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Research Article | Open Access

NIR-responsive Collagen-based Sponge Coated with Polydimethylsiloxane/Candle Soot for Oil-Water Separation

Min Zhang1( ), Chenchen Guo1, Yu Wang1, Yunlong Zhang1, Hui Wu1, Liulian Huang1, Yonghao Ni1,2, Cuicui Ding3, Lihui Chen1
College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou, Fujian Province, 350002, China
Department of Chemical Engineering and Limerick Pulp & Paper Centre, University of New Brunswick, Fredericton, E3B 5A3, Canada
College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, Fujian Province, 350108, China
Show Author Information

Abstract

To fabricate an oil-water separation material that is rich in source, eco-friendly, and responsive, in this study, we successfully developed a collagen-based sponge for application to oil-water separation based on a green and facile strategy. In this design, widely-available collagen (COL) was used as the substrate: it was immersed in polydimethylsiloxane (PDMS) suspension with candle soot (CS) nanoparticles, followed by hot curing. The resultant sponge (CS/PDMS-COL) possessed good hydrophobicity with a water contact angle of 148.3° under a low PDMS concentration of 2%. The results from field emission scanning electron microscope, Fourier transform infrared spectrometer, X-ray photoelectron spectrometer, and X-ray diffractometry demonstrated the successful coating of CS and PDMS on the surface of COL substrate. The CS/PDMS-COL can adsorb eight oils, with the adsorption capacity for trichloromethane reaching 95 g/g. With benzene as the target adsorbent, the separation efficiency was maintained at no less than 95% even after recycling 20 times. CS/PDMS-COL was also used to separate oil-in-water emulsion. Moreover, the sponge killed bacteria effectively due to its excellent near-infrared photothermal responsiveness. This study provides new insight into the preparation of facile oil-water separation materials based on naturally occurring biomaterials effortlessly.

Keywords

photothermal effectantibacterial propertyoil-water separationcollagen spongecandle soot

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Paper and Biomaterials
Volume 7 Issue 3,
July 2022
Pages 30-41
DOI: 10.1213/j.issn.2096-2355.2022.03.004
Cite this article:
Zhang M, Guo C, Wang Y, et al. NIR-responsive Collagen-based Sponge Coated with Polydimethylsiloxane/Candle Soot for Oil-Water Separation. Paper and Biomaterials, 2022, 7(3): 30-41. https://doi.org/10.1213/j.issn.2096-2355.2022.03.004

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Received: 22 April 2022
Accepted: 10 May 2022
Published: 25 July 2022
© 2022 Paper and Biomaterials

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
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