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Research Article | Open Access

Improved piezoelectric and luminescent properties in Sm-modified Bi0.5Na0.5TiO3-BaTiO3 multifunctional ceramics

Shuai Chenga,b,1, Kehong Zhangd,1, Chongyang Lib, Boping Zhangc,( ), Jianguo Chena,( ), Kang Suna, Changrong zhoub, Jingtai Zhaob, Qisheng Linb, Guanghui Raob,( ), Siqi Shia,( )
School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China
Guangxi Key Laboratory of Information Materials & School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin, 541004, Guangxi, China
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China
School of Information Engineering, Lanzhou University of Finance and Economics, Lanzhou, 730020, China

1Shuai Cheng and Kehong Zhang contributed equally to this work.

Peer review under responsibility of The Chinese Ceramic Society.

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Graphical Abstract

Abstract

The 0.93(Na0.5Bi0.5)1-xSmxTiO3-0.07BaTiO3 multifunctional ceramics were prepared by solid-phase reaction method. The phase structure, microstructure, electrical and photoluminescent properties were systematically studied. With increasing x, the ceramics undergoes the phase transition from rhombohedral to tetragonal with some rhombohedral distortion, along with a reduced grain size and increased relative density. On the other hand, the Sm3+ doping enhances the electric-field driven reversible phase transition and domain size, and reduces the domain walls, thereby contributing to improved piezoelectricity and decreased depolarization temperature (Td) from 91 ℃ to 40 ℃. Excellent piezoelectric properties of d33 = 213 pC/N and kp = 29.9% are achieved in the x = 0.010 ceramic. Under excitation (407 nm), the Sm3+-doped ceramic exhibits bright reddish-orange fluorescence at 564, 599, 646 nm and 710 nm. A polarization-induced enhancement of photoluminescence is obtained in BNBT-xSm ceramics with an improved relative intensity of emission band at 646 nm. These results indicate that Sm3+-doped BNBT ceramics show great potential in electro-optic integration and coupling device applications.

Keywords

PhotoluminescenceThermal stabilityPhase transitionsCurie temperaturePiezoelectricity

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Journal of Materiomics
Volume 10 Issue 4,
July 2024
Pages 803-810
DOI: 10.1016/j.jmat.2023.09.012
Cite this article:
Cheng S, Zhang K, Li C, et al. Improved piezoelectric and luminescent properties in Sm-modified Bi0.5Na0.5TiO3-BaTiO3 multifunctional ceramics. Journal of Materiomics, 2024, 10(4): 803-810. https://doi.org/10.1016/j.jmat.2023.09.012

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Received: 15 August 2023
Revised: 15 September 2023
Accepted: 22 September 2023
Published: 18 October 2023
© 2023 The Authors.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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