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Research Article | Open Access

Nanostructured lubricant additives for titanium alloy: Lubrication by the solid–liquid interface with Coulomb repulsion

Linlin DUAN1,2, Dan JIA1,2, Jian LI1,2, Jianfang LIU3, Haitao DUAN1,2( )
State Key Laboratory of Special Surface Protection Materials and Application Technology, Wuhan Research Institute of Materials Protection, Wuhan 430030, China
Hubei Longzhong Laboratory, Xiangyang 441000, China
College of Life Science and Technology, Wuhan Polytechnic University, Wuhan 430030, China
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Abstract

In this work, the advantage of Coulomb repulsion in the intermolecular forces experienced by molecules on the solid–liquid nanosized contact interface is taken, and the superior friction-reducing property of Cu3(PO4)2·3H2O (CuP) oil-based additives has been confirmed for titanium alloy. Three-dimensional (3D) CuP nanoflowers (CuP-Fs) with a strong capillary absorption effect are prepared to achieve the homogeneous mixing of solid CuP and lubricating oil. Lubrication by CuP-Fs additives for titanium alloy, friction coefficient (COF) can be reduced by 73.68%, and wear rate (WR) reduced by 99.69%. It is demonstrated that the extraordinary friction-reducing property is due to the repulsive solid–liquid interface with low viscous shear force originating from Coulomb repulsion between polar water molecules in CuP and non-polar oil molecules. However, any steric hindrance or connection between this repulsive solid–liquid interface will trigger the adhesion and increase the viscous shear force, for example, dispersant, hydrogen bondings, and shaky adsorbed water molecules. Besides, the lamellar thickness of CuP and the molecular size of lubricant both have a great influence on tribological properties. Here the lubrication mechanism based on interface Coulomb repulsion is proposed that may help broaden the scope of the exploration in low-friction nanomaterial design and new lubricant systems.

Keywords

wearlubricationnanomaterialadditivesolid–liquid interface

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References

[1]
Berman D, Erdemir A, Sumant A. Approaches for achieving superlubricity in two-dimensional materials. ACS Nano 12(3): 2122–2137 (2018)
Crossref Google Scholar
[2]
Fu X, Qiu Y, Zhao Y. Lipid incorporated synthetic hydrogels show cartilage-like lubrication. Sci Bull 5(66): 409–410 (2021)
Crossref Google Scholar
[3]
Maeda N, Chen N, Tirrell M, Israelachvili J. Adhesion and friction mechanisms of polymer-on-polymer Surfaces. Science 297(5580): 379–382 (2002)
Crossref Google Scholar
[4]
Vacha R, Rick S W, Jungwirth P, Beer A, Aguiar H, Samson J S, Roke S. The orientation and charge of water at the hydrophobic oil droplet water interface. J Am Chem Soc 133(26): 10204–10210 (2011)
Crossref Google Scholar
[5]
Wright R, Wang K, Qu J, Zhao B. Oil-soluble polymer brush grafted nanoparticles as effective lubricant additives for friction and wear reduction. Angew Chem Int Ed Engl 128(30): 8656–8660 (2016)
Crossref Google Scholar
[6]
Qu J, Barnhill W, Luo H, Meyer H M, Leonard D N, Landauer A K, Kheireddin B, Gao H, Papke B L, Dai S. Synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) as lubricant additives. Adv Mater 27(32): 4767–4774 (2015)
Crossref Google Scholar
[7]
Wu W, Liu J, Li Z, Zhao X, Liu G, Liu S, Ma S, Li W, Liu W. Surface-functionalized nanoMOFs in oil for friction and wear reduction and antioxidation. Chem Eng J 410: 128306 (2021)
Crossref Google Scholar
[8]
Song H, Wang Z, Yang J, Jia X, Zhang Z. Facile synthesis of copper/polydopamine functionalized graphene oxide nano composites with enhanced tribological performance. Chem Eng J 324: 51–62 (2017)
Crossref Google Scholar
[9]
Mou Z, Wang B, Lu H, Dai S, Huang Z. Synthesis of poly(ionic liquid)s brush-grafted carbon dots for high-performance lubricant additives of polyethylene glycol. Carbon 154: 301–312 (2019)
Crossref Google Scholar
[10]
Zhai W, Zhou K. Nanomaterials in superlubricity. Adv Funct Mater 29(28): 1806395 (2019)
Crossref Google Scholar
[11]
Duan L L, Li J, Duan H T. Nanomaterials for lubricating oil application: A review. Friction 11(5): 647–684 (2023)
Crossref Google Scholar
[12]
Schauerte O. Titanium in automotive production. Adv Eng Mater 5: 411–418 (2003)
Crossref Google Scholar
[13]
Veiga C, Devim J P, Loureiro A J R. Properties and applications of titanium alloys: A brief review. Rev Adv Mater Sci 32: 133–148 (2012)
Google Scholar
[14]
Amanov A, Sasaki S. A study on the tribological characteristics of duplex-treated Ti–6Al–4V alloy under oil-lubricated sliding conditions. Tribol Int 64: 155–163 (2013)
Crossref Google Scholar
[15]
Hod O, Meyer E, Zheng Q. Urbakh M. Structural superlubricity and ultralow friction across the length scales. Nature 563: 485–492 (2018)
Crossref Google Scholar
[16]
Duan L, Jia D, Zhan S, Zhang W, Yang T, Tu J, Liu J, Li J, Duan H. Copper phosphate nanosheets as high-performance oil-based nanoadditives: Tribological properties and lubrication mechanism. Tribol Int 179: 108077 (2023)
Crossref Google Scholar
[17]
Wu X, Gong K, Zhao G, Lou W, Wang X, Liu W. MoS2/WS2 quantum dots as high‐performance lubricant additive in polyalkylene glycol for steel/steel contact at elevated temperature. Adv Mater Inter 5: 1700859 (2018)
Crossref Google Scholar
[18]
Osim W, Stojanovic A, Akbarzadeh J, Peterlik H, Binder W. Surface modification of MoS2 nanoparticles with ionic liquid-ligands: towards highly dispersed nanoparticles. Chem Commun (Camb) 49: 9311–9313 (2013)
Crossref Google Scholar
[19]
Gong K, Wu X, Zhao G, Wang X. Tribological properties of polymeric aryl phosphates grafted onto multi-walled carbon nanotubes as high-performances lubricant additive. Tribol Int 116: 172–179 (2017)
Crossref Google Scholar
[20]
Kogovšek J, Kalin M. Various MoS2-, WS2- and C-based micro- and nanoparticles in boundary lubrication. Tribol Lett 53: 585–597 (2014)
Crossref Google Scholar
[21]
Wang H, Liu Y, Liu W, Wang R, Wen J, Sheng H, Peng J, Erdemir A, Luo J. Tribological behavior of NiAl-layered double hydroxide nanoplatelets as oil-based lubricant additives. ACS Appl Mater Inter 9: 30891–30899 (2017)
Crossref Google Scholar
[22]
Qu J, Blau P, Watkins T, Cavin O, Kulkarni N. Friction and wear of titanium alloys sliding against metal, polymer, and ceramic counterfaces. Wear 258: 1348–1356 (2005)
Crossref Google Scholar
[23]
Cafolla C, Voïtchovsky K. Voïtchovsky. Lubricating properties of single metal ions at interfaces. Nanoscale 10: 11831–11840 (2018)
Crossref Google Scholar
[24]
Bocquet L, Charlaix E. Nanofluidics from bulk to interfaces. Chem Soc Rev 39: 1073–1095 (2010)
Crossref Google Scholar
[25]
Liu X, Xu N, Li W, Zhang M, Chen L, Lou W, Wang X. Exploring the effect of nanoparticle size on the tribological properties of SiO2/polyalkylene glycol nanofluid under different lubrication conditions. Tribol Int 109: 467–472 (2017)
Crossref Google Scholar
[26]
Wang Z, Ren R, Song H, Jia X. Improved tribological properties of the synthesized copper/carbon nanotube nanocomposites for rapeseed oil-based additives. Appl Surf Sci 428: 630–639 (2018)
Crossref Google Scholar
[27]
Bozzini S, Petrini P, Tanzi MC, Zurcher S, Tosatti S. Poly(ethylene glycol) and hydroxy functionalized alkane phosphate mixed self-assembled monolayers to control nonspecifific adsorption of proteins on titanium oxide surfaces. Langmuir 26: 6529–6534 (2010)
Crossref Google Scholar
[28]
Yang Y, Zhang C, Wang Y, Dai Y, Luo J. Friction and wear performance of titanium alloy against tungsten carbide lubricated with phosphate ester. Tribol Int 95: 27–34 (2016)
Crossref Google Scholar
[29]
Mani G, Johnson D M, Marton D, Dougherty V L, Feldman M D, Patel D, Ayon A, Agrawal M. Stability of self-assembled monolayers on titanium and gold. Langmuir 24: 6774–6784 (2008)
Crossref Google Scholar
[30]
James N, Han E, Cruz R, Jureller J, Jaeger H. Interparticle hydrogen bonding can elicit shear jamming in dense suspensions. Nat Mater 17: 965–970 (2018)
Crossref Google Scholar
[31]
James N, Hsu C, Spencer N. Tuning interparticle hydrogen bonding in shear-jamming suspensions: Kinetic effects and consequences for tribology and rheology. J Phys Chem Lett 10(8): 1663–1668 (2019)
Crossref Google Scholar
[32]
Pullanchery S, Kulik S, Rehl B, Hassanali A, Roke S. Charge transfer across C-H…O hydrogen bonds stabilizes oil droplets in water. Science 374(6573): 1366–1370 (2021)
Crossref Google Scholar
[33]
Ilan B. Molecular structure and dynamics at liquid-liquid interfaces. Annu Rev Phys Chem 48: 407–451 (1997)
Crossref Google Scholar
[34]
Hsu C, Mandal J, Ramakrishna S, Spencer N, Isa L. Exploring the roles of roughness, friction and adhesion in discontinuous shear thickening by means of thermo-responsive particles. Nat Commun 12: 1477 (2021)
Crossref Google Scholar
[35]
Peters I, Majumdar S, Jaeger H. Direct observation of dynamic shear jamming in dense suspensions. Nature 532: 214–217 (2016)
Crossref Google Scholar
[36]
Mohammed R, Bailey A, Luckham P, Taylor S. Dewatering of crude oil emulsions 1. Rheological behaviour of the crude oil-water interface. Colloid Surface A 80(2–3): 223–235 (1993)
Crossref Google Scholar
[37]
Yan Z, Qu J. Ionic liquids as lubricant additives: A review. ACS Appl Mater Inter 9(4): 3209 (2016)
Crossref Google Scholar
[38]
Ivanov I. Effect of surface mobility on the dynamic behavior of thin liquid films. Pure Appl Chem 52: 1241–1262 (1980)
Crossref Google Scholar
[39]
Gu W, Chu K, Lu Z, Zhang G, Qi S. Synergistic effects of 3D porous graphene and T161 as hybrid lubricant additives on 316 ASS surface. Tribol Int 161: 107072 (2021)
Crossref Google Scholar
[40]
Sun C, Sun Y, Ni Y, Zhang X, Pan J, Wang X, Zhou J, Li L, Zheng W, Yu S, Pan L, Sun Z. Coulomb repulsion at the nanometer-sized contact: A force driving superhydrophobicity, superfluidity, superlubricity, and supersolidity. J Phys Chem C 113(46): 20009–20019 (2009)
Crossref Google Scholar
Friction
Volume 12 Issue 7,
July 2024
Pages 1564-1579
DOI: 10.1007/s40544-023-0835-6
Cite this article:
DUAN L, JIA D, LI J, et al. Nanostructured lubricant additives for titanium alloy: Lubrication by the solid–liquid interface with Coulomb repulsion. Friction, 2024, 12(7): 1564-1579. https://doi.org/10.1007/s40544-023-0835-6

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Received: 12 February 2023
Revised: 08 May 2023
Accepted: 27 September 2023
Published: 12 March 2024
© The author(s) 2023.

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