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Research paper | Open Access

Enhanced piezoelectric properties and thermal stability of LiNbO3-modified PNN–PZT ceramics

Wei Penga( ), Jianglei Changa, Jianwei Zhaob, Dawei Wangb,c( ), Zhen Liud, Genshui Wangd, Shuxiang Donga( )
Institute for Advanced Study, Shenzhen University, Shenzhen, 518060, China
Shenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China
School of Instrumentation Science and Engineering, Harbin Institute of Technology, Harbin, 150080, China
Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China

Peer review under responsibility of The Chinese Ceramic Society.

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Graphical Abstract

Abstract

Piezoelectric PZT ceramics with high piezoelectric properties and good thermal stability are urgently desired concerning the practical application. New compositions of LiNbO3 modified Pb(Ni1/3Nb2/3)O3PbZrO3PbTiO3 ceramics have been prepared in this study. The effects of the introduction of the LiNbO3 on the system were comprehensively investigated in terms of the phase structure, microstructure, electric properties, and thermal stability behavior of the ceramics. All compositions are located in the morphotropic phase boundary (MPB) region, and the ratio of the rhombohedral (R) phase increases obviously with the increase of LiNbO3 concentration. With increasing the LiNbO3 content, the piezoelectric properties were significantly enhanced. The sample added with 2% (in mole) LiNbO3 shows excellent electric properties, including Tm = 185 ℃, εr= 5,643, kp = 0.626, Qm = 51, d33 = 902 pC/N. More importantly, no thermal depolarization behavior was observed in the temperature range of 25–100 ℃. For PNN-PZT-x%LN ceramics, which is mainly attributed to the pinning effect resulted by the (Li'Pb - NbZr=Ti·) defect dipoles.

Keywords

Thermal stabilityPiezoelectric propertyLiNbO3PNN-PZTDefect dipole

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Journal of Materiomics
Volume 10 Issue 5,
September 2024
Pages 995-1003
DOI: 10.1016/j.jmat.2023.10.013
Cite this article:
Peng W, Chang J, Zhao J, et al. Enhanced piezoelectric properties and thermal stability of LiNbO3-modified PNN–PZT ceramics. Journal of Materiomics, 2024, 10(5): 995-1003. https://doi.org/10.1016/j.jmat.2023.10.013

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Received: 03 August 2023
Revised: 13 October 2023
Accepted: 28 October 2023
Published: 22 November 2023
© 2023 The Authors.

This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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