Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
Electrical contact materials are increasingly widely used, but the existing electric contact lubricants still have lots of room for improvement, such as anti-wear performance and lubrication life. Due to the excellent electrical and lubrication properties, graphene shows great potential in lubricating the sliding electrical contact interface, but there is a lack of relevant research. Some researchers have studied the lubrication performance of graphene between the gold-coated/TiN-coated friction pair at an ultra-low current. However, the lubrication performance of graphene on more widely used electrical contact materials such as copper and its alloys under larger and more commonly used current or voltage conditions has not been reported. In this paper, we study the lubrication performance of graphene in the copper and its alloys sliding electrical contact interface under usual parameters, which is explored through four aspects: different substrates—copper and brass, different test methods—constant voltage and constant current, different normal loads and durability test. The experiments demonstrate that graphene can significantly reduce the friction and wear on brass and copper under the above test methods and parameters, with low contact resistance at the same time. Our work is expected to provide a new lubricant for electrical contact materials and contribute to enriching the tribological theory of graphene.
Gong H J, Yu C C, Zhang L, Xie G X, Guo D, Luo J B. Intelligent lubricating materials: A review. Compos Part B Eng 202: 108450 (2020)
He F, Xie G X, Luo J B. Electrical bearing failures in electric vehicles. Friction 8(1): 4–28 (2020)
Zhang P, Zhang L, Wei D B, Wu P F, Cao J W, Shijia C R, Qu X H, Fu K X. Effect of graphite type on the contact plateaus and friction properties of copper-based friction material for high-speed railway train. Wear 432–433: 202927 (2019)
Zhu J H, Ghezel-Ayagh H. Cathode-side electrical contact and contact materials for solid oxide fuel cell stacking: A review. Int J Hydrog Energy 42(38): 24278–24300 (2017)
Farfan-Cabrera L I. Tribology of electric vehicles: A review of critical components, current state and future improvement trends. Tribol Int 138: 473–486 (2019)
Lin X Y, Liu R T, Chen J, Xiong X, Liao N. Study on current-carrying friction and wear properties of copper-graphite brush material reinforced by organosilicon. J Mater Res Technol 12: 365–375 (2021)
Zhai W Z, Bai L C, Zhou R H, Fan X L, Kang G Z, Liu Y, Zhou K. Recent progress on wear-resistant materials: Designs, properties, and applications. Adv Sci 8(11): 2003739 (2021)
Bouchoucha A, Chekroud S, Paulmier D. Influence of the electrical sliding speed on friction and wear processes in an electrical contact copper–stainless steel. Appl Surf Sci 223(4): 330–342 (2004)
Zhao H, Feng Y, Zhou Z J, Qian G, Zhang J C, Huang X C, Zhang X B. Effect of electrical current density, apparent contact pressure, and sliding velocity on the electrical sliding wear behavior of Cu–Ti3AlC2 composites. Wear 444–445: 203156 (2020)
Zuo R F, Chen J Y, Han Z H, Dong Y, Jow J. Electroless silver plating on modified fly ash particle surface. Appl Surf Sci 513: 145857 (2020)
Liu J D, Chen H T, Ji H J, Li M Y. Highly conductive Cu–Cu joint formation by low-temperature sintering of formic acid-treated Cu nanoparticles. ACS Appl Mater Interfaces 8(48): 33289–33298 (2016)
Yi F, Zhang M, Xu Y. Effect of the electric current on the friction and wear properties of the CNT–Ag–G composites. Carbon 43(13): 2685–2692 (2005)
Li H Y, Wang X H, Guo X H, Yang X H, Liang S H. Material transfer behavior of AgTiB2 and AgSnO2 electrical contact materials under different currents. Mater Des 114: 139–148 (2017)
Qiu M, Zhang Y Z, Yang J H, Zhu J. Microstructure and tribological characteristics of Ti–6Al–4V alloy against GCr15 under high speed and dry sliding. Mater Sci Eng A 434(1–2): 71–75 (2006)
Zeng Y M, He F, Wang Q, Yan X H, Xie G X. Friction and wear behaviors of molybdenum disulfide nanosheets under normal electric field. Appl Surf Sci 455: 527–532 (2018)
Huang Y H, Yao Q Z, Lu Z X, Jiao L Y, Zhang S, Li Q Y, Meng Y G. Antiwear performance of monolayer MoS2 modulated by residual straining. ACS Appl Nano Mater 1(12): 7092–7097 (2018)
Bares J A, Argibay N, Dickrell P L, Bourne G R, Burris D L, Ziegert J C, Sawyer W G. In situ graphite lubrication of metallic sliding electrical contacts. Wear 267(9–10): 1462–1469 (2009)
Kalin M, Poljanec D. Influence of the contact parameters and several graphite materials on the tribological behaviour of graphite/copper two-disc electrical contacts. Tribol Int 126: 192–205 (2018)
Poljanec D, Kalin M. Effect of polarity and various contact pairing combinations of electrographite, polymer-bonded graphite and copper on the performance of sliding electrical contacts. Wear 426–427: 1163–1175 (2019)
Sun K, Diao D F. Current density effect on current-carrying friction of amorphous carbon film. Carbon 157: 113–119 (2020)
Sun K, Fan X, Zhang W Q, Xue P D, Diao D F. Contact-focusing electron flow induced nanosized graphene sheet formation in amorphous carbon films for fast low-friction. Carbon 149: 45–54 (2019)
Hyun W J, Park O O, Chin B D. Foldable graphene electronic circuits based on paper substrates. Adv Mater 25: 4729–4734 (2013)
Huang Y H, Yao Q Z, Qi Y Z, Cheng Y, Wang H T, Li Q Y, Meng Y G. Wear evolution of monolayer graphene at the macroscale. Carbon 115: 600–607 (2017)
Huang Y H, Li Q Y, Zhang J, Wang H T, Zhao P, Meng Y G. Electric resistance as a sensitive measure for detecting graphene wear during macroscale tribological tests. Sci China Technol Sci 64(1): 179–186 (2021)
Mao F, Wiklund U, Andersson A M, Jansson U. Graphene as a lubricant on Ag for electrical contact applications. J Mater Sci 50(19): 6518–6525 (2015)
Berman D, Erdemir A, Sumant A V. Graphene as a protective coating and superior lubricant for electrical contacts. Appl Phys Lett 105(23): 231907 (2014)
Zuo X, Du M D, Zhou Y K. Influence of contact parameters on the coupling temperature of copper-brass electrical contacts. Eng Fail Anal 136: 106205 (2022)
Chen J, Yao B W, Li C, Shi G Q. An improved Hummers method for eco-friendly synthesis of graphene oxide. Carbon 64: 225–229 (2013)
Sadykov F A, Barykin N P, Aslanyan I R. Wear of copper and its alloys with submicrocrystalline structure. Wear 225–229: 649–655 (1999)
Shen L N, Li Z, Zhang Z M, Dong Q Y, Xiao Z, Lei Q, Qiu W T. Effects of silicon and thermo-mechanical process on microstructure and properties of Cu–10Ni–3Al–0.8Si alloy. Mater Des 1980 2015 62: 265–270 (2014)
Leffers T, Ray R K. The brass-type texture and its deviation from the copper-type texture. Prog Mater Sci 54(3): 351–396 (2009)
Berman D, Erdemir A, Sumant A V. Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54: 454–459 (2013)
Jeong D H, Erb U, Aust K T, Palumbo G. The relationship between hardness and abrasive wear resistance of electrodeposited nanocrystalline Ni–P coatings. Scr Mater 48(8): 1067–1072 (2003)
Gore G J, Gates J D. Effect of hardness on three very different forms of wear. Wear 203–204: 544–563 (1997)
Mo Y F, Szlufarska I. Roughness picture of friction in dry nanoscale contacts. Phys Rev B 81(3): 035405 (2010)
Qu Y T, Campbell P G, Gu L, Knipe J M, Dzenitis E, Santiago J G, Stadermann M. Energy consumption analysis of constant voltage and constant current operations in capacitive deionization. Desalination 400: 18–24 (2016)
Li Y J, Li K N, Xie Y, Liu J Y, Fu C Y, Liu B. Optimized charging of lithium-ion battery for electric vehicles: Adaptive multistage constant current–constant voltage charging strategy. Renew Energy 146: 2688–2699 (2020)
Cao Z F, Xia Y Q, Chen C, Zheng K, Zhang Y. A synergetic strategy based on laser surface texturing and lubricating grease for improving the tribological and electrical properties of Ag coating under current-carrying friction. Friction 9(5): 978–989 (2021)
Zhang S, Fu Y Q, Du H J, Zeng X T, Liu Y C. Magnetron sputtering of nanocomposite (Ti, Cr)CN/DLC coatings. Surf Coat Technol 162(1): 42–48 (2003)
Zhao F, Li H X, Ji L, Wang Y J, Zhou H D, Chen J M. Ti-DLC films with superior friction performance. Diam Relat Mater 19(4): 342–349 (2010)
Scharf T W, Ohlhausen J A, Tallant D R, Prasad S V. Mechanisms of friction in diamondlike nanocomposite coatings. J Appl Phys 101(6): 063521 (2007)
This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.
The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.
To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.