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Research Article | Open Access

(Bi0.51 Na0.47)TiO3 based lead free ceramics with high energy density and efficiency

Yu Huanga, Fei Lib, Hua Haoa( ), Fangquan Xiac, Hanxing Liud, Shujun Zhange( )
State Key Lab Silicate Materials for Architecture, Center for Smart Materials and Device Integration, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China
Electronic Materials Research Laboratory, Key Lab Ministry of Education and International Center for Dielectric Research, School of Electronic and Information Engineering, Xi'an Jiaotong University, Xi'an, 710049, China
School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Center for Smart Materials and Device Integration, International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China
Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong, NSW, 2500, Australia

Peer review under responsibility of The Chinese Ceramic Society.

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Graphical Abstract

Abstract

Dielectric ceramics with high energy storage density and energy efficiency play an important role in high power energy storage applications. In this work, lead free relaxor ferroelectric ceramics in (1-x)Bi0.51Na0.47TiO3- xBa(Zr0.3Ti0.7)O3 (BNT-BZT100x: x = 0.20, 0.30, 0.40 and 0.50) system are fabricated by conventional solid-state sintering method. The BNT-BZT100x ceramics are sintered dense with minimal pores, exhibiting pseudocubic symmetry and strong relaxor characteristic. A high energy storage density of 3.1 J/cm3 and high energy efficiency of 91% are simultaneously achieved in BNT-BZT40 ceramic with 0.1 mm in thickness, at the applied electric field of 280 kV/cm. The temperature stability of the energy density is studied over temperature range of 20–160 ℃, showing minimal variation below 1.5%, together with the excellent cycling reliability (the variations of both energy density and efficiency are below 3% up to 106 cycles), making BNT-BZT40 ceramic promising candidate for high-temperature dielectric and energy storage applications.

Keywords

Energy storageLead free ceramicRelaxor characteristic

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Journal of Materiomics
Volume 5 Issue 3,
September 2019
Pages 385-393
DOI: 10.1016/j.jmat.2019.03.006
Cite this article:
Huang Y, Li F, Hao H, et al. (Bi0.51 Na0.47)TiO3 based lead free ceramics with high energy density and efficiency. Journal of Materiomics, 2019, 5(3): 385-393. https://doi.org/10.1016/j.jmat.2019.03.006

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Received: 17 February 2019
Revised: 20 March 2019
Accepted: 30 March 2019
Published: 09 April 2019
© 2019 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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