AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Magnesium silicate hydroxides (MSHs) with granular, schistose, and tubular morphologies were separately incorporated to enhance the tribological properties of phosphate/MoS2 composite coatings. The nano-schistose MSH demonstrated superior tribological performance due to its effective interactions with the worn surface and frictional synergies with solid lubricants. Incorporation of nano-schistose MSH decreased the friction coefficient of composite coatings by about 34.7% and increased the anti-wear performance of composite coatings by about thirteen times. Nano-schistose MSH facilitated the formation of a friction-induced multi-layer heterogenous slipping structure with layered solid lubricants at the friction interface. Moreover, tribo-chemical reactions between nano-schistose MSH and worn surface promoted the in-situ formation of a cermet supporting film, and this also induced the gradual in-situ formation of a lubrication film on the top of worn surface. Consequently, the contact state between tribo-pairs was timely regulated and the invalidation of the nanocomposite slipping structure was effectively restrained during the friction process. As a result, the service life of the phosphate composite coatings was significantly extended and further abrasion on the worn surface was notably reduced.
Yin Y L, Yu H L, Wang H M, Song Z Y, Zhang Z, Ji X C, Cui T H, Wei M, Zhang W. Friction and wear behaviors of steel/bronze tribopairs lubricated by oil with serpentine natural mineral additive. Wear 456–457: 203387 (2020)
Zhang B S, Xu Y, Gao F, Shi P J, Xu B S, Wu Y X. Sliding friction and wear behaviors of surface-coated natural serpentine mineral powders as lubricant additive. Appl Surf Sci 257(7): 2540–2549 (2011)
Yu H L, Xu Y, Shi P J, Wang H M, Zhang W, Xu B S. Effect of thermal activation on the tribological behaviours of serpentine ultrafine powders as an additive in liquid paraffin. Tribol Int 44(12): 1736–1741 (2011)
Gao K, Chang Q Y, Wang B, Zhou N N, Qing T. The tribological performances of modified magnesium silicate hydroxide as lubricant additive. Tribol Int 121: 64–70 (2018)
Jia Y L, Chen L, Feng X Z, Zhou H D, Chen J M. Tribological behavior of molybdenum disulfide bonded solid lubricating coatings cured with organosiloxane-modified phosphate binder. RSC Adv 5(85): 69606–69615 (2015)
Jia Y L, Wan H Q, Chen L, Zhou H D, Chen J M. Effects of phosphate binder on the lubricity and wear resistance of graphite coating at elevated temperatures. Surf Coat Technol 315: 490–497 (2017)
Gao X, Zhang J, Ju P F, Liu J Z, Ji L, Liu X H, Ma T B, Chen L, Li H X, Zhou H D, et al. Shear-induced interfacial structural conversion of graphene oxide to graphene at macroscale. Adv Funct Mater 30(46): 2004498 (2020)
Gigli L, Kawai S, Guerra R, Manini N, Pawlak R, Feng X L, Müllen K, Ruffieux P, Fasel R, Tosatti E, et al. Detachment dynamics of graphene nanoribbons on gold. ACS Nano 13(1): 689–697 (2019)
Agrawal K S, Barhate V N, Patil V S, Patil L S, Mahajan A M. Plasma-enhanced atomic layer-deposited La2O3 ultra-thin films on Si and 6H–SiC: A comparative study. Appl Phys A—Mater 126(8): 650 (2020)
Gan C L, Liang T, Li W, Fan X Q, Zhu M H. Amine-terminated ionic liquid modified graphene oxide/copper nanocomposite toward efficient lubrication. Appl Surf Sci 491: 105–115 (2019)
Lee H, Han G, Kim M, Ahn H S, Lee H. High mechanical and tribological stability of an elastic ultrathin overcoating layer for flexible silver nanowire films. Adv Mater 27(13): 2252–2259 (2015)
Zhang Z Y, Du Y F, Huang S L, Meng F N, Chen L L, Xie W X, Chang K K, Zhang C H, Lu Y, Lin C T, et al. Macroscale superlubricity enabled by graphene-coated surfaces. Adv Sci 7(4): 1903239 (2020)
Zhang Z Y, Wang B, Kang R K, Zhang B, Guo D M. Changes in surface layer of silicon wafers from diamond scratching. CIRP Annals—Manufacturing Technology 64(1): 349–352 (2015)
Zhang Z Y, Cui J F, Wang B, Wang Z G, Kang R K, Guo D M. A novel approach of mechanical chemical grinding. J Alloys Compd 726: 514–524 (2017)
Wang B, Gao K, Chang Q Y, Berman D, Tian Y. Magnesium silicate hydroxide–MoS2–Sb2O3 coating nanomaterials for high-temperature superlubricity. ACS Appl Nano Mater 4(7): 7097–7106 (2021)
Wang B, Chang Q Y, Gao K, Fang H R, Qing T, Zhou N N. The synthesis of magnesium silicate hydroxide with different morphologies and the comparison of their tribological properties. Tribol Int 119: 672–679 (2018)
Xi Z C, Sun J B, Chen L, Cui H X, Ma Y J, Zhou H D, Chen J M. Strengthening mechanism of nanosized magnesium silicate hydroxide on the tribological properties of phosphate-bonded solid coatings. ACS Appl Nano Mater 6(13): 11590–11600 (2023)
Qi X W, Lu L, Jia Z N, Yang Y L, Liu H R. Comparative tribological properties of magnesium hexasilicate and serpentine powder as lubricating oil additives under high temperature. Tribol Int 49: 53–57 (2012)
Chang Q Y, Wang B, Gao K. Pressure-dependent anti-wear mechanisms of synthetic magnesium silicate hydroxide nanoparticles. Tribol Int 135: 230–236 (2019)
Qi X W, Jia Z N, Yang Y L, Fan B L. Characterization and auto-restoration mechanism of nanoscale serpentine powder as lubricating oil additive under high temperature. Tribol Int 44(7–8): 805–810 (2011)
Qu J J, Qu H J, Wen Z P, Luo Y X. Self-repairing properties of complex titanium grease containing hydroxyl silicate. Tribol Int 149: 105685 (2020)
Li P P, Ju P F, Ji L, Li H X, Liu X H, Chen L, Zhou H D, Chen J M. Toward robust macroscale superlubricity on engineering steel substrate. Adv Mater 32(36): 2002039 (2020)
Liao M Z, Nicolini P, Du L J, Yuan J H, Wang S P, Yu H, Tang J, Cheng P, Watanabe K, Taniguchi T, et al. UItra-low friction and edge-pinning effect in large-lattice-mismatch van der Waals heterostructures. Nat Mater 21(1): 47–53 (2022)
Mandelli D, Leven I, Hod O, Urbakh M. Sliding friction of graphene/hexagonal–boron nitride heterojunctions: A route to robust superlubricity. Sci Rep 7: 10851 (2017)
Pei L L, Chen W Q, Ju P F, Zhou H, Xu Z, Ji L, Ma T B, Li H X, Liu X H, Zhou H D, et al. Regulating vacuum tribological behavior of a-C: H film by interfacial activity. J Phys Chem Lett 12(42): 10333–10338 (2021)
Won M S, Penkov O V, Kim D E. Durability and degradation mechanism of graphene coatings deposited on Cu substrates under dry contact sliding. Carbon 54: 472–481 (2013)
Zhang T, Zhao J G, Zhang J, Zhang S S, Li J W, Li S J, Li X Y, Zhang J. Nano-magnesium silicate hydroxide/crumpled graphene balls composites, a novel kind of lubricating additive with high performance for friction and wear reduction. Materials 13(17): 3669 (2020)
Gao K, Wang B, Shirani A, Chang Q Y, Berman D. Macroscale superlubricity accomplished by Sb2O3–MSH/C under high temperature. Front Chem 9: 667878 (2021)
Qin Y, Wu M X, Yang G, Yang Y, Zhao L M. Tribological performance of magnesium silicate hydroxide/Ni composite as an oil-based additive for steel–steel contact. Tribol Lett 69(1): 19 (2021)
Xu X, Li Q, Su F H, Sun J F, Li W F. In-situ formation of onion-like carbon film by tribo-induced catalytic degradation of hydrocarbon: Effect of lubrication condition and load. Chem Eng J 459: 141566 (2023)
Wang B, Chang Q Y, Gao K, Wen X L, Bai P P, Tian Y. Superlow wear realizable tribofilms from lubricant oil containing hydrothermally synthesized magnesium silicate hydroxide/carbon core–shell nanoplates. Langmuir 37(1): 240–248 (2021)
Zhang H, Chang Q Y. Enhanced ability of magnesium silicate hydroxide in transforming base oil into amorphous carbon by annealing heat treatment. Diam Relat Mater 117: 108476 (2021)
Dong R, Zhang Y L, Xu H Z, Bao L Y, Ma S H, Wang X G, Yu Q L, Cai M R, Zhou F, Liu W M. Friction induced mechanochemistry: Self-adaptive lubrication through in situ tribo-click system. Chem Eng J 454: 139772 (2023)
Wu J W, Wang X, Zhou L H, Wei X C, Wang W R. Formation factors of the surface layer generated from serpentine as lubricant additive and composite reinforcement. Tribol Lett 65(3): 93 (2017)
Jia Z N, Yang Y L, Chen J J, Yu X J. Influence of serpentine content on tribological behaviors of PTFE/serpentine composite under dry sliding condition. Wear 268(7–8): 996–1001 (2010)
Azhaarudeen S, Faruck A A M, Nevosad A. Tribological behaviour and wear mechanisms of manganese phosphate coatings under dry reciprocating sliding contact conditions. Tribol Int 122: 189–199 (2018)
Cihan E, İpek S, Durgun E, Baykara M Z. Structural lubricity under ambient conditions. Nat Commun 7: 12055 (2016)
Liu H Y, Xie M X, Pan B L, Li N, Zhang J H, Lu M, Luo J, Wang H G. In-situ intercalated pyrolytic graphene/serpentine hybrid as an efficient lubricant additive in paraffin oil. Colloids Surf A 652: 129929 (2022)
Chang Q Y, Zhang H, Gao R Q. Amorphous carbon doping nano-magnesium silicate hydroxide with significant tribological property. Tribol Lett 67(3): 76 (2019)
Chang Q Y, Zhang H, Gao R Q. Magnesium silicate hydroxide modified by carbon from hydrothermal carbonization of gelatin for tribological application. Diam Relat Mater 95: 36–43 (2019)
Yu H L, Xu Y, Shi P J, Wang H M, Zhao Y, Xu B S, Bai Z M. Tribological behaviors of surface-coated serpentine ultrafine powders as lubricant additive. Tribol Int 43(3): 667–675 (2010)
Ma Y J, Wan H Q, Ye Y P, Chen L, Li H X, Zhou H D, Chen J M. In-situ synthesis of size-tunable silver sulfide nanoparticles to improve tribological properties of the polytetrafluoroethylene-based nanocomposite lubricating coatings. Tribol Int 148: 106324 (2020)
Xi Z C, Sun J B, Chen L, Cui H X, Ma Y J, Zhou H D, Chen J M. Influence of natural serpentine on tribological performance of phosphate bonded solid coatings. Tribol Lett 70(2): 42 (2022)
Wang Y L, Zhang Z Z, Jiang W, Wang K, Liu M, He Y H, Liao C Y, Li P L, Yuan J Y, Yang M M. Mono-dispersed AuNPs decorated enlarged halloysite nanotubes to encapsulate [HMIm][NTf2] microcapsules for improving the wear resistance of composites. Compos Part A—Appl S 175: 107752 (2023)
Zhang Z Y, Wang X, Meng F N, Liu D D, Huang S L, Cui J F, Wang J M, Wen W. Origin and evolution of a crack in silicon induced by a single grain grinding. J Manuf Process 75: 617–626 (2022)
Wang B, Zhang Z Y, Chang K K, Cui J F, Rosenkranz A, Yu J H, Lin C T, Chen G X, Zang K T, Luo J, et al. New deformation-induced nanostructure in silicon. Nano Lett 18(7): 4611–4617 (2018)
This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.
The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.
To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
