PDF (2.5 MB)
Collect
Submit Manuscript
Show Outline
Outline
Abstract
Keywords
Electronic Supplementary Material
References
Show full outline
Hide outline
Original Paper | Open Access

Effects of CH4/CO2 multi-component gas on components and properties of tight oil during CO2 utilization and storage: Physical experiment and composition numerical simulation

Zhi-Hao JiaaRen-Yi Caoa()Bin-Yu WangaLin-Song ChengaJin-Chong ZhouaBao-Biao PuaFu-Guo YinaMing Mab
College of Petroleum Engineering, China University of Petroleum, Beijing, 102245, China
The Pennsylvania State University, University Park, PA, 16802, USA

Edited by Yan-Hua Sun

Show Author Information

Abstract

An essential technology of carbon capture, utilization and storage-enhanced oil recovery (CCUS-EOR) for tight oil reservoirs is CO2 huff-puff followed by associated produced gas reinjection. In this paper, the effects of multi-component gas on the properties and components of tight oil are studied. First, the core displacement experiments using the CH4/CO2 multi-component gas are conducted to determine the oil displacement efficiency under different CO2 and CH4 ratios. Then, a viscometer and a liquid density balance are used to investigate the change characteristics of oil viscosity and density after multi-component gas displacement with different CO2 and CH4 ratios. In addition, a laboratory scale numerical model is established to validate the experimental results. Finally, a composition model of multi-stage fractured horizontal well in tight oil reservoir considering nano-confinement effects is established to investigate the effects of multi-component gas on the components of produced dead oil and formation crude oil. The experimental results show that the oil displacement efficiency of multi-component gas displacement is greater than that of single-component gas displacement. The CH4 decreases the viscosity and density of light oil, while CO2 decreases the viscosity but increases the density. And the numerical simulation results show that CO2 extracts more heavy components from the liquid phase into the vapor phase, while CH4 extracts more light components from the liquid phase into the vapor phase during cyclic gas injection. The multi-component gas can extract both the light components and the heavy components from oil, and the balanced production of each component can be achieved by using multi-component gas huff-puff.

Electronic Supplementary Material

Download File(s)
petsci-20-6-3478_ESM.pdf (61.7 KB)

References

 

Al Hinai, N.M., Myers, M.B., Dehghani, A.M., Wood, C.D., Valdez, R., Jin, F., Xie, Q., Saeedi, A., 2019. Effects of oligomers dissolved in CO2 or associated gas on IFT and miscibility pressure with a gas-light crude oil system. J. Petrol. Sci. Eng. 181, 106210. https://doi.org/10.1016/j.petrol.2019.106210.

 

Ally, J., Molla, S., Mostowfi, F., 2016. Condensation in nanoporous packed beds. Langmuir 32 (18), 4494–4499. https://doi.org/10.1021/acs.langmuir.6b01056.

 

Alquriaishi, A., Shokir, E., 2011. Experimental investigation of miscible CO2 flooding. Petrol. Sci. Technol. 29 (19), 2005–2016. https://doi.org/10.1080/10916461003662976.

 
Al-Riyami, H.F., Kamali, F., Hussain, F., 2017. Effect of gravity on near-miscible CO2 flooding. In: SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition doi:10.2118/188120-MS.
 
Ambrose, R.J., Hartman, R.C., Diaz-Campos, M., Akkutlu, I.Y., Sondergeld, C.H., 2010. New pore-scale considerations for shale gas in place calculations. In: SPE Unconventional Gas Conference. https://doi.org/10.2118/131772-MS.
 

Assef, Y., Kantzas, A., Almao, P.P., 2019. Numerical modelling of cyclic CO2 injection in unconventional tight oil resources; trivial effects of heterogeneity and hysteresis in Bakken Formation. Fuel 236 (15), 1512–1528. https://doi.org/10.1016/j.fuel.2018.09.046.

 

Bender, S., Akin, S., 2017. Flue gas injection for EOR and sequestration: case study. J. Petrol. Sci. Eng. 157, 1033–1045. https://doi.org/10.1016/j.petrol.2017.07.044.

 

Christensen, J.R., Stenby, E.H., Skauge, A., 2001. Review of WAG field experience. SPE Reservoir Eval. Eng. 4 (2), 97–106. https://doi.org/10.2118/71203-PA.

 

Crawford, P.B., Reynolds, B., Rushing, M.D., Thomassom, B., 1978. Nitrogen may be used for miscible displacement in oil reservoirs. J. Petrol. Technol. 30 (12), 1715–1716. https://doi.org/10.2118/6445-PA.

 

Dindoruk, B., Orr, F.M., Johns, R.T., 1997. Theory of multicontact miscible displacement with nitrogen. SPE J. 2 (3), 268–279. https://doi.org/10.2118/30771-PA.

 

Dong, M., Huang, S., 2002. Flue gas injection for heavy oil recovery. J. Can. Petrol. Technol. 41 (9), 44–50. https://doi.org/10.2118/02-09-04.

 

Dong, X., Liu, H., Hou, J., Wu, K., Chen, Z., 2016. Phase equilibria of confined fluids in nanopores of tight and shale rocks considering the effect of capillary pressure and adsorption film. Ind. Eng. Chem. Res. 55 (3), 798–811. https://doi.org/10.1021/acs.iecr.5b04276.

 
Duiveman, M.W., Herwin, H., Grivot, P.G., 2005. Integrated management of water, lean gas, and air injection: the successful ingredients to EOR projects on the mature H and il Field. In: SPE Asia Pacific Oil and Gas Conference and Exhibition. https://doi.org/10.2118/93858-MS.
 
Guo, H., Dong, J., Wang, Z., Liu, H., Ma, R., Kong, D., Wang, F., Xin, X., Li, Y., She, H., 2018. EOR survey in China-Part 1. In: SPE Improved Oil Recovery Conference. https://doi.org/10.2118/190286-MS.
 

Han, J., Lee, M., Lee, W., Lee, Y., Sung, W., 2016. Effect of gravity segregation on CO2 sequestration and oil production during CO2 flooding. Appl. Energy 161, 85–91. https://doi.org/10.1016/j.apenergy.2015.10.021.

 

Harpalani, S., Mitra, A., 2010. Impact of CO2 injection on flow behavior of coalbed methane reservoirs. Transport Porous Media 82, 141–156. https://doi.org/10.1007/s11242-009-9475-1.

 

Huang, K., Zhu, W., Sun, L., Wang, Q., Qing, L., 2019. Experimental study on gas EOR for heavy oil in Glutenite Reservoirs after water flooding. J. Petrol. Sci. Eng. 181, 106130. https://doi.org/10.1016/j.petrol.2019.05.081.

 

Hudgins, D.A., Llave, F.M., Chung, F.T.H., 1990. Nitrogen miscible displacement of light crude oil: a laboratory study. SPE Reservoir Eng. 5 (1), 100–106. https://doi.org/10.2118/17372-PA.

 
Janssen, M.T., Azimi, F., Zitha, P.L., 2018. Immiscible nitrogen flooding in Bentheimer Sandstones: comparing gas injection schemes for enhanced oil recovery. In: SPE Improved Oil Recovery Conference. https://doi.org/10.2118/190285-MS.
 

Jia, C., Zheng, M., Zhang, Y., 2012a. Unconventional hydrocarbon resources in China and the prospect of exploration and development. Petrol. Explor. Dev. 39 (2), 129–136. https://doi.org/10.1016/S1876-3804(12)60026-3.

 

Jia, C., Zou, C., Li, D., Zheng, M., 2012b. Assessment criteria, main types, basic features and resource prospects of the tight oil in China. Acta Pet. Sin. 33 (2), 343–350 (in Chinese). CNKI: SUN: SYXB.0.2012-03-000.

 

Jia, H., Sheng, J., 2017. Discussion of the feasibility of air injection for enhanced oil recovery in shale. Petroleum 3 (2), 249–257. https://doi.org/10.1016/J.PETLM.2016.12.003.

 

Jokar, S.M., Wood, D.A., Sinehbaghizadeh, S., Parvasi, P., Javanmardi, J., 2021. Transformation of associated natural gas into valuable products to avoid gas wastage in the form of flaring. J. Nat. Gas Sci. Eng. 94, 104078. https://doi.org/10.1016/j.jngse.2021.104078.

 

Kuang, L., Tang, Y., Lei, D., Chang, Q., Qu, Y., Hou, L., Liu, D., 2012. Formation conditions and exploration potential of tight oil in the Permian saline lacustrine dolomitic rock, Junggar Basin, NW China. Petrol. Explor. Dev. 39 (6), 700–711. https://doi.org/10.1016/S1876-3804(12)60095-0.

 
Lakatos, I., Bauer, K., Lakatos-Szabo, J., Puskas, S., Palasthy, G., Trömböczki, S., Kosztin, B., 1999. Injection of lean gases into light oil reservoirs: interfacial aspects. In: SPE Annual Technical Conference and Exhibition. https://doi.org/10.2118/56605-MS.
 

Li, D., Saraji, S., Jiao, Z., Zhang, Y., 2021. CO2 injection strategies for enhanced oil recovery and geological sequestration in a tight reservoir: an experimental study. Fuel 284, 119013. https://doi.org/10.1016/j.fuel.2020.119013.

 

Li, Z., Firoozabadi, A., 2009. Interfacial tension of non-associating pure substances and binary mixtures by density functional theory combined with Peng–Robinson equation of state. J. Chem. Phys. 130 (15), 154108. https://doi.org/10.1063/1.3100237.

 
Liu, Z., Hou, J., Gao, Z., Wu, Y., 1998. The feasibility studies of natural gas flooding in Ansai Field. In: International Petroleum Conference and Exhibition. https://doi.org/10.2118/39885-MS.
 
Luo, K., Li, S., Zheng, X., Chen, G., Dai, Z., Liu, N., 2001. Experimental investigation into revaporization of retrograde condensate by lean gas injection. In: SPE Asia Pacific Oil and Gas Conference and Exhibition. https://doi.org/10.2118/68683-MS.
 
Ning, S., Jhaveri, B., Chambers, B., Jia, N., Gao, J., 2011. Viscosity reduction EOR with CO2 & enriched CO2 to improve recovery of Alaska North Slope viscous oils. In: SPE Western North American Region Meeting doi:10.2118/144358-MS.
 
Pang, J., Zuo, J., Zhang, D., Du, L., 2012. Impact of porous media on saturation pressures of gas and oil in tight reservoirs. In: SPE Canadian Unconventional Resources Conference. https://doi.org/10.2118/161143-MS.
 
Parsa, E., Yin, X., Ozkan, E., 2015. Direct observation of the impact of nanopore confinement on petroleum gas condensation. In: SPE Annual Technical Conference and Exhibition. https://doi.org/10.2118/175118-MS.
 

Pinho, B., Girardon, S., Bazer-Bachi, F., Bergeot, G., Marre, S., Aymonier, C., 2014. A microfluidic approach for investigating multicomponent system thermodynamics at high pressures and temperatures. Lab Chip 14 (19), 3843–3849. https://doi.org/10.1039/c4lc00505h.

 

Pu, W., Bing, W., Jin, F., Li, Y., Tang, Z., 2016. Experimental investigation of CO2 huff-n-puff process for enhancing oil recovery in tight reservoirs. Chem. Eng. Res. Des. 111, 269–276. https://doi.org/10.1016/j.cherd.2016.05.012.

 

Qiu, Y., Wang, X., Liu, X., Cao, J., Liu, Y., Xi, B., Gao, W., 2020. In situ Raman spectroscopic quantification of CH4–CO2 mixture: application to fluid inclusions hosted in quartz veins from the Longmaxi Formation shales in Sichuan Basin, southwestern China. Petrol. Sci. 17, 23–35. https://doi.org/10.1007/s12182-019-00395-z.

 

Riazi, M., Sohrabi, M., Jamiolahmady, M., 2011. Experimental study of pore-scale mechanisms of carbonated water injection. Transport Porous Media 86, 73–86. https://doi.org/10.1007/s11242-010-9606-8.

 

Rogers, J., Grigg, R., 2001. A literature analysis of the WAG injectivity abnormalities in the CO2 process. SPE Reservoir Eval. Eng. 4 (5), 375–386. https://doi.org/10.2118/73830-PA.

 

Shyeh-Yung, J., Stadler, M., 1995. Effect of injectant composition and pressure on displacement of oil by enriched hydrocarbon gases. SPE Reservoir Eng. 10 (2), 109–115. https://doi.org/10.2118/28624-PA.

 

Singh, S., Sinha, A., Deo, G., Singh, J., 2009. Vapor-liquid phase coexistence, critical properties, and surface tension of confined alkanes. J. Phys. Chem. C 113 (17), 7170–7180. https://doi.org/10.1021/jp8073915.

 

Song, C., Yang, D., 2017. Experimental and numerical evaluation of CO2 huff-n-puff processes in Bakken Formation. Fuel 190 (15), 145–162. https://doi.org/10.1016/j.fuel.2016.11.041.

 

Song, Z., Song, Y., Guo, J., Zhang, Z., Hou, J., 2020. Adsorption induced critical shifts of confined fluids in shale nanopores. Chem. Eng. J. 385, 123837. https://doi.org/10.1016/j.cej.2019.123837.

 

Teklu, T.W., Alharthy, N., Kazemi, H., Yin, X., Graves, R.M., AlSumaiti, A.M., 2014. Phase behavior and minimum miscibility pressure in nanopores. SPE Reservoir Eval. Eng. 17 (3), 396–403. https://doi.org/10.2118/168865-PA.

 

Tian, Y., Xiong, Y., Wang, L., Lei, Z., Zhang, Y., Yin, X., Wu, Y., 2019. A compositional model for gas injection IOR/EOR in tight oil reservoirs under coupled nanopore confinement and geomechanics effects. J. Nat. Gas Sci. Eng. 71, 102973. https://doi.org/10.1016/j.jngse.2019.102973.

 
Tuta, A.T., Singhal, A.K., 1998. Reservoir engineering aspects of oil recovery from low permeability reservoirs by air injection. In: SPE International Oil and Gas Conference and Exhibition. https://doi.org/10.2118/48841-MS.
 

Vishnyakov, A., Piotrovskaya, E., Brodskaya, E., Votyakov, E., Tovbin, Y., 2001. Critical properties of Lennard-Jones fluids in narrow slit-shaped pores. Langmuir 17 (14), 4451–4458. https://doi.org/10.1021/la001641a.

 

Wang, J., Liu, H., Qian, G., Peng, Y., 2021. Mechanisms and capacity of high-pressure soaking after hydraulic fracturing in tight/shale oil reservoirs. Petrol. Sci. 18, 546–564. https://doi.org/10.1007/s12182-020-00524-z.

 

Wang, L., Tian, Y., Yu, X., Wang, C., Yao, B., Wang, S., Philip, W., Wang, X., Yang, Z., Wang, Y., 2017a. Advances in improved/enhanced oil recovery technologies for tight and shale reservoirs. Fuel 210 (15), 425–445. https://doi.org/10.1016/j.fuel.2017.08.095.

 

Wang, Y., Zhang, Y., Liu, Y., Zhang, L., Ren, S., Lu, J., Wang, X., Fan, N., 2017b. The stability study of CO2 foams at high pressure and high temperature. J. Petrol. Sci. Eng. 154, 234–243. https://doi.org/10.1016/j.petrol.2017.04.029.

 

Wei, J., Zhou, X., Zhou, J., Li, J., Wang, A., 2020. Recovery efficiency of tight oil reservoirs with different injection fluids: an experimental investigation of oil-water distribution feature. J. Petrol. Sci. Eng. 195, 107678. https://doi.org/10.1016/j.petrol.2020.107678.

 

Yang, G., Li, X., 2020. Modified Peng-Robinson equation of state for CO2/hydrocarbon systems within nanopores. J. Nat. Gas Sci. Eng. 84 (12), 103700. https://doi.org/10.1016/j.jngse.2020.103700.

 

Yang, G., Fan, Z., Li, X., 2019. Determination of confined fluid phase behavior using extended Peng–Robinson equation of state. Chem. Eng. J. 378, 122032. https://doi.org/10.1016/j.cej.2019.122032.

 

Yao, J., Deng, X., Zhao, Y., Han, T., Chu, M., Pang, J., 2013. Characteristics of tight oil in triassic yanchang formation, Ordos Basin. Petrol. Explor. Dev. 40 (2), 161–169. https://doi.org/10.1016/S1876-3804(13)60019-1.

 

Yu, H., Lu, X., Fu, W., Wang, Y., Xu, H., Xie, Q., Qu, X., Lu, J., 2020. Determination of minimum near miscible pressure region during CO2 and associated gas injection for tight oil reservoir in ordos basin, China. Fuel 263 (1), 116737. https://doi.org/10.1016/j.fuel.2019.116737.

 

Yu, H., Yang, Z., Luo, L., Liu, J., Cheng, S., Qu, X., Lei, Q., Lu, J., 2019. Application of cumulative-in-situ injection-production technology to supplement hydrocarbon recovery among fractured tight oil reservoirs: a case study in changqing oilfield, China. Fuel 242 (15), 804–818. https://doi.org/10.1016/j.fuel.2018.12.121.

 

Yu, Y., Li, L., Sheng, J., 2017. A comparative experimental study of gas injection in shale plugs by flooding and huff-n-puff processes. J. Nat. Gas Sci. Eng. 38, 195–202. https://doi.org/10.1016/j.jngse.2016.12.040.

 

Yu, Y., Meng, X., Sheng, J., 2016. Experimental and numerical evaluation of the potential of improving oil recovery from shale plugs by nitrogen gas flooding. Journal of Unconventional Oil and Gas Resources 15, 56–65. https://doi.org/10.1016/j.juogr.2016.05.003.

 

Zhang, J., Zhang, H., Ma, L., Liu, Y., Zhang, L., 2020. Performance evaluation and mechanism with different CO2 flooding modes in tight oil reservoir with fractures. J. Petrol. Sci. Eng. 188, 106950. https://doi.org/10.1016/j.petrol.2020.106950.

 

Zhang, X., Xiao, P., Sun, C., Luo, G., Ju, Ju, Wang, X., Wang, H., Yang, H., 2018a. Optimal activated carbon for separation of CO2 from (H2 + CO2) gas mixture. Petrol. Sci. 15, 625–633. https://doi.org/10.1007/s12182-018-0243-0.

 

Zhang, Y., Di, Y., Yu, W., Sepehrnoori, K., 2018b. A comprehensive model for investigation of carbon dioxide enhanced oil recovery with nanopore confinement in the bakken tight oil reservoir. SPE Reservoir Eval. Eng. 22 (1), 122–136. https://doi.org/10.2118/187211-PA.

 

Zheng, Z., Di, Y., Wu, Y., 2021. Nanopore confinement effect on the phase behavior of CO2/hydrocarbons in tight oil reservoirs considering capillary pressure, fluidwall interaction, and molecule adsorption. https://doi.org/10.1155/2021/2435930. Geofluids 2435930.

 

Zhou, X., Yuan, Q., Zhang, Y., Wang, H., Zeng, F., Zhang, L., 2019. Performance evaluation of CO2 flooding process in tight oil reservoir via experimental and numerical simulation studies. Fuel 236, 730–746. https://doi.org/10.1016/j.fuel.2018.09.035.

 

Zhu, C., Guo, W., Wang, Y., Li, Y., 2021. Experimental study of enhanced oil recovery by CO2 huff-n-puff in shales and tight sandstones with fractures. Petrol. Sci. 18, 852–869. https://doi.org/10.1007/s12182-020-00538-7.

 

Zou, C., Yang, Z., Hou, L., Cui, J., Wu, S., Lin, S., 2015. Geological characteristics and “sweet area” evaluation for tight oil. Petrol. Sci. 4, 606–617. https://doi.org/10.1007/S12182-015-0058-1.

Petroleum Science
Pages 3478-3487
Cite this article:
Jia Z-H, Cao R-Y, Wang B-Y, et al. Effects of CH4/CO2 multi-component gas on components and properties of tight oil during CO2 utilization and storage: Physical experiment and composition numerical simulation. Petroleum Science, 2023, 20(6): 3478-3487. https://doi.org/10.1016/j.petsci.2023.06.002
Metrics & Citations  
Article History
Copyright
Rights and Permissions
Return