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Research Article | Open Access

A novel strategy of constructing 2D supramolecular organic framework sensor for the identification of toxic metal ions

Ying Wanga, Ning Hanb( ), Chao-Qun Maa, Hui Liua, Shengsheng Yua, Rongzhou Wanga, Vijay Kumar Thakurc, Ling-Bao Xinga( )
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo, 255000, PR China
Department of Materials Engineering, KU Leuven, Leuven, 3001, Belgium
Biorefining and Advanced Materials Research Center, Scotland's Rural College (SRUC), Kings Buildings, West Mains Road, Edinburgh, EH9 3JG, UK
Show Author Information

Abstract

Two novel two-dimensional (2D) supramolecular organic frameworks were fabricated in water based on the encapsulation-enhanced donor-acceptor interaction between the methyl viologen (MV) units, methoxy naphthyl (MN) units, and CB [8]. The tetraphenylethylene (TPE) derivatives 1 with four MV units were employed as rigid building blocks and the two MN units modified oligoethylene glycol derivatives 2 and 3 served as flexible edges, respectively. The obtained two SOFs have obvious sheet-like structures and exhibit fluorescence emission at 350–500 ​nm. In addition, these two SOFs were employed for the luminescent detection of Cr(Ⅵ) and Mn(Ⅶ) in aqueous solutions, and the detection limits of CrO42−, Cr2O72−, and MnO4− were calculated in a very low concentration range, indicating that these two SOFs can serve as a potential sensor for Cr(Ⅵ) and Mn(Ⅶ) detection in water. This work constructs two SOFs in an aqueous solution through a facile method and further enriches the applications of SOFs.

Keywords

Two-dimensional supramolecular organic frameworkEncapsulation-enhanced donor-acceptor interactionLuminescent detection

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Nano Materials Science
Volume 5 Issue 3,
September 2023
Pages 335-342
DOI: 10.1016/j.nanoms.2023.01.002
Cite this article:
Wang Y, Han N, Ma C-Q, et al. A novel strategy of constructing 2D supramolecular organic framework sensor for the identification of toxic metal ions. Nano Materials Science, 2023, 5(3): 335-342. https://doi.org/10.1016/j.nanoms.2023.01.002

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Received: 18 July 2022
Accepted: 28 December 2022
Published: 03 February 2023
© 2023 Chongqing University.

This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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