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Research Article | Open Access

Improving Electrochemical Performance of Cellulose Fiber-based Supercapacitor Electrode Using Polypyrrole-wrapped Iron Oxyhydroxide

Youngchu Kang, Hailan Jin, Xianhui An, Xueren Qian( )
Key Laboratory of Bio-based Material Science & Technology (Northeast Forestry University) Ministry of Education, Harbin, Heilongjiang Province, 150040, China
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Abstract

Polypyrrole (PPy)@cellulose fiber-based composites have been widely investigated as electrode materials for use in flexible supercapacitors. However, they cannot readily provide high specific capacitance and cyclic stability owing to their inherent drawbacks, such as high resistance, Weber impedance, and volume expansion or collapse during charging/discharging. In this study, iron oxyhydroxide (FeOOH) is incorporated in the abovementioned composite to decrease the equivalent series resistance, charge transfer resistance, and Weber impedance, thereby enhancing electron transfer and ion diffusion, which results in superior electrochemical performance. The PPy-wrapped FeOOH@cellulose fiber-based composite electrode with the molar ratio of FeSO4 to NaBH4 of 1∶1 exhibits a high specific capacitance of 513.8 F/g at a current density of 0.2 A/g, as well as an excellent capacitance retention of 89.4% after 1000 cycles.

Keywords

electrochemical performancepolypyrroleelectrode materialiron oxyhydroxidecellulose fibers

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Paper and Biomaterials
Volume 6 Issue 3,
July 2021
Pages 10-19
DOI: 10.1213/j.issn.2096-2355.2021.03.002
Cite this article:
Kang Y, Jin H, An X, et al. Improving Electrochemical Performance of Cellulose Fiber-based Supercapacitor Electrode Using Polypyrrole-wrapped Iron Oxyhydroxide. Paper and Biomaterials, 2021, 6(3): 10-19. https://doi.org/10.1213/j.issn.2096-2355.2021.03.002

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Received: 30 April 2021
Accepted: 16 June 2021
Published: 25 July 2021
© 2021 Paper and Biomaterials

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
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