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Research Article | Open Access

Hydrogenation of Pyrolysis Oil from Loblolly Pine Residue

Ajoy Kanti Mondal1,6, Chengrong Qin2, Arthur J. Ragauskas3,4, Yonghao Ni1,5( ), Fang Huang1,2( )
College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou, Fujian Province, 350108, China
Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning, Guangxi Zhuang Autonomous Region, 530004, China
Department of Forestry, Wildlife, and Fisheries, Center for Renewable Carbon, University of Tennessee Institute of Agriculture, Knoxville, Tennessee, 37996, USA
Joint Institute for Biological Science, Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37831, USA
Department of Chemical Engineering, University of New Brunswick, Fredericton, E3B 5A3, Canada
Institute of Fuel Research and Development, Bangladesh Council of Scientific and Industrial Research, Dhaka-1205, Bangladesh
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Abstract

Loblolly pine residue prepared with and without zeolite ZSM-5 was pyrolyzed at 600℃ and the pyrolysis oil was hydrogenated using formic acid as a hydrogen source, in the presence of a Ru/activated carbon catalyst. As indicated by the pyrolysis yield, addition of the zeolite ZSM-5 increased the yield of light oil but decreased the yield of heavy oil. The pyrolysis oils were analyzed by 13C-, 31P-, 19F-nuclear magnetic resonance (NMR), and heteronuclear single quantum coherence or heteronuclear single quantum correlation nuclear magnetic resonance (HSQC-NMR), demonstrating that the zeolite ZSM-5 can efficiently induce decarboxylation reactions and decrease the content of aliphatic hydroxyl groups in the heavy oil by 57%. After hydrogenation of the pyrolysis oil, the aromatic carbon content decreased by 78%, with a significant increase in the aliphatic carbon content.

Keywords

hydrogenationpyrolysis oilLoblolly pine residuezeolite ZSM-5

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Paper and Biomaterials
Volume 5 Issue 1,
January 2020
Pages 1-13
DOI: 10.12103/j.issn.2096-2355.2020.01.001
Cite this article:
Mondal AK, Qin C, Ragauskas AJ, et al. Hydrogenation of Pyrolysis Oil from Loblolly Pine Residue. Paper and Biomaterials, 2020, 5(1): 1-13. https://doi.org/10.12103/j.issn.2096-2355.2020.01.001

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Received: 15 September 2019
Accepted: 06 November 2019
Published: 15 January 2020
© 2020 Paper and Biomaterials

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
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