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Paper | Open Access

Bifunctional flexible electrochromic energy storage devices based on silver nanowire flexible transparent electrodes

He Zhang1,2Fangyuan Sun2Ge Cao2Dongyan Zhou2Guofan Zhang2Jiayun Feng1Shang Wang1Fengyu Su3,4( )Yanqing Tian2,5Yan Jun Liu3( )Yanhong Tian1,6 ( )
State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Department of Materials Science and Engineering, Southern University of Science and Technology Shenzhen 518055, People’s Republic of China
Department of Electrical and Electronic Engineering, Southern University of Science and Technology Shenzhen 518055, People’s Republic of China
Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055, People’s Republic of China
Key Laboratory of Energy Conversion and Storage Technology (Southern University of Science and Technology), Ministry of Education, Shenzhen 518055, People’s Republic of China
Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou 450041, People’s Republic of China
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Abstract

Flexible electrochromic energy storage devices (FECESDs) for powering flexible electronics have attracted considerable attention. Silver nanowires (AgNWs) are one kind of the most promising flexible transparent electrodes (FTEs) materials for the emerging flexible devices. Currently, fabricating FECESD based on AgNWs FTEs is still hindered by their intrinsic poor electrochemical stability. To address this issue, a hybrid AgNWs/Co(OH)2/PEDOT:PSS electrode is proposed. The PEDOT:PSS could not only improve the resistance against electrochemical corrosion of AgNWs, but also work as functional layer to realize the color-changing and energy storage properties. Moreover, the Co(OH)2 interlayer further improved the color-changing and energy storage performance. Based on the improvement, we assembled the symmetrical FECESDs. Under the same condition, the areal capacitance (0.8 mF cm−2) and coloration efficiency (269.80 cm2 C−1) of AgNWs/Co(OH)2/PEDOT:PSS FECESDs were obviously higher than AgNWs/PEDOT:PSS FECESDs. Furthermore, the obtained FECESDs exhibited excellent stability against the mechanical deformation. The areal capacitance remained stable during 1000 times cyclic bending with a 25 mm curvature radius. These results demonstrated the broad application potential of the AgNWs/Co(OH)2/PEDOT:PSS FECESD for the emerging portable and multifunctional electronics.

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International Journal of Extreme Manufacturing
Pages 015503-015503
Cite this article:
Zhang H, Sun F, Cao G, et al. Bifunctional flexible electrochromic energy storage devices based on silver nanowire flexible transparent electrodes. International Journal of Extreme Manufacturing, 2023, 5(1): 015503. https://doi.org/10.1088/2631-7990/aca638

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Received: 17 February 2022
Revised: 03 June 2022
Accepted: 24 November 2022
Published: 12 December 2022
© 2022 The Author(s).

Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

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