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Paper | Open Access

Manufacturing N,O-carboxymethyl chitosan-reduced graphene oxide under freeze-dying for performance improvement of Li-S battery

Zhibin Jiang1,2,6Lujie Jin3,6Xiying Jian1Jinxia Huang1Hongshuai Wang3Binhong Wu1Kang Wang1Ling Chen1Youyong Li3,4( )Xiang Liu5Weishan Li1( )
School of Chemistry, Engineering Research Center of MTEES (Ministry of Education), Research Center of BMET (Guangdong Province), Engineering Laboratory of OFMHEB (Guangdong Province), Key Laboratory of ETESPG (GHEI), and Innovative Platform for ITBMD (Guangzhou Municipality), South China Normal University, Guangzhou, People’s Republic of China
Shenzhen School Affiliated to Sun Yat-Sen University, Shenzhen, People’s Republic of China
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, People’s Republic of China
Macao Institute of Materials Science and Engineering, Macau University of Science and Technology, Macau SAR, People’s Republic of China
College of Energy Science and Engineering, Nanjing Tech University, Nanjing, People’s Republic of China

6 These authors contributed equally to this work.

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Abstract

Lithium-sulfur (Li-S) batteries can provide far higher energy density than currently commercialized lithium ion batteries, but challenges remain before it they are used in practice. One of the challenges is the shuttle effect that originates from soluble intermediates, like lithium polysulfides. To address this issue, we report a novel laminar composite, N,O-carboxymethyl chitosan-reduced graphene oxide (CC-rGO), which is manufactured via the self-assembly of CC onto GO and subsequent reduction of GO under an extreme condition of 1 Pa and −50 ℃. The synthesized laminar CC-rGO composite is mixed with acetylene black (AB) and coated on a commercial polypropylene (PP) membrane, resulting in a separator (CC-rGO/AB/PP) that can not only completely suppress the polysulfides penetration, but also can accelerate the lithium ion transportation, providing a Li-S battery with excellent cyclic stability and rate capability. As confirmed by theoretic simulations, this unique feature of CC-rGO is attributed to its strong repulsive interaction to polysulfide anions and its benefit for fast lithium ion transportation through the paths paved by the heteroatoms in CC.

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International Journal of Extreme Manufacturing
Pages 015502-015502
Cite this article:
Jiang Z, Jin L, Jian X, et al. Manufacturing N,O-carboxymethyl chitosan-reduced graphene oxide under freeze-dying for performance improvement of Li-S battery. International Journal of Extreme Manufacturing, 2023, 5(1): 015502. https://doi.org/10.1088/2631-7990/aca44c

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Received: 20 February 2022
Revised: 16 May 2022
Accepted: 18 November 2022
Published: 08 December 2022
© 2022 The Author(s).

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