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Research paper | Open Access

Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3: A novel high-entropy perovskite oxide with enhanced electromagnetic wave absorption properties

Mengru Lia,Qing ZhiaJinlu LiaChengwen WuaXuewen JiangaZhiyu MinbRui Zhanga,cHailong WangaHaibin Wangc( )Bingbing Fana( )
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China
School of Material Science and Engineering, Luoyang Institute of Science and Technology, Luoyang, 471023, Henan, China
Institute of Advanced Ceramics, Henan Academy of Sciences, Zhengzhou, 450046, China

Peer review under responsibility of The Chinese Ceramic Society.

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Abstract

Perovskite materials (ABO3) possess a wealth of elements selectable and exhibit a diverse range of octahedral transformations. The emergence of high-entropy perovskite ceramics provides a fresh perspective for advancing the field of wave-absorbing materials. In this study, we concentrate on the wet chemical synthesis of a high-entropy perovskite oxide, Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3, and investigate its crystal structure, microstructure, chemical composition, magnetic properties, and microwave absorbing capabilities. The results indicate that when sintered at a temperature of 1,350 ℃, the sample achieves a minimum reflection loss of −54.0 dB at a frequency of 9.68 GHz, accompanied by a maximum effective absorption bandwidth (EAB) of 7.44 GHz at the thickness of 1.8 mm. The high-entropy design of the B-site induces distortions of oxygen vacancy and octahedral structure of the perovskite material. This leads to the fine tuning of its dielectric and magnetic properties, thereby endowing perovskite with excellent electromagnetic wave absorption capabilities. Consequently, perovskite emerges as a promising new electromagnetic wave absorption material with significant potential.

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Journal of Materiomics
Pages 1176-1185
Cite this article:
Li M, Zhi Q, Li J, et al. Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3: A novel high-entropy perovskite oxide with enhanced electromagnetic wave absorption properties. Journal of Materiomics, 2024, 10(6): 1176-1185. https://doi.org/10.1016/j.jmat.2023.11.019

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Received: 16 September 2023
Revised: 09 November 2023
Accepted: 23 November 2023
Published: 23 December 2023
© 2023

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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