricating greases with a fibrous structure. Tribol Trans 62: 121 (2018)
[21]
Delgado M A, Valencia C, Sánchez M C, Franco J M, Gallegos C. Influence of soap concentration and oil viscosity on the rheology and microstructure of lubricating greases. Ind Eng Chem Res 45(6): 19021910 (2006)
[22]
Acar N, Kuhn E, Franco J M. Tribological and rheological characterization of new completely biogenic lubricating greases: A comparative experimental investigation. Lubricants 6(2): 45 (2018)
[23]
Acar N, Franco J M, Kuhn E, Gonçalves D E P, Seabra J H O. Tribological investigation on the friction and wear behaviors of biogenic lubricating greases in steel–steel contact. Appl Sci 10(4): 1477 (2020)
[24]
NETZSCH-Gerätebau GmbH, Precise determination of the specific heat capacity by means of DSC on https://www.netzsch-thermal-analysis.com/en/contract-testing/tips-tricks/dsc/precise-determination-of-the-specific-heat-by-means-of-dsc/, 2022.
[25]
NETZSCH-Gerätebau GmbH, Specific heat capacity (cp), on https://www.netzsch-thermal-analysis.com/en/contract-testing/glossary/specific-heat-capacity-cp/, 2022.
[26]
Delgado M A, Secouard S, Valencia C, Franco J M. On the steady-state flow and yielding behaviour of lubricating greases. Fluids 4(1): 1477 (2019)
[27]
Deutsches Institut für Normung. DIN 51810 Prüfung von Schmierstoffen-Prüfung der rheologischen Eigenschaften von Schmierfetten: Teil 1: Bestimmung der Scherviskosität mit dem Rotationsviskosimeter und dem Messsystem Kegel/Platte. Beuth, 2017 (in German), on https://www.beuth.de/de/norm/din-51810-1/269916043.
[28]
European Chemicals Agency, Lithium stearate: Density on: https://echa.europa.eu/es/registration-dossier/-/registered-dossier/22040/4/5, 2022.
[29]
[30]
European Chemicals Agency, fatty acids, tallow, calcium salts: density, on https://echa.europa.eu/es/registration-dossier/-/registered-dossier/5720/4/5, 2022.
[31]
Polymer Properties Database, Polyhydroxybutyrate: Density, on https://polymerdatabase.com/polymers/poly3-hydroxybutyrate.html, 2022.
[32]
European Chemicals Agency, Urea: Density, on https://echa.europa.eu/de/registration-dossier/-/registered-dossier/16152/4/5, 2022.
[33]
Chemical Book, Ethyl cellulose: Density, on https://www.chemicalbook.com/ChemicalProductProperty_EN_CB6165620.htm, 2022.
[34]
European Chemicals Agency, Castor oil: Density, on https://echa.europa.eu/de/registration-dossier/-/registered-dossier/14599/4/5, 2022.
[35]
Tinto W F, Elufioye T O, Roach J. Chapter 22-Waxes. In: Pharmacognosy. Badal S, Delgoda R, Eds. Boston: Academic Press, 2017: 443455.
[36]
OKS Spezialschmierstoffe GmbH, oils with high-performance additives for reliable lubrication: properties of base oils, on https://www.oks-germany.com/en/tribology/types-of-lubricants/oils/, 2022.
[37]
AMD Special Oil LLC, Sunflower Oil, High Oleic RBDW: Density, on https://www.amdoilsales.com/products/ho-sunflower/, 2022.
[38]
Kraft Chemical, Safety Data Sheet MTC oil: Density, on https://greenfield.com/wp-content/uploads/2018/11/MCT-Oil-SDS.pdf, 2022.
[39]
PubChem, Cellulose: Density, on https://pubchem.ncbi.nlm.nih.gov/compound/CELLULOSE, 2022.
[40]
Wikipedia, Glycerol monostearate: Density, on https://en.wikipedia.org/wiki/Glycerol_monostearate, 2022.
[41]
[42]
PubChem, 1-Hexadecanol (Cetyl alcohol): Density, on https://pubchem.ncbi.nlm.nih.gov/compound/1-Hexadecanol#section=Density, 2022.
[43]
Ahme L, Kuhn E, Delgado Canto M Á. Experimental study on the expended energy on structural degradation of lubricating greases. Tribol lett 70(3): 81(2022)
[44]
Wu L, Tan Q. A study of cooling system in a grease-lubricated precision spindle. Adv Mech Eng 8(8): 1687814016665296 (2016)
[45]
Balan C, Franco J M. Influence of the geometry on the transient and steady flow of lubricating greases. Tribol Trans 44(1): 5358 (2001)
Friction
Pages 780-795
Cite this article:
AHME L, KUHN E, DELGADO MÁ. An approach of the internal friction-dependent temperature changes for conventional and pure biogenic lubricating greases. Friction, 2024, 12(4): 780-795. https://doi.org/10.1007/s40544-023-0818-7

311

Views

12

Downloads

1

Crossref

1

Web of Science

1

Scopus

0

CSCD

Altmetrics

Received: 17 December 2022
Revised: 25 May 2023
Accepted: 27 August 2023
Published: 20 December 2023
© The author(s) 2023.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Return