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Opinion Paper | Open Access

Influence of Re-ions with different ionic radius in Ba12ReNb9O36 on crystal structure and microwave dielectric properties

Pengcheng Zhanga, Hao Lia( ), Xiaoqing Chena, Xing Zhangb,c, Hongcheng Yangb,c, Canbing Lia, Shuren Zhangb,c
College of Electrical and Information Engineering, Hunan University, Changsha, 410082, China
State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054, China
National Engineering Research Center of Electromagnetic Radiation Control Materials, University of Electronic Science and Technology of China, Chengdu, 610054, China
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Graphical Abstract

Abstract

The Ba12ReNb9O36 (ReYb, Ce, Tm, Er, Y, Ho, Dy, Gd) ceramics are synthesized by solid-phase reaction method. The phase composition, crystal structure, microstructure, and microwave dielectric properties of the ceramics are investigated by X-ray diffraction, X-ray photoelectron spectroscopy, Scanning electron microscopy and Raman spectrum. The optimal microwave dielectric properties (εr = 37.23, Q × f = 36600 GHz, and τf = 34 ppm/℃) are obtained for Ba12YbNb9O36 ceramic sintered at 1420 ℃ for 6 h. In this system, the variation of dielectric constant is dominated by polarizability. The Q × f is mainly affected by internal strain/fluctuation of d-spacing. The variation of τf is related to the temperature coefficient of dielectric constant and the oxygen octahedron distortion. Furthermore, the reduction of Ce4+ ions, the relative density, linear thermal expansion coefficient, and the second phase are also important factors affecting microwave dielectric properties.

Keywords

Raman spectrumPolarizabilityMicrowave dielectric ceramicBa12ReNb9O36

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Journal of Materiomics
Volume 8 Issue 1,
January 2022
Pages 104-112
DOI: 10.1016/j.jmat.2021.05.001
Cite this article:
Zhang P, Li H, Chen X, et al. Influence of Re-ions with different ionic radius in Ba12ReNb9O36 on crystal structure and microwave dielectric properties. Journal of Materiomics, 2022, 8(1): 104-112. https://doi.org/10.1016/j.jmat.2021.05.001

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Received: 13 September 2020
Revised: 16 April 2021
Accepted: 04 May 2021
Published: 24 May 2021
© 2021 The Chinese Ceramic Society.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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