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Letter | Open Access

Interface and energy band manipulation of Bi₂O₃-Bi₂S₃ electrode enabling advanced magnesium-ion storage

Qiang Tang^{^a}, Yingze Song^{^a}(), Xuan Cao^{^a}, Cheng Yang^{^b}, Dong Wang^{^c}, Tingting Qin^{^b}(), Wei Zhang^{^d}()

a

State Key Laboratory of Environment-Friendly Energy Materials, Tianfu Institute of Research and Innovation, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, PR China

b

Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China

c

State Key Laboratory of Chem/Bio-Sensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, PR China

d

Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, PR China

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Abstract

Rechargeable magnesium-ion (Mg-ion) batteries have attracted wide attention for energy storage. However, magnesium anode is still limited by the irreversible Mg plating/stripping procedure. Herein, a well-designed binary Bi₂O₃-Bi₂S₃ (BO-BS) heterostructure is fulfilled by virtue of the cooperative interface and energy band engineering targeted fast Mg-ion storage. The built-in electronic field resulting from the asymmetrical electron distribution at the interface of electron-rich S center at Bi₂S₃ side and electron-poor O center at Bi₂O₃ side effectively accelerates the electrochemical reaction kinetics in the Mg-ion battery system. Moreover, the as-designed heterogenous interface also benefits to maintaining the electrode integrity. With these advantages, the BO-BS electrode displays a remarkable capacity of 150.36 mAh g⁻¹ at 0.67 A g^–1 and a superior cycling stability. This investigation would offer novel insights into the rational design of functional heterogenous electrode materials targeted the fast reaction kinetics for energy storage systems.

Keywords

Magnesium-ion battery Bi₂O₃-Bi₂S₃ heterostructure Interface and energy band engineering Electrochemical reaction kinetics Electrode integrity

References

[1]

L. Chen, J.L. Bao, X. Dong, D.G. Truhlar, Y. Wang, C. Wang, Y. Xia, ACS Energy Lett. 2 (5) (2017) 1115–1121, doi:10.1021/acsenergylett.7b00040.

[2]

Z. Pan, T. Qin, W. Zhang, X. Chu, T. Dong, N. Yue, Z. Wang, W. Zheng, J. Energy Chem. 68 (2022) 42–48, doi:10.1016/j.jechem.2021.11.031.

[3]

W. Zuo, W. Zhu, D. Zhao, Y. Sun, Y. Li, J. Liu, X.W. Lou, Energy Environ. Sci. 9 (9) (2016) 2881–2891, doi:10.1039/c6ee01871h.

[4]

N. Prasad, B. Karthikeyan, Appl. Phys. A Mater. 124 (6) (2018) 421, doi:10.1007/s00339-018-1802-3.

[5]

Y. Zhu, J. Yin, A.H. Emwas, O.F. Mohammed, H.N. Alshareef, Adv. Funct. Mater. 31 (50) (2021) 2107523, doi:10.1002/adfm.202107523.

[6]

C. Li, S. Dong, R. Tang, X. Ge, Z. Zhang, C. Wang, Y. Lu, L. Yin, Energy Environ. Sci. 11 (11) (2018) 3201–3211, doi:10.1039/c8ee01046c.

[7]

C. Yan, Y. Zhu, Y. Li, Z. Fang, L. Peng, X. Zhou, G. Chen, G. Yu, Adv. Funct. Mater. 28 (7) (2018) 1705951, doi:10.1002/adfm.201705951.

[8]

Y. Zheng, T. Zhou, C. Zhang, J. Mao, H. Liu, Z. Guo, Angew. Chem. Int. Ed. 55 (10) (2016) 3408–3413, doi:10.1002/anie.201510978.

[9]

T. Qin, D. Wang, X. Zhang, Y. Wang, N.E. Drewett, W. Zhang, T. Dong, T. Li, Z. Wang, T. Deng, Z. Pan, N. Yue, R. Yang, K. Huang, S. Feng, R. Huang, W. Zheng, Energy Storage Mater. 36 (2021) 376–386, doi:10.1016/j.ensm.2021.01.013.

[10]

H. Shan, J. Qin, Y. Ding, H.M.K. Sari, X. Song, W. Liu, Y. Hao, J. Wang, C. Xie, J. Zhang, X. Li, Adv. Mater. 33 (37) (2021) 2102471, doi:10.1002/adma.202102471.

[11]

K. Biswas, L.-.D. Zhao, M.G. Kanatzidis, Adv. Energy Mater. 2 (6) (2012) 634–638, doi:10.1002/aenm.201100775.

[12]

Z.H. Ge, B.P. Zhang, P.P. Shang, J.F. Li, J. Mater. Chem. 21 (25) (2011) 9194–9200, doi:10.1039/c1jm11069a.

[13]

G. Kresse, J. Hafner, Phys. Rev. B 47 (1) (1993) 558–561, doi:10.1103/PhysRevB.47.558.

[14]

J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77 (18) (1996) 3865–3868, doi:10.1103/PhysRevLett.77.3865.

[15]

J.P. Perdew, A. Ruzsinszky, G.I. Csonka, O.A. Vydrov, G.E. Scuseria, L.A. Constantin, X.L. Zhou, K. Burke, Phys. Rev. Lett. 100 (13) (2008) 136406, doi:10.1103/PhysRevLett.100.136406.

[16]

P.E. Blöchl, Phys. Rev. B 50 (24) (1994) 17953–17979, doi:10.1103/PhysRevB.50.17953.

[17]

B. Hammer, L.B. Hansen, J.K. Nørskov, Phys. Rev. B 59 (1999) 7413, doi:10.1103/PhysRevB.59.7413.

[18]

R. Asahi, W. Mannstadt, A.J. Freeman, Phys. Rev. B 59 (11) (1999) 7486–7492, doi:10.1103/PhysRevB.59.7486.

[19]

J. Iniguez, D. Vanderbilt, L. Bellaiche, Phys. Rev. B 67 (2003) 224107, doi:10.1103/PhysRevB.67.224107.

[20]

G.H. Zhong, J.L. Wang, Z. Zeng, J. Phys. Conf. Ser. 29 (2006) 106–109, doi:10.1088/1742-6596/29/1/020.

[21]

T. Qin, X. Zhang, D. Wang, T. Deng, H. Wang, X. Liu, X. Shi, Z. Li, H. Chen, X. Meng, W. Zhang, W. Zheng, ACS Appl. Mater. Interfaces 11 (2) (2019) 2103–2111, doi:10.1021/acsami.8b19575.

[22]

X. Wang, W. Li, D. Xiong, D.Y. Petrovykh, L. Liu, Adv. Funct. Mater. 26 (23) (2016) 4067–4077, doi:10.1002/adfm.201505509.

[23]

D. Wu, G. Huo, W. Chen, X.Z. Fu, J.L. Luo, Appl. Catal. B Environ. 271 (2020) 118957, doi:10.1016/j.apcatb.2020.118957.

[24]

J. Yi, K. Liao, C. Zhang, T. Zhang, F. Li, H. Zhou, ACS Appl. Mater. Interfaces 7 (20) (2015) 10823–10827, doi:10.1021/acsami.5b01727.

[25]

J. Mei, T. Liao, G.A. Ayoko, Z. Sun, ACS Appl. Mater. Interfaces 11 (31) (2019) 28205–28212, doi:10.1021/acsami.9b09882.

[26]

H. Ticha, M. Kincl, L. Tichy, Mater. Chem. Phys. 138 (2–3) (2013) 633–639, doi:10.1016/j.matchemphys.2012.12.032.

[27]

F. Chang, B. Lei, C. Yang, J. Wang, X. Hu, Chem. Eng. J. 413 (2021) 127443, doi:10.1016/j.cej.2020.127443.

[28]

P. Veerakumar, G. Jaysiva, S.M. Chen, K.C. Lin, ACS Appl. Mater. Interfaces 14 (4) (2022) 5908–5920, doi:10.1021/acsami.1c16723.

[29]

Z. Wu, T. Liao, S. Wang, J.A. Mudiyanselage, A.S. Micallef, W. Li, A.P. O'Mullane, J. Yang, W. Luo, K. Ostrikov, Y. Gu, Z. Sun, Nano Micro Lett. 4 (1) (2022) 90 1, doi:10.1007/s40820-022-00832-6.

[30]

R. Liu, L. Ma, G. Niu, X. Li, E. Li, Y. Bai, G. Yuan, Adv. Funct. Mater. 27 (29) (2017) 1701635, doi:10.1002/adfm.201701635.

[31]

H. Zheng, Y. Zeng, H. Zhang, X. Zhao, M. Chen, J. Liu, X. Lu, J. Power Sources. 433 (2019) 228730, doi:10.1016/j.jpowsour.2019.05.090.

[32]

M. Xu, Y. Niu, X. Teng, S. Gong, L. Ji, Z. Chen, J. Energy Chem. 65 (2022) 605–615, doi:10.1016/j.jechem.2021.06.028.

[33]

J. Li, Z. Li, X. Liu, C. Li, Y. Zheng, K.W.K. Yeung, Z. Cui, Y. Liang, S. Zhu, W. Hu, Y. Qi, T. Zhang, X. Wang, S. Wu, Nat. Commun. 12 (1) (2021) 1224, doi:10.1038/s41467-021-21435-6.

[34]

L. Cao, X. Liang, X. Ou, X. Yang, Y. Li, C. Yang, Z. Lin, M. Liu, Adv. Funct. Mater. 30 (16) (2020) 1910732, doi:10.1002/adfm.201910732.

[35]

Y. Sang, X. Cao, G. Dai, L. Wang, Y. Peng, B. Geng, J. Hazard. Mater. 381 (2020) 120942, doi:10.1016/j.jhazmat.2019.120942.

[36]

W. Luo, F. Li, Q. Li, X. Wang, W. Yang, L. Zhou, L. Mai, ACS Appl. Mater. Interfaces 10 (8) (2018) 7201–7207, doi:10.1021/acsami.8b01613.

[37]

P.F. Sui, C. Xu, M.N. Zhu, S. Liu, Q. Liu, J.L. Luo, Small 18 (1) (2022) 2105682, doi:10.1002/smll.202105682.

[38]

X. Yang, P. Deng, D. Liu, S. Zhao, D. Li, H. Wu, Y. Ma, B.Y. Xia, M. Li, C. Xiao, S. Ding, J. Mater. Chem A 8 (5) (2020) 2472–2480, doi:10.1039/c9ta11363k.

[39]

S. Liu, X.F. Lu, J. Xiao, X. Wang, X.W.D. Lou, Angew. Chem. Int. Ed. 58 (39) (2019) 13828–13833, doi:10.1002/anie.201907674.

[40]

W. Wang, Y. Xiao, X. Li, Q. Cheng, G. Wang, Chem. Eng. J. 371 (2019) 327–336, doi:10.1016/j.cej.2019.04.048.

[41]

Y.L. Liu, M.Q. Li, G.G. Wang, L.Y. Dang, F. Li, M.E. Pam, H.Y. Zhang, J.C. Han, H.Y. Yang, Energy Environ. Mater. 4 (3) (2020) 465–473, doi:10.1002/eem2.12130.

[42]

X. Cheng, R. Shao, D. Li, H. Yang, Y. Wu, B. Wang, C. Sun, Y. Jiang, Q. Zhang, Y. Yu, Adv. Funct. Mater. 31 (22) (2021) 2011264, doi:10.1002/adfm.202011264.

[43]

Q. Li, S. Jing, Z. Yong, Q. Zhang, C. Liu, K. Zhu, Y. Feng, W. Gong, Y. Yao, Energy Storage Mater. 42 (2021) 815–825, doi:10.1016/j.ensm.2021.08.032.

[44]

T. Qin, W. Zhang, Y. Ma, W. Zhang, T. Dong, X. Chu, T. Li, Z. Wang, N. Yue, H. Liu, L. Zheng, X. Fan, X. Lang, Q. Jiang, W. Zheng, Energy Storage Mater. 45 (2022) 33–39, doi:10.1016/j.ensm.2021.11.032.

[45]

T. Dong, W. Yi, T. Deng, T. Qin, X. Chu, H. Yang, L. Zheng, S.J. Yoo, J.G. Kim, Z. Wang, Y. Wang, W. Zhang, W. Zheng, Energy Environ. Mater. (2022).

[46]

G. Zan, T. Wu, P. Hu, Y. Zhou, S. Zhao, S. Xu, J. Chen, Y. Cui, Q. Wu, Energy Storage Mater 28 (2020) 82–90, doi:10.1016/j.ensm.2020.02.027.

[47]

T. Tang, Z. Yin, J. Chen, S. Zhang, W. Sheng, W. Wei, Y. Xiao, Q. Shi, S. Cao, Chem. Eng. J. 417 (2021) 128058, doi:10.1016/j.cej.2020.128058.

[48]

H. Zheng, H. Li, M. Yu, M. Zhang, Y. Tong, F. Cheng, X. Lu, J. Mater. Chem. A 5 (48) (2017) 25539–25544, doi:10.1039/c7ta08451j.

[49]

H. Cheng, J. Wang, Y. Yang, H. Shi, J. Shi, X. Jiao, P. Han, X. Yao, W. Chen, X. Wei, P.K. Chu, X. Zhang, Small 18 (26) (2022) 2200857, doi:10.1002/smll.202200857.

[50]

C. Li, Y. Liu, Z. Zhuo, H. Ju, D. Li, Y. Guo, X. Wu, H. Li, T. Zhai, Adv. Funct. Mater. 8 (27) (2018) 1801775, doi:10.1002/aenm.201801775.

[51]

Y. Zhang, Z. Jin, D. Liu, Z. Tan, B.B. Mamba, A.T. Kuvarega, J. Gui, ACS Appl. Mater. Interfaces 5 (4) (2022) 5448–5458, doi:10.1021/acsanm.2c00446.

Journal of Magnesium and Alloys

Volume 12 Issue 9,
September 2024

Pages 3543-3552

DOI: 10.1016/j.jma.2023.01.007

Cite this article:

Tang Q, Song Y, Cao X, et al. Interface and energy band manipulation of Bi₂O₃-Bi₂S₃ electrode enabling advanced magnesium-ion storage. Journal of Magnesium and Alloys, 2024, 12(9): 3543-3552. https://doi.org/10.1016/j.jma.2023.01.007

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