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Research Article | Open Access

Glass modified barium strontium titanate ceramics for energy storage capacitor at elevated temperatures

Zong-Yang Shena( ), Yu Wanga, Yanxue Tangb, Yuanying Yua, Wen-Qin Luoa, Xingcai Wangc, Yueming Lia, Zhumei Wanga, Fusheng Songa
Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, 333403, China
Key Laboratory of Optoelectronic Material and Device, Shanghai Normal University, Shanghai, 200234, China
Chengdu Hongming UESTC Electronic New Materials Co., Ltd., Chengdu, 610100, China

Peer review under responsibility of The Chinese Ceramic Society.

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Graphical Abstract

Abstract

A glass with composition of B2O3-Bi2O3-SiO2-CaO-BaO-Al2O3-ZrO2 (BBSZ) modified BaxSr1-xTiO3 (BST, x = 0.3 and 0.4) ceramics were prepared by a conventional solid state reaction method abided by a formula of BST + y%BBSZ (y = 0, 2, 4, 7, and 10, in mass). The effect of BBSZ glass content on the structure, dielectric properties and energy storage characteristics of the ceramics was investigated. The dielectric constant reduced but the endurable electrical strength enhanced due to the BBSZ glass addition in BST ceramics. In particular, the dielectric loss of the ceramics at elevated temperature (e.g. 200 ℃) can be strongly suppressed from tanδ>20% to tanδ<3% after BBSZ glass modification. For Ba0.3Sr0.7TiO3+2% BBSZ ceramics, an optimized energy storage density (γ = 0.63 J/cm3) and efficiency (η = 91.6%) under an applied electric field of 160 kV/cm was obtained at room temperature. Meanwhile, the temperature dependent polarization-electric field (P-E) hysteresis loops were measured to evaluate the energy storage characteristics of the ceramics potential for high voltage capacitor application at elevated temperatures.

Keywords

Energy storageCeramic capacitorBarium strontium titanateGlass modification

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Journal of Materiomics
Volume 5 Issue 4,
December 2019
Pages 641-648
DOI: 10.1016/j.jmat.2019.06.003
Cite this article:
Shen Z-Y, Wang Y, Tang Y, et al. Glass modified barium strontium titanate ceramics for energy storage capacitor at elevated temperatures. Journal of Materiomics, 2019, 5(4): 641-648. https://doi.org/10.1016/j.jmat.2019.06.003

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Received: 07 February 2019
Revised: 23 May 2019
Accepted: 15 June 2019
Published: 16 June 2019
©2019 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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