Graphical Abstract
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Oxide-ion conductors have been widely used as catalytic, conductive, detecting and other materials under oxidizing, reducing, inert, mixed environments and the like. However, so far the evaluation of their oxygen-ion transport (such as oxide-ion conductivity and oxygen permeability) either is extrinsic or is limited only in oxidizing or inert environment. Herein, the evaluation of intrinsic oxygen-ion transport for oxide-ion conductors in all environments seems especially important. In this work, a new test system was designed to enable the oxide-ion conductors placing in single oxidizing, reducing, inert or mixed environment separately, which also realized all the oxygen-vacancy concentrations of oxide-ion conductors are in equilibrium in all environments. The intrinsic oxide-ion conductivity and oxygen permeability were evaluated in all environments, and the influencing factors regulated by environments also were analyzed to correlate the variation of oxygen-ion transport.
Takht Ravanchi M, Kaghazchi T, Kargari A. Application of membrane separation processes in petrochemical industry: a review. Desalination 2009;235:199–244.
Moos R. A brief overview on automotive exhaust gas sensors based on electroceramics. Int J Appl Ceram Technol 2005;2:401–13.
Jacobson AJ. Materials for solid oxide fuel cells. Chem Mater 2010;22:660–74.
Chen Y, deGlee B, Tang Y, Wang Z, Zhao B, Wei Y, et al. A robust fuel cell operated on nearly dry methane at 500 degrees c enabled by synergistic thermal catalysis and electrocatalysis. Nat Energy 2018;3:1042–50.
Sydyknazar S, Cascos V, Fernández-Díaz MT, Alonso JA. Design, synthesis and performance of ba-doped derivatives of SrMo0.9Fe0.1O3-δ perovskite as anode materials in sofcs. J Materiomics 2019;5:280–5.
Goodenough JB, Manthiram A, Paranthaman M, Zhen YS. Oxide ion electrolytes. Mater Sci Eng B 1992;12:357–64.
Goodenough JB. Oxide-ion conductors by design. Nature 2000;404:821–3.
Martinez-Coronado R, Singh P, Alonso-Alonso J, Goodenough JB. Structural investigation of the oxide-ion electrolyte with SrMO3 (M = Si/Ge) structure. J Mater Chem 2014;2:4355–60.
Rahman SMH, Ahmed I, Haugsrud R, Eriksson SG, Knee CS. Characterisation of structure and conductivity of BaTi0.5Sc0.5O3-delta. Solid State Ionics 2014;255:140–6.
Zweier JL, Thompson-Gorman S, Kuppusamy P. Measurement of oxygen concentrations in the intact beating heart using electron paramagnetic resonance spectroscopy: a technique for measuring oxygen concentrationsin situ. J Bioenerg Biomembr 1991;23:855–71.
Huan Y, Chen S, Zeng R, Wei T, Dong D, Hu X, et al. Intrinsic effects of ruddlesden-popper-based bifunctional catalysts for high-temperature oxygen reduction and evolution. Adv Energy Mater 2019;9:1901573.
Yoshida H, Inagaki T, Miura K, Inaba M, Ogumi Z. Density functional theory calculation on the effect of local structure of doped ceria on ionic conductivity. Solid State Ionics 2003;160:109–16.
Badwal SPS, Ciacchi FT. Ceramic membrane technologies for oxygen separation. Adv Mater 2001;13:993–6.
Sunarso J, Baumann S, Serra JM, Meulenberg WA, Liu S, Lin YS, et al. Mixed ionic–electronic conducting (MIEC) ceramic-based membranes for oxygen separation. J Membr Sci 2008;320:13–41.
Wang Y, Jia C, Lyu Z, Han M, Wu J, Sun Z, et al. Performance and stability analysis of SOFC containing thin and dense gadolinium-doped ceria interlayer sintered at low temperature. J Materiomics 2022;8:347–57.
Shao Z, Haile SM. A high-performance cathode for the next generation of solid-oxide fuel cells. Nature 2004;431:170–3.
Arena F, Barbera K, Italiano G, Bonura G, Spadaro L, Frusteri F. Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol. J Catal 2007;249:185–94.
Pool JA, Lobkovsky E, Chirik PJ. Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex. Nature 2004;427:527–30.
Huang YH, Dass RI, Xing ZL, Goodenough JB. Double perovskites as anode materials for solid-oxide fuel cells. Science 2006;312:254–7.
Zhou M, Ahmad A. Synthesis, processing and characterization of calcia-stabilized zirconia solid electrolytes for oxygen sensing applications. Mater Res Bull 2006;41:690–6.
Mugita M, Miyashita Y, Kuriyama S, Taguchi K, Sasaki N, Nakano Y. Development of probes for electrochemical measurement of free oxygen content in liquid steel and its application. Solid State Ionics 1981;3–4:589–93.
Kim I-D, Rothschild A, Lee BH, Kim DY, Jo SM, Tuller HL. Ultrasensitive chemiresistors based on electrospun TiO2 nanofibers. Nano Lett 2006;6:2009–13.
Zhang Y, Zeng W, Ye H, Li Y. Enhanced carbon monoxide sensing properties of TiO2 with exposed (001) facet: a combined first-principle and experimental study. Appl Surf Sci 2018;442:507–16.
Wan Q, Li QH, Chen YJ, Wang TH, He XL, Li JP, et al. Fabrication and ethanol sensing characteristics of ZnO nanowire gas sensors. Appl Phys Lett 2004;84:3654–6.
Bae G, Jeon IS, Jang M, Song W, Myung S, Lim J, et al. Complementary dual-channel gas sensor devices based on a role-allocated ZnO/graphene hybrid heterostructure. ACS Appl Mater Interfaces 2019;11:16830–7.
Trovarelli A, de Leitenburg C, Boaro M, Dolcetti G. The utilization of ceria in industrial catalysis. Catal Today 1999;50:353–67.
Wang H, Cao FX, Song YH, Yang GQ, Ge HQ, Liu ZT, et al. Two-step hydrothermally synthesized Ce1-xZrxO2 for oxidative dehydrogenation of ethylbenzene with carbon dioxide. J CO2 Util 2019;34:99–107.
Chen G. Electrochemical technologies in wastewater treatment. Sep Purif Technol 2004;38:11–41.
Liu YN, Liu N, Chen Y, Zhang W, Qu R, Zhang Q, et al. A versatile CeO2/Co3O4 coated mesh for food wastewater treatment: simultaneous oil removal and uv catalysis of food additives. Water Res 2018;137:144–52.
Setayesh SR, Nazari P, Maghbool R. Engineered FeVO4/CeO2 nanocomposite as a two-way superior electro-fenton catalyst for model and real wastewater treatment. J Environ Sci 2020;97:110–9.
Feng M, Goodenough JB, Huang K, Milliken C. Fuel cells with doped lanthanum gallate electrolyte. J Power Sources 1996;63:47–51.
Strickler DW, Carlson WG. Electrical conductivity in the ZrO2-rich region of several M2O3—ZrO2 systems. J Am Ceram Soc 1965;48:286–9.
Berenov A, Atkinson A, Kilner J, Ananyev M, Eremin V, Porotnikova N, et al. Oxygen tracer diffusion and surface exchange kinetics in Ba0.5Sr0.5Co0.8Fe0.2O3-delta. Solid State Ionics 2014;268:102–9.
Li M, Niu H, Druce J, Tellez H, Ishihara T, Kilner JA, et al. A CO2-tolerant perovskite oxide with high oxide ion and electronic conductivity. Adv Mater 2020;32:1905200.
Worell WL. Electrical properties of mixed-conducting oxides having high oxygen-ion conductivity. Solid State Ionics 1992;52:147–51.
Teraoka Y, Zhang HM, Okamoto K, Yamazoe N. Mixed ionic-electronic conductivity of La1−xSrxCo1−yFeyO3−δ perovskite-type oxides. Mater Res Bull 1988;23:51–8.
Huang K, Tichy RS, Goodenough JB. Superior perovskite oxide-ion conductor; strontium- and magnesium-doped LaGaO3: I, phase relationships and electrical properties. J Am Ceram Soc 1998;81:2565–75.
Huang K, Tichy RS, Goodenough JB. Superior perovskite oxide-ion conductor; strontium- and magnesium-doped LaGaO3: Ii, ac impedance spectroscopy. J Am Ceram Soc 1998;81:2576–80.
Li CJ, Chen X, Zhang SL, Li CX, Yang GJ. Novel approaches to prepare the high performance dense electolyte and interconnect applicable to SOFC by atmospheric plasma spraying. ECS Trans 2017;78:1831–8.
Shaula AL, Yaremchenko AA, Kharton VV, Logvinovich DI, Naumovich EN, Kovalevsky AV, et al. Oxygen permeability of LaGaO3-based ceramic membranes. J Membr Sci 2003;221:69–77.
Shao Z, Yang W, Cong Y, Dong H, Tong J, Xiong G. Investigation of the permeation behavior and stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxygen membrane. J Membr Sci 2000;172:177–88.
Wang B, Yi J, Winnubst L, Chen C. Stability and oxygen permeation behavior of Ce0.8Sm0.2O2-δ–La0.8Sr0.2CrO3-δ composite membrane under large oxygen partial pressure gradients. J Membr Sci 2006;286:22–5.
Vasala S, Lehtimäki M, Huang YH, Yamauchi H, Goodenough JB, Karppinen M. Degree of order and redox balance in B-site ordered double-perovskite oxides, Sr2MMoO6-δ (M=Mg, Mn, Fe, Co, Ni, Zn). J Solid State Chem 2010;183:1007–12.
Su Y, Wei T, Li Y, Yin B, Huan Y, Dong D, et al. A highly active CH4 catalyst correlated with solid oxide fuel cell anode performance. J Mater Chem 2021;9:5067–74.
Shannon RD. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A 1976;32:751–67.
Chen H, Guo Z, Zhang LA, Li Y, Li F, Zhang Y, et al. Improving the electrocatalytic activity and durability of the La0.6Sr0.4Co0.2Fe0.8O3-δ cathode by surface modification. ACS Appl Mater Interfaces 2018;10:39785–93.
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