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Research Article | Open Access

Numerical Simulation of Microwave-assisted Depolymerization of Kraft Lignin

Zhenhao Ma1Wenliang Wang1,2( )Jiale Huang1Yujun Ma1Hui Miao1Yishuai Fu1Xiaoxiao Ren1
College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China
Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, Qilu University of Technology (Shandong Academy of Sciences), Ji'nan, Shandong Provice, 250353, China
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Abstract

Kraft lignin has the potential to replace traditional fossil resources for the preparation of high-value chemicals because it is rich in aromatic rings and active functional groups. An effective method for the pyrolysis of kraft lignin into chemicals/fuels is microwave-assisted depolymerization. A simulation model is urgently needed to illustrate the coupling effect and mechanism of lignin conversion during the depolymerization process. In this study, COMSOL Multiphysics was used to simulate the microwave-assisted depolymerization process. The results showed that microwave power had a significant effect on the electric field and temperature distribution in the microwave cavity, while the reaction time had little effect on the electric field. The effect of the nitrogen flow rate on the electric field and temperature was negligible. The intensity of the electric field, heating rate of lignin, and final temperature of lignin depolymerization increased with increasing microwave power.

References

[1]

Kwon G, Bhatnagar A, Wang H. A review of recent advancements in utilization of biomass and industrial wastes into engineered biochar. Journal of Hazardous Materials, 2020, DOI: 10.1016/j.jhazmat.2020.123242.

[2]

Hu X, Gholizadeh M. Biomass pyrolysis: A review of the process development and challenges from initial researches up to the commercialisation stage. Journal of Energy Chemistry, 2019, 39, 109-143.

[3]

Farag S, Mudraboyina B P, Jessop P G. Impact of the heating mechanism on the yield and composition of bio-oil from pyrolysis of kraft lignin. Biomass and Bioenergy, 2016, 95, 344-353.

[4]

Feng Y, Li G, Li X. Enhancement of biomass conversion in catalytic fast pyrolysis by microwave-assisted formic acid pretreatment. Bioresource Technology, 2016, 214, 520-527.

[5]

Liu X, Bouxin F P, Fan J. Microwave-assisted catalytic depolymerization of lignin from birch sawdust to produce phenolic monomers utilizing a hydrogen-free strategy. Journal of Hazardous Materials, 2021, DOI: 10.1016/j.jhazmat.2020.123490.

[6]

Zhou M, Sharma B K, Li J. Catalytic valorization of lignin to liquid fuels over solid acid catalyst assisted by microwave heating. Fuel, 2019, 239, 239-244.

[7]

Ma R, Yuan N, Sun S. Preliminary investigation of the microwave pyrolysis mechanism of sludge based on high frequency structure simulator simulation of the electromagnetic field distribution. Bioresource Technology, 2017, 234, 370-379.

[8]

Ciacci T, Galgano A, Di Blasi C. Numerical simulation of the electromagnetic field and the heat and mass transfer processes during microwave-induced pyrolysis of a wood block. Chemical Engineering Science, 2010, 65(14), 4117-4133.

[9]

Miran W, Palazoğlu T K. Development and experimental validation of a multiphysics model for 915 MHz microwave tempering of frozen food rotating on a turntable. Biosystems Engineering, 2019, 180, 191-203.

[10]

Mokhta Z M, Ong M Y, Salman B. Simulation studies on microwave-assisted pyrolysis of biomass for bioenergy production with special attention on waveguide number and location. Energy, 2020, DOI: 10.1016/j.energy.2019.116474.

[11]

Ma W, Hong T, Xie T. Simulation and analysis of oleic acid pretreatment for microwave-assisted biodiesel production. Processes, 2018, DOI:10.3390/pr6090142.

[12]

Li H, Shi S, Lin B. A fully coupled electromagnetic, heat transfer and multiphase porous media model for microwave heating of coal. Fuel Processing Technology, 2019, 189, 49-61.

[13]

Gadkari S, Fidalgo B, Gu S. Numerical investigation of microwave-assisted pyrolysis of lignin. Fuel Processing Technology, 2017, 156, 473-484.

[14]

Salvi D, Boldor D, Aita G M. COMSOL Multiphysics model for continuous flow microwave heating of liquids. Journal of Food Engineering, 2011, 104(3), 422-429.

[15]

Cui K, Liao T, Qiu C. Microwave-induced heating behavior of Y-TZP ceramics under multiphysics system. Green Processing and Synthesis, 2020, 9(1), 119-130.

[16]

Wang W, Wang M, Huang J. High efficiency pyrolysis of used cigarette filters for ester-rich bio-oil through microwave-assisted heating. Journal of Cleaner Production, 2020, DOI:10.1016/j.jclepro.2020.120596.

[17]

Zhang K, Hu H, Liu X. Study on thermal characteristics of deep groove ball bearing based on Green's Function and COMSOL. Journal of Physics: Conference Series, 2021, DOI:10.1088/1742-6596/1798/1/012046.

[18]

Wang R, Yu K. Stress and Deformation Analysis of High Concrete Face Rockfill Dam Based on COMSOL Multiphysics. IOP Conference Series: Earth and Environmental Science, 2021, DOI: 10.1088/1755-1315/643/1/012013.

[19]

Geedipalli S S R, Rakesh V, Datta A K. Modeling the heating uniformity contributed by a rotating turntable in microwave ovens. Journal of Food Engineering, 2007, 82 (3), 359-368.

[20]

Halim S A, Swithenbank J. Simulation study of parameters influencing microwave heating of biomass. Journal of the Energy Institute, 2019, 92(4), 1191-1212.

[21]

Zhang C, Lan J, Hong T. Dynamic analysis and simulation on continuous flow processing of biodiesel production in single-mode microwave cavity. International Journal of Applied Electromagnetics and Mechanics, 2016, 51(2), 199-213.

[22]

Yu S, Duan Y, Zhou X. Three-dimensional simulation of a novel microwave-assisted heating device for methyl ricinoleate pyrolysis. Applied Thermal Engineering, 2019, 153, 341-351.

[23]

Khachatryan L, Barekati-Goudarzi M, Kekejian D. Pyrolysis of lignin in gas-phase isothermal and cw-CO2 laser powered non-isothermal reactors. Energy & Fuels, 2018, 32(12), 12597-12606.

[24]

Li H, Shi S, Lin B. A fully coupled electromagnetic, heat transfer and multiphase porous media model for microwave heating of coal. Fuel Processing Technology, 2019, 189, 49-61.

[25]

Motasemi F, Gerber A G. Multicomponent conjugate heat and mass transfer in biomass materials during microwave pyrolysis for biofuel production. Fuel, 2018, 211, 649-660.

[26]

Wang W, Ma Z, Zhao X. Effect of Various Microwave Absorbents on the Microwave-Assisted Lignin Depolymerization Process. ACS Sustainable Chemistry & Engineering, 2020, 8(43), 16086-16090.

[27]

Duan D, Zhao Y, Fan L. Low-power microwave radiation-assisted depolymerization of ethanol organosolv lignin in ethanol/formic acid mixtures. BioResources, 2017, 12(3), 5308-5320.

[28]

Dong C, Feng C, Liu Q. Mechanism on microwave-assisted acidic solvolysis of black-liquor lignin. Bioresource Technology, 2014, 162, 136-141.

[29]

Huang Y F, Chiueh P T, Kuan W H. Microwave pyrolysis of lignocellulosic biomass: Heating performance and reaction kinetics. Energy, 2016, 100, 137-144.

Paper and Biomaterials
Pages 47-53
Cite this article:
Ma Z, Wang W, Huang J, et al. Numerical Simulation of Microwave-assisted Depolymerization of Kraft Lignin. Paper and Biomaterials, 2021, 6(4): 47-53. https://doi.org/10.1213/j.issn.2096-2355.2021.04.006

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Received: 26 March 2021
Accepted: 29 April 2021
Published: 25 October 2021
© 2021 Paper and Biomaterials

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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